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ABC transporter G family member 29 Coniferyl Alcohol Transporter Coniferyl Alcohol Transporter 4-Coumaryl Alcohol Transporter Sinapyl Alcohol Transporter 5- Hydroxyconiferyl Alcohol Transporter Sinapyl Alcohol Transporter 1-O-Sinapoyl- beta D-Glucose Transporter 1-O-Sinapoyl- beta D-Glucose Transporter phenylalanine ammonia lyase 1 4CL1 Cinnamoyl-CoA reductase 1 Cinnamate 4-hydroxylase Cinnamate 4-hydroxylase 4CL1 Cinnamoyl-CoA reductase 1 Hydroxycinnamoyl- CoA shikimate/quinate hydroxycinnamoyl transferase Hydroxycinnamoyl- CoA shikimate/quinate hydroxycinnamoyl transferase Cytochrome P450 98A3 Hydroxycinnamoyl- CoA shikimate/quinate hydroxycinnamoyl transferase Cytochrome P450 98A3 Hydroxycinnamoyl- CoA shikimate/quinate hydroxycinnamoyl transferase Caffeoylshikimate esterase 4CL1 Caffeate O- methyltransferase Cinnamoyl-CoA reductase 1 CAD5 CAD5 4CL1 Caffeoyl-CoA O- methyltransferase 1 Cinnamoyl-CoA reductase 1 Caffeate O- methyltransferase CAD5 Caffeate O- methyltransferase Aldehyde dehydrogenase family 2 member C4 Ferulate 5-hydroxylase 4CL1 Cinnamoyl-CoA reductase 1 CAD5 Ferulate 5-hydroxylase Ferulate 5-hydroxylase Caffeate O- methyltransferase 4CL1 Caffeoyl-CoA O- methyltransferase 1 Cinnamoyl-CoA reductase 1 CAD5 Caffeate O- methyltransferase Caffeate O- methyltransferase Aldehyde dehydrogenase family 2 member C4 Feruloyl CoA ortho-hydroxylase 2 Peroxidase 1 Peroxidase 1 Peroxidase 1 Peroxidase 1 Cytochrome P450 98A8 Unknown Cytochrome P450 98A8 Tapetum-specific methyltransferase 1 UDP- glycosyltransferase 72E3 UDP- glycosyltransferase 72E3 UDP- glycosyltransferase 72E3 UDP- glycosyltransferase 84A2 Serine carboxypeptidase- like 8 Serine carboxypeptidase- like 19 L-Phenylalanine trans-Cinnamic acid Coumaroyl-CoA Cinnamoyl-CoA 4-Coumaryl alcohol 4-Coumaryl alcohol Coniferyl alcohol Coniferyl alcohol Coniferyl alcohol 4-Coumaryl alcohol Sinapyl alcohol Sinapyl alcohol 5- Hydroxyconiferyl alcohol 5- Hydroxyconiferyl alcohol Sinapyl alcohol 1-O-Sinapoyl- beta-D-glucose 1-O-Sinapoyl- beta-D-glucose 1-O-Sinapoyl- beta-D-glucose Ammonium ATP CoA AMP Diphosphoric acid Cinnamaldehyde CoA NADP NADPH H+ O2 4-Hydroxycinnamic acid H2O O2 H2O ATP CoA AMP PPi p-Coumaraldehyde CoA NADP NADPH H+ Quinate CoA p-Coumaroyl quinic acid Shikimic acid CoA 4- Coumaroylshikimic acid O2 Chlorogenic acid H2O Caffeoyl-CoA