ReactionCatalysis203607
type: Catalysis
controller: Unknown
controlled: Reaction214002
control type: ACTIVATION

Reference/ChEBI CHEBI 16015
type: UnificationXref
id: CHEBI:16015
db: ChEBI

ReactionCatalysis203606
type: Catalysis
controller: Unknown
controlled: 2.5.1.115
control type: ACTIVATION

Reference/ChEBI CHEBI 33270
type: UnificationXref
id: CHEBI:33270
db: ChEBI

ReactionCatalysis203609
type: Catalysis
controller: Unknown
controlled: Reaction214004
control type: ACTIVATION

Reference/ChemSpider 30572
type: UnificationXref
id: 30572
db: ChemSpider

ReactionCatalysis203608
type: Catalysis
controller: Unknown
controlled: 5.5.1.24
control type: ACTIVATION

ReactionCatalysis203603
type: Catalysis
controller: Unknown
controlled: 1.13.11.27
control type: ACTIVATION

Compound/PW C000749 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: S-Adenosylhomocysteine
stoichiometric coefficient: 1.0

ReactionCatalysis203605
type: Catalysis
controller: Unknown
controlled: Reaction214000
control type: ACTIVATION

ReactionCatalysis203604
type: Catalysis
controller: Unknown
controlled: 2.5.1.117
control type: ACTIVATION

Reference/ChEBI CHEBI 33277
type: UnificationXref
id: CHEBI:33277
db: ChEBI

Unknown
type: ProteinReference
organism: Cannabis sativa

Reference/BioCyc P-HYDROXY-PHENYLPYRUVATE
type: UnificationXref
id: P-HYDROXY-PHENYLPYRUVATE
db: BioCyc

Reference/CAS 6699-20-3
type: UnificationXref
id: 6699-20-3
db: CAS

Reference/KEGG Compound C14155
type: UnificationXref
id: C14155
db: KEGG Compound

Reference/HMDB HMDB0001185
type: UnificationXref
id: HMDB0001185
db: HMDB

Reference/ChemSpider 50
type: UnificationXref
id: 50
db: ChemSpider

Unknown
type: Protein
cellular location: Chloroplast
entity reference: Unknown

Reference/SMPDB SMP0123242
type: UnificationXref
id: SMP0123242
db: SMPDB

Reference/ChemSpider 24785305
type: UnificationXref
id: 24785305
db: ChemSpider

ReactionCatalysis203614
type: Catalysis
controller: Unknown
controlled: Reaction214009
control type: ACTIVATION

ReactionCatalysis203613
type: Catalysis
controller: Unknown
controlled: Reaction214008
control type: ACTIVATION

Reference/ChemSpider 5833
type: UnificationXref
id: 5833
db: ChemSpider

ReactionCatalysis203610
type: Catalysis
controller: Unknown
controlled: Reaction214005
control type: ACTIVATION

ReactionCatalysis203612
type: Catalysis
controller: Unknown
controlled: Reaction214007
control type: ACTIVATION

ReactionCatalysis203611
type: Catalysis
controller: Unknown
controlled: Reaction214006
control type: ACTIVATION

Reference/CAS 14101-61-2
type: UnificationXref
id: 14101-61-2
db: CAS

Compound/PW C000095/Stoichiometry/1.0
type: Stoichiometry
physical entity: L-Glutamic acid
stoichiometric coefficient: 1.0

ChemicalStructure/PW C000103
type: ChemicalStructure
structure format: SMILES
structure data: N[C@@H](CC1=CC=C(O)C=C1)C(O)=O

Reference/PubChem-compound 51
type: UnificationXref
id: 51
db: PubChem-compound

Compound/PW C104756 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Solanesyl pyrophosphate
stoichiometric coefficient: 1.0

α-Tocotrienol
type: SmallMolecule
cellular location: Chloroplast
entity reference: α-Tocotrienol

Compound/PW C001149 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: γ-Tocopherol
stoichiometric coefficient: 1.0

ChemicalStructure/PW C057909
type: ChemicalStructure
structure format: SMILES

S-Adenosylmethionine
type: SmallMoleculeReference
xref: Reference/PubChem-compound 24762165
xref: Reference/KEGG Compound C00019
xref: Reference/ChemSpider 31983
xref: Reference/ChEBI CHEBI 15414
xref: Reference/CAS 485-80-3
xref: Reference/BioCyc S-ADENOSYLMETHIONINE
xref: Reference/HMDB HMDB0001185
chemical formula: C15H23N6O5S
molecular weight: 399.14505
structure: ChemicalStructure/PW C000921