Quinate CoA O2 5-O- Caffeoylshikimic acid H2O CoA Shikimic acid H2O 3,4-Dihydroxy- trans-cinnamate Shikimic acid ATP CoA AMP Diphosphoric acid S- Adenosylmethionine S- Adenosylhomocysteine trans-Ferulic acid Caffeic aldehyde CoA NADP NADPH H+ NADPH H+ Caffeyl alcohol NADP NADPH H+ NADP ATP CoA AMP Diphosphoric acid Feruloyl-CoA S- Adenosylmethionine S- Adenosylhomocysteine Coniferyl aldehyde CoA NADP NADPH H+ S- Adenosylmethionine S- Adenosylhomocysteine NADP NADPH H+ S- Adenosylmethionine S- Adenosylhomocysteine H2O NADP NADPH H+ NADPH H+ O2 3-(3,4- Dihydroxy-5- methoxy)-2- propenoic acid NADP H2O CoA ATP 5- Hydroxyferuloyl- CoA AMP Diphosphoric acid NADPH H+ 5- Hydroxyconiferaldehyde CoA NADP NADPH H+ NADP NADPH H+ O2 NADP H2O NADPH H+ O2 NADP H2O S- Adenosylmethionine S- Adenosylhomocysteine Sinapic acid ATP CoA AMP Diphosphoric acid Sinapoyl-CoA S- Adenosylmethionine S- Adenosylhomocysteine Sinapoyl aldehyde CoA NADP NADPH H+ NADP NADPH H+ S- Adenosylmethionine S- Adenosylhomocysteine S- Adenosylmethionine S- Adenosylhomocysteine NADP H2O NADPH H+ Oxoglutaric acid O2 6- Hydroxyferuloyl- CoA Succinic acid CO2 p-Hydroxyphenyl lignin Guaiacyl lignin 5-Hydroxy- guaiacyl lignin Syringyl lignin N1,N5,N10- Tricoumaroyl spermidine N1,N5,N10- Tricaffeoyl spermidine N1,N5,N10- Triferuloyl spermidine N1,N5,N10- Tri(hydroxyferuloyl) spermidine S- Adenosylmethionine N1,N5- Di(hydroxyferuloyl)- N10-sinapoyl spermidine S- Adenosylhomocysteine Uridine diphosphate glucose Uridine 5'-diphosphate 4-Hydroxycinnamyl alcohol 4-D-glucoside Uridine diphosphate glucose Uridine 5'-diphosphate Coniferin Uridine diphosphate glucose Uridine 5'-diphosphate Syringin Uridine diphosphate glucose Uridine 5'-diphosphate L-Malic acid D-Glucose Sinapoyl malate Sinapine D-Glucose Choline Heme Heme Zinc (II) ion Zinc (II) ion Zinc (II) ion Ascorbic acid Fe2+ Heme Mg2+ [Reduced NADPH--- hemoprotein reductase] [Oxidized NADPH--- hemoprotein reductase] [Reduced NADPH--- hemoprotein reductase] [Oxidized NADPH--- hemoprotein reductase] [Reduced NADPH--- hemoprotein reductase] [Oxidized NADPH--- hemoprotein reductase] [Reduced NADPH--- hemoprotein reductase] [Oxidized NADPH--- hemoprotein reductase] Phenylalanine Biosynthesis Ubiquinone Biosynthesis Flavonoid Biosynthesis Stillbenoid Diarylhe Ptanoid and Gingerol Biosynthesis CAD4 CAD4 CAD4 CAD4 CAD4 Zinc (II) ion Zinc (II) ion Zinc (II) ion Zinc (II) ion Zinc (II) ion Heme Zinc (II) ion Heme Heme Zinc (II) ion Heme Calcium Heme Calcium Heme Calcium Heme Calcium Heme Nucleus Vacuole Cytoplasm Extracellular Space
Nucleus Vacuole ABCG29 Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown PAL1 4CL1 CCR1 CYP73A5 CYP73A5 4CL1 CCR1 HST HST CYP98A3 HST CYP98A3 HST CSE 4CL1 OMT1 CCR1 CAD5 CAD5 4CL1 CCOAOMT1 CCR1 OMT1 CAD5 OMT1 ALDH2C4 CYP84A1 4CL1 CCR1 CAD5 CYP84A1 CYP84A1 OMT1 4CL1 CCOAOMT1 CCR1 CAD5 OMT1 OMT1 ALDH2C4 F6'H2 PER1 PER1 PER1 PER1 CYP98A8 Unknown CYP98A8 TSM1 UGT72E3 UGT72E3 UGT72E3 UGT84A2 SCPL8 SCPL19 L-Phenylalanine trans-Cinnamic acid Coumaroyl-CoA Cinnamoyl-CoA 4-Coumaryl alcohol 4-Coumaryl alcohol Coniferyl alcohol Coniferyl alcohol Coniferyl alcohol 4-Coumaryl alcohol Sinapyl alcohol Sinapyl alcohol 5- Hydroxyconiferyl alcohol 5- Hydroxyconiferyl alcohol Sinapyl alcohol 1-O-Sinapoyl- beta-D-glucose 1-O-Sinapoyl- beta-D-glucose 1-O-Sinapoyl- beta-D-glucose Ammonium Adenosine triphosphate Coenzyme A Adenosine monophosphate Diphosphoric acid Cinnamaldehyde Coenzyme A NADP NADPH Hydrogen Ion Oxygen 4-Hydroxycinnamic acid Water Oxygen Water Adenosine triphosphate Coenzyme A Adenosine monophosphate Pyrophosphate p-Coumaraldehyde Coenzyme A NADP NADPH Hydrogen Ion Quinate Coenzyme A p-Coumaroyl quinic acid Shikimic acid Coenzyme A 4- Coumaroylshikimic acid Oxygen Chlorogenic acid Water Caffeoyl-CoA Quinate Coenzyme A Oxygen 5-O- Caffeoylshikimic acid Water Coenzyme A Shikimic acid Water 3,4-Dihydroxy- trans-cinnamate Shikimic acid Adenosine triphosphate Coenzyme A Adenosine monophosphate Diphosphoric acid S- Adenosylmethionine S- Adenosylhomocysteine trans-Ferulic acid Caffeic aldehyde Coenzyme A NADP NADPH Hydrogen Ion NADPH Hydrogen Ion Caffeyl alcohol NADP NADPH Hydrogen Ion NADP Adenosine triphosphate Coenzyme A Adenosine monophosphate Diphosphoric acid Feruloyl-CoA S- Adenosylmethionine S- Adenosylhomocysteine Coniferyl aldehyde Coenzyme A NADP NADPH Hydrogen Ion S- Adenosylmethionine S- Adenosylhomocysteine NADP NADPH Hydrogen Ion S- Adenosylmethionine S- Adenosylhomocysteine Water NADP NADPH Hydrogen Ion NADPH Hydrogen Ion Oxygen 3-(3,4- Dihydroxy-5- methoxy)-2- propenoic acid NADP Water Coenzyme A Adenosine triphosphate 5- Hydroxyferuloyl- CoA Adenosine monophosphate Diphosphoric acid NADPH Hydrogen Ion 5- Hydroxyconiferaldehyde Coenzyme A NADP NADPH Hydrogen Ion NADP NADPH Hydrogen