Reference/KEGG Compound C17570
type: UnificationXref
id: C17570
db: KEGG Compound

Reference/ChEBI CHEBI 44747
type: UnificationXref
id: CHEBI:44747
db: ChEBI

Reference/TAXONOMY 3483
type: UnificationXref
id: 3483
db: TAXONOMY

Reference/ChemSpider 954
type: UnificationXref
id: 954
db: ChemSpider

Reference/ChemSpider 952
type: UnificationXref
id: 952
db: ChemSpider

Reference/GENE ONTOLOGY GO 0005829
type: UnificationXref
id: GO:0005829
db: GENE ONTOLOGY

ChemicalStructure/PW C057910
type: ChemicalStructure
structure format: SMILES

Reference/ChemSpider 274
type: UnificationXref
id: 274
db: ChemSpider

Reference/GENE ONTOLOGY GO 0009507
type: UnificationXref
id: GO:0009507
db: GENE ONTOLOGY

Reference/CAS 1721-51-3
type: UnificationXref
id: 1721-51-3
db: CAS

Compound/PW C000921 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: S-Adenosylmethionine
stoichiometric coefficient: 1.0

Oxoglutaric acid
type: SmallMoleculeReference
xref: Reference/CAS 328-50-7
xref: Reference/PubChem-compound 51
xref: Reference/BioCyc 2-KETOGLUTARATE
xref: Reference/HMDB HMDB0000208
xref: Reference/ChEBI CHEBI 30915
xref: Reference/KEGG Compound C00026
xref: Reference/ChemSpider 50
chemical formula: C5H6O5
molecular weight: 146.02153
structure: ChemicalStructure/PW C000134

Reference/BioCyc GERANYLGERANYL-PP
type: UnificationXref
id: GERANYLGERANYL-PP
db: BioCyc

Reference/BioCyc TYR
type: UnificationXref
id: TYR
db: BioCyc

2-Methyl-6-phytylhydroquinone
type: SmallMoleculeReference
xref: Reference/CAS 54432-31-4
xref: Reference/ChemSpider 24785305
xref: Reference/PubChem-compound 23724601
xref: Reference/HMDB HMDB0038959
xref: Reference/KEGG Compound C15882
xref: Reference/ChEBI CHEBI 75406
chemical formula: C27H46O2
molecular weight: 402.3498
structure: ChemicalStructure/PW C019799

Reference/CAS 59-02-9
type: UnificationXref
id: 59-02-9
db: CAS

Reference/BioCyc ADENOSYL-HOMO-CYS
type: UnificationXref
id: ADENOSYL-HOMO-CYS
db: BioCyc

ChemicalStructure/PW C000558
type: ChemicalStructure
structure format: SMILES
structure data: OC(=O)C(=O)CC1=CC=C(O)C=C1

Reference/KEGG Compound C20737
type: UnificationXref
id: C20737
db: KEGG Compound

Reference/CAS 485-80-3
type: UnificationXref
id: 485-80-3
db: CAS

Reference/PubChem-compound 6830
type: UnificationXref
id: 6830
db: PubChem-compound

Reference/KEGG Compound C04145
type: UnificationXref
id: C04145
db: KEGG Compound

Reference/PubChem-compound 1023
type: UnificationXref
id: 1023
db: PubChem-compound

Reference/HMDB HMDB0001893
type: UnificationXref
id: HMDB0001893
db: HMDB

Compound/PW C000558/Stoichiometry/1.0
type: Stoichiometry
physical entity: 4-Hydroxyphenylpyruvic acid
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0004486
type: UnificationXref
id: HMDB0004486
db: HMDB

6-Geranylgeranyl-2-methylbenzene-1,4-diol
type: SmallMolecule
cellular location: Chloroplast
entity reference: 6-Geranylgeranyl-2-methylbenzene-1,4-diol

Reference/PubChem-compound 7791
type: UnificationXref
id: 7791
db: PubChem-compound

ChemicalStructure/PW C000921
type: ChemicalStructure
structure format: SMILES

Reference/CAS 979-92-0
type: UnificationXref
id: 979-92-0
db: CAS

Reference/KEGG Compound C00353
type: UnificationXref
id: C00353
db: KEGG Compound

Reference/HMDB HMDB0000208
type: UnificationXref
id: HMDB0000208
db: HMDB

Carbon dioxide
type: SmallMolecule
cellular location: Cytosol
entity reference: Carbon dioxide

Cytosol
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0005829

Reference/BioCyc CPD-6641
type: UnificationXref
id: CPD-6641
db: BioCyc

Carbon dioxide
type: SmallMolecule
cellular location: Chloroplast
entity reference: Carbon dioxide