Ion Oxygen NADP Water NADPH Hydrogen Ion Oxygen NADP Water S- Adenosylmethionine S- Adenosylhomocysteine Sinapic acid Adenosine triphosphate Coenzyme A Adenosine monophosphate Diphosphoric acid Sinapoyl-CoA S- Adenosylmethionine S- Adenosylhomocysteine Sinapoyl aldehyde Coenzyme A NADP NADPH Hydrogen Ion NADP NADPH Hydrogen Ion S- Adenosylmethionine S- Adenosylhomocysteine S- Adenosylmethionine S- Adenosylhomocysteine NADP Water NADPH Hydrogen Ion Oxoglutaric acid Oxygen 6- Hydroxyferuloyl- CoA Succinic acid Carbon dioxide p-Hydroxyphenyl lignin Guaiacyl lignin 5-Hydroxy- guaiacyl lignin Syringyl lignin N1,N5,N10- Tricoumaroyl spermidine N1,N5,N10- Tricaffeoyl spermidine N1,N5,N10- Triferuloyl spermidine N1,N5,N10- Tri(hydroxyferuloyl) spermidine S- Adenosylmethionine N1,N5- Di(hydroxyferuloyl)- N10-sinapoyl spermidine S- Adenosylhomocysteine Uridine diphosphate glucose Uridine 5'-diphosphate 4-Hydroxycinnamyl alcohol 4-D-glucoside Uridine diphosphate glucose Uridine 5'-diphosphate Coniferin Uridine diphosphate glucose Uridine 5'-diphosphate Syringin Uridine diphosphate glucose Uridine 5'-diphosphate L-Malic acid D-Glucose Sinapoyl malate Sinapine D-Glucose Choline [Reduced NADPH--- hemoprotein reductase] [Oxidized NADPH--- hemoprotein reductase] [Reduced NADPH--- hemoprotein reductase] [Oxidized NADPH--- hemoprotein reductase] [Reduced NADPH--- hemoprotein reductase] [Oxidized NADPH--- hemoprotein reductase] [Reduced NADPH--- hemoprotein reductase] [Oxidized NADPH--- hemoprotein reductase] Phenylalanine Biosynthesis Ubiquinone Biosynthesis Flavonoid Biosynthesis Stillbenoid Diarylhe Ptanoid and Gingerol Biosynthesis CAD4 CAD4 CAD4 CAD4 CAD4
ABCG29 PAL1 4CL1 CCR1 CYP73A5 CYP73A5 4CL1 CCR1 HST HST CYP98A3 HST CYP98A3 HST CSE 4CL1 OMT1 CCR1 CAD5 CAD5 4CL1 CCOAOMT1 CCR1 OMT1 CAD5 OMT1 ALDH2C4 CYP84A1 4CL1 CCR1 CAD5 CYP84A1 CYP84A1 OMT1 4CL1 CCOAOMT1 CCR1 CAD5 OMT1 OMT1 ALDH2C4 F6'H2 PER1 PER1 PER1 PER1 CYP98A8 CYP98A8 TSM1 UGT72E3 UGT72E3 UGT72E3 UGT84A2 SCPL8 SCPL19 Phe Cinnama CoumCoA CinaCoA 3-OHPP 3-OHPP Conifer Conifer Conifer 3-OHPP SA SA 5-Hy al 5-Hy al SA 1-O-S-b 1-O-S-b 1-O-S-b Ammon ATP CoA AMP Dip aci Cinnama CoA NADP NADPH H+ O2 PC H2O O2 H2O ATP CoA AMP PPi p-Couma CoA NADP NADPH H+ Quinate CoA pCoqa Shikima CoA 4-CouSA O2 Chlroga H2O CafeyCA Quinate CoA O2 5-O-C a H2O CoA Shikima H2O Caffeat Shikima ATP CoA AMP Dip aci SAMe SAH Ferulat Caf ald CoA NADP NADPH H+ NADPH H+ Caf alc NADP NADPH H+ NADP ATP CoA AMP Dip aci FruylCA SAMe SAH Con ald CoA NADP NADPH H+ SAMe SAH NADP NADPH H+ SAMe SAH H2O NADP NADPH H+ NADPH H+ O2 Hfl NADP H2O CoA ATP 5-Hy-Co AMP Dip aci NADPH H+ 5-Hydro CoA NADP NADPH H+ NADP NADPH H+ O2 NADP H2O NADPH H+ O2 NADP H2O SAMe SAH Sinapat ATP CoA AMP Dip aci Sin-CoA SAMe SAH Sin ald CoA NADP NADPH H+ NADP NADPH H+ SAMe SAH SAMe SAH NADP H2O NADPH H+ AKG O2 6-Hy-Co Succini CO2 p-Hy li Gua lig 5-H-g l Syr lig N1-Tr s N1-Tr s N-T s N1-Tr s SAMe N-D-N-s SAH UDPG UDP 4HA4DG UDPG UDP Abietin UDPG UDP Syrin UDPG UDP Malate D-Glc Sin mal Sinapin D-Glc Choline Heme Heme Zinc Zinc Zinc VitC Fe2+ Heme Mg2+ RNHR ONHR RNHR ONHR RNHR ONHR RNHR ONHR Phe Bio Ubi Bio Fla Bio S D P a CAD4 CAD4 CAD4 CAD4 CAD4 Zinc Zinc Zinc Zinc Zinc Heme Zinc Heme Heme Zinc Heme Ca2+ Heme Ca2+ Heme Ca2+ Heme Ca2+ Heme Nucleus Vacuole Cytoplasm Extracellular Space
Nucleus Vacuole ABCG29 PAL1 4CL1 CCR1 CYP73A5 CYP73A5 4CL1 CCR1 HST HST CYP98A3 HST CYP98A3 HST CSE 4CL1 OMT1 CCR1 CAD5 CAD5 4CL1 CCOAOMT1 CCR1 OMT1 CAD5 OMT1 ALDH2C4 CYP84A1 4CL1 CCR1 CAD5 CYP84A1 CYP84A1 OMT1 4CL1 CCOAOMT1 CCR1 CAD5 OMT1 OMT1 ALDH2C4 F6'H2 PER1 PER1 PER1 PER1 CYP98A8 CYP98A8 TSM1 UGT72E3 UGT72E3 UGT72E3 UGT84A2 SCPL8 SCPL19 Phe Cinnama CoumCoA CinaCoA 3-OHPP 3-OHPP Conifer Conifer Conifer 3-OHPP SA SA 5-Hy al 5-Hy al SA 1-O-S-b 1-O-S-b 1-O-S-b Ammon ATP CoA AMP Dip aci Cinnama CoA NADP NADPH H+ O2 PC H2O O2 H2O ATP CoA AMP Ppi p-Couma CoA NADP NADPH H+ Quinate CoA pCoqa Shikima CoA 4-CouSA O2 Chlroga H2O CafeyCA Quinate CoA O2 5-O-C a H2O CoA Shikima H2O Caffeat Shikima ATP CoA AMP Dip aci SAMe SAH Ferulat Caf ald CoA NADP NADPH H+ NADPH H+ Caf alc NADP NADPH H+ NADP ATP CoA AMP Dip aci FruylCA SAMe SAH Con ald CoA NADP NADPH H+ SAMe SAH NADP NADPH H+ SAMe SAH H2O NADP NADPH H+ NADPH H+ O2 Hfl NADP H2O CoA ATP 5-Hy-Co AMP Dip aci NADPH H+ 5-Hydro CoA NADP NADPH H+ NADP NADPH H+ O2 NADP H2O NADPH H+ O2 NADP H2O SAMe SAH Sinapat ATP CoA AMP Dip aci Sin-CoA SAMe SAH Sin ald CoA NADP NADPH H+ NADP NADPH H+ SAMe SAH SAMe SAH NADP H2O NADPH H+ AKG O2 6-Hy-Co Succini CO2 p-Hy li Gua lig 5-H-g l Syr lig N1-Tr s N1-Tr s N-T s N1-Tr s SAMe N-D-N-s SAH UDPG UDP 4HA4DG UDPG UDP Abietin UDPG UDP Syrin UDPG UDP Malate D-Glc Sin mal Sinapin D-Glc Choline RNHR ONHR RNHR ONHR RNHR ONHR RNHR ONHR Phe Bio Ubi Bio Fla Bio S D P a CAD4 CAD4 CAD4 CAD4 CAD4