S-Adenosylhomocysteine
type: SmallMoleculeReference
xref: Reference/PubChem-compound 25246222
xref: Reference/ChemSpider 388301
xref: Reference/BioCyc ADENOSYL-HOMO-CYS
xref: Reference/CAS 979-92-0
xref: Reference/KEGG Compound C00021
xref: Reference/ChEBI CHEBI 16680
xref: Reference/HMDB HMDB0000939
chemical formula: C14H20N6O5S
molecular weight: 384.12158
structure: ChemicalStructure/PW C000749

L-Glutamic acid
type: SmallMolecule
entity reference: L-Glutamic acid

plastoquinol-9
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 28026
xref: Reference/ChemSpider 4945177
xref: Reference/KEGG Compound C16695
xref: Reference/BioCyc CPD-12829
xref: Reference/PubChem-compound 6440941
chemical formula: C53H82O2
molecular weight: 750.6315
structure: ChemicalStructure/PW C057910

ChemicalStructure/PW C000134
type: ChemicalStructure
structure format: SMILES
structure data: OC(=O)CCC(=O)C(O)=O

Solanesyl pyrophosphate
type: SmallMolecule
cellular location: Chloroplast
entity reference: Solanesyl pyrophosphate

Reference/CAS 124-38-9
type: UnificationXref
id: 124-38-9
db: CAS

Diphosphoric acid
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 29888
xref: Reference/CAS 2466-09-3
xref: Reference/KEGG Compound C00013
xref: Reference/PubChem-compound 1023
chemical formula: H4O7P2
molecular weight: 177.94322
structure: ChemicalStructure/PW C108886

Reference/ChEBI CHEBI 30915
type: UnificationXref
id: CHEBI:30915
db: ChEBI

Compound/PW C000084 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: Homogentisic acid
stoichiometric coefficient: 1.0

Reference/KEGG Compound C00007
type: UnificationXref
id: C00007
db: KEGG Compound

Reference/CAS 451-13-8
type: UnificationXref
id: 451-13-8
db: CAS

Reference/ChEBI CHEBI 15414
type: UnificationXref
id: CHEBI:15414
db: ChEBI

Reference/PubChem-compound 447277
type: UnificationXref
id: 447277
db: PubChem-compound

ChemicalStructure/PW C019799
type: ChemicalStructure
structure format: SMILES

Unknown
type: Protein
cellular location: Cytosol
entity reference: Unknown

Diphosphoric acid
type: SmallMolecule
cellular location: Chloroplast
entity reference: Diphosphoric acid

Ubiquinone and other terpenoid-quinone biosynthesis
type: Pathway
pathway order: PathwayEnzymeReaction/2467626
pathway order: PathwayEnzymeReaction/2467625
pathway order: PathwayEnzymeReaction/2467628
pathway order: PathwayEnzymeReaction/2467627
pathway order: PathwayEnzymeReaction/2467629
pathway order: PathwayEnzymeReaction/2467631
pathway order: PathwayEnzymeReaction/2467630
pathway order: PathwayEnzymeReaction/2467622
pathway order: PathwayEnzymeReaction/2467633
pathway order: PathwayEnzymeReaction/2467632
pathway order: PathwayEnzymeReaction/2467624
pathway order: PathwayEnzymeReaction/2467623
pathway component: ReactionCatalysis203607
pathway component: Reaction214007
pathway component: ReactionCatalysis203606
pathway component: Reaction214006
pathway component: ReactionCatalysis203609
pathway component: Reaction214009
pathway component: 1.13.11.27
pathway component: ReactionCatalysis203608
pathway component: Reaction214008
pathway component: ReactionCatalysis203603
pathway component: 2.5.1.117
pathway component: ReactionCatalysis203614
pathway component: ReactionCatalysis203613
pathway component: ReactionCatalysis203605
pathway component: ReactionCatalysis203604
pathway component: ReactionCatalysis203610
pathway component: 2.5.1.115
pathway component: ReactionCatalysis203612
pathway component: Reaction214000
pathway component: ReactionCatalysis203611
pathway component: 5.5.1.24
pathway component: Reaction214002
pathway component: Reaction214005
pathway component: Reaction214004
xref: Reference/SMPDB SMP0123242
xref: Reference/PathWhiz PW124592
organism: Cannabis sativa

Reference/KEGG Compound C15883
type: UnificationXref
id: C15883
db: KEGG Compound

Geranylgeranyl-PP
type: SmallMoleculeReference
xref: Reference/CAS 6699-20-3
xref: Reference/ChemSpider 394418
xref: Reference/PubChem-compound 447277
xref: Reference/KEGG Compound C00353
xref: Reference/BioCyc GERANYLGERANYL-PP
xref: Reference/ChEBI CHEBI 48861
xref: Reference/HMDB HMDB0004486
chemical formula: C20H36O7P2
molecular weight: 450.19363
structure: ChemicalStructure/PW C002145

Reference/HMDB HMDB0006327
type: UnificationXref
id: HMDB0006327
db: HMDB

Compound/PW C109089 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 6-Geranylgeranyl-2-methylbenzene-1,4-diol
stoichiometric coefficient: 1.0

Reference/BioCyc GLT
type: UnificationXref
id: GLT
db: BioCyc

Reference/ChEBI CHEBI 48861
type: UnificationXref
id: CHEBI:48861
db: ChEBI

Homogentisic acid
type: SmallMoleculeReference
xref: Reference/CAS 451-13-8
xref: Reference/ChEBI CHEBI 44747
xref: Reference/ChemSpider 759
xref: Reference/HMDB HMDB0000130
xref: Reference/KEGG Compound C00544
xref: Reference/PubChem-compound 780
chemical formula: C8H8O4
molecular weight: 168.04225
structure: ChemicalStructure/PW C000084

Reference/PubChem-compound 14985
type: UnificationXref
id: 14985
db: PubChem-compound

Reference/KEGG Compound C00019
type: UnificationXref
id: C00019
db: KEGG Compound

Reference/PubChem-compound 14986
type: UnificationXref
id: 14986
db: PubChem-compound

Reference/ChemSpider 394418
type: UnificationXref
id: 394418
db: ChemSpider

Reference/KEGG Compound C00011
type: UnificationXref
id: C00011
db: KEGG Compound

ChemicalStructure/PW C001316
type: ChemicalStructure
structure format: SMILES
structure data: O=C=O

Reference/BioCyc S-ADENOSYLMETHIONINE
type: UnificationXref
id: S-ADENOSYLMETHIONINE
db: BioCyc

Reference/PubChem-compound 254741206
type: UnificationXref
id: 254741206
db: PubChem-compound

Reference/PubChem-compound 254741205
type: UnificationXref
id: 254741205
db: PubChem-compound

Reference/KEGG Compound C00013
type: UnificationXref
id: C00013
db: KEGG Compound

Reference/ChEBI CHEBI 28026
type: UnificationXref
id: CHEBI:28026
db: ChEBI

Reference/ChemSpider 4945177
type: UnificationXref
id: 4945177
db: ChemSpider

α-Tocopherol
type: SmallMoleculeReference
xref: Reference/PubChem-compound 14985
xref: Reference/HMDB HMDB0001893
xref: Reference/CAS 59-02-9
xref: Reference/BioCyc CPD-1125
xref: Reference/ChemSpider 14265
xref: Reference/KEGG Compound C02477
xref: Reference/ChEBI CHEBI 18145
chemical formula: C29H50O2
molecular weight: 430.38107
structure: ChemicalStructure/PW C001261

Compound/PW C001261 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: α-Tocopherol
stoichiometric coefficient: 1.0

Compound/PW C057910 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: plastoquinol-9
stoichiometric coefficient: 1.0

Compound/PW C002145 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Geranylgeranyl-PP
stoichiometric coefficient: 1.0

Reference/ChemSpider 388301
type: UnificationXref
id: 388301
db: ChemSpider

Reference/ChEBI CHEBI 15999
type: UnificationXref
id: CHEBI:15999
db: ChEBI

Reference/HMDB HMDB0038959
type: UnificationXref
id: HMDB0038959
db: HMDB

S-Adenosylmethionine
type: SmallMolecule
cellular location: Chloroplast
entity reference: S-Adenosylmethionine

γ-Tocopherol
type: SmallMoleculeReference
xref: Reference/CAS 10191-41-0
xref: Reference/PubChem-compound 14986
xref: Reference/ChEBI CHEBI 298402
xref: Reference/HMDB HMDB0001492
xref: Reference/ChemSpider 14266
chemical formula: C28H48O2
molecular weight: 416.36542
structure: ChemicalStructure/PW C001149

Reference/KEGG Compound C00021
type: UnificationXref
id: C00021
db: KEGG Compound

Compound/PW C001065 Cytosol/Stoichiometry/2.0
type: Stoichiometry
physical entity: Oxygen
stoichiometric coefficient: 2.0

Reference/KEGG Compound C00026
type: UnificationXref
id: C00026
db: KEGG Compound

Reference/KEGG Compound C00025
type: UnificationXref
id: C00025
db: KEGG Compound

6-Geranylgeranyl-2-methylbenzene-1,4-diol
type: SmallMoleculeReference
xref: Reference/KEGG Compound C20737
xref: Reference/PubChem-compound 254741205
chemical formula: C27H40O2
molecular weight: 396.30283
structure: ChemicalStructure/PW C109089

2-Methyl-6-phytylhydroquinone
type: SmallMolecule
cellular location: Chloroplast
entity reference: 2-Methyl-6-phytylhydroquinone

Reference/PathWhiz PW124592
type: UnificationXref
id: PW124592
db: PathWhiz

Phytyl pyrophosphate
type: SmallMoleculeReference
xref: Reference/PubChem-compound 7791
xref: Reference/ChEBI CHEBI 75837
xref: Reference/KEGG Compound C05427
chemical formula: C20H42O7P2
molecular weight: 456.24057
structure: ChemicalStructure/PW C104757

Compound/PW C000103/Stoichiometry/1.0
type: Stoichiometry
physical entity: L-Tyrosine
stoichiometric coefficient: 1.0

Solanesyl pyrophosphate
type: SmallMoleculeReference
xref: Reference/PubChem-compound 6830
xref: Reference/KEGG Compound C04145
xref: Reference/ChEBI CHEBI 18144
chemical formula: C45H76O7P2
molecular weight: 790.50665
structure: ChemicalStructure/PW C104756

Cannabis sativa
type: BioSource
xref: Reference/TAXONOMY 3483

S-Adenosylhomocysteine
type: SmallMolecule
cellular location: Chloroplast
entity reference: S-Adenosylhomocysteine

6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol
type: SmallMoleculeReference
xref: Reference/KEGG Compound C20738
xref: Reference/PubChem-compound 254741206
chemical formula: C28H42O2
molecular weight: 410.31848
structure: ChemicalStructure/PW C109091

2,3-Dimethyl-5-phytyl-1,4-hydroquinone
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 75407
xref: Reference/PubChem-compound 47205203
xref: Reference/KEGG Compound C15883
chemical formula: C28H48O2
molecular weight: 416.36542
structure: ChemicalStructure/PW C109093

Reference/CAS 328-50-7
type: UnificationXref
id: 328-50-7
db: CAS

Reference/KEGG Compound C15882
type: UnificationXref
id: C15882
db: KEGG Compound

Reference/HMDB HMDB0000130
type: UnificationXref
id: HMDB0000130
db: HMDB

ChemicalStructure/PW C001261
type: ChemicalStructure
structure format: SMILES

Compound/PW C057909 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 2-methyl-6-solanesyl-1,4-benzoquinol
stoichiometric coefficient: 1.0

Reference/ChemSpider 4445512
type: UnificationXref
id: 4445512
db: ChemSpider

1.13.11.27
type: BiochemicalReaction
participant stoichiometry: Compound/PW C000084 Cytosol/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001316 Cytosol/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001065 Cytosol/Stoichiometry/2.0
participant stoichiometry: Compound/PW C000558 Cytosol/Stoichiometry/1.0
right: Carbon dioxide
right: Homogentisic acid
spontaneous: false
EC number: 1.13.11.27
left: 4-Hydroxyphenylpyruvic acid
left: Oxygen
name: 4-Hydroxyphenylpyruvic acid + 2 Oxygen → Carbon dioxide + Homogentisic acid
conversion direction: LEFT_TO_RIGHT

4-Hydroxyphenylpyruvic acid
type: SmallMoleculeReference
xref: Reference/BioCyc P-HYDROXY-PHENYLPYRUVATE
xref: Reference/CAS 156-39-8
xref: Reference/ChEBI CHEBI 15999
xref: Reference/PubChem-compound 979
xref: Reference/HMDB HMDB0000707
xref: Reference/ChemSpider 954
xref: Reference/KEGG Compound C01179
chemical formula: C9H8O4
molecular weight: 180.04225
structure: ChemicalStructure/PW C000558

α-Tocopherol
type: SmallMolecule
cellular location: Chloroplast
entity reference: α-Tocopherol

2.5.1.117
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057909 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001316 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C104756 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000084 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108886 Chloroplast/Stoichiometry/1.0
right: 2-methyl-6-solanesyl-1,4-benzoquinol
right: Diphosphoric acid
right: Carbon dioxide
spontaneous: false
EC number: 2.5.1.117
left: Solanesyl pyrophosphate
left: Homogentisic acid
name: Homogentisic acid + Solanesyl pyrophosphate → 2-methyl-6-solanesyl-1,4-benzoquinol + 2 Carbon dioxide + Diphosphoric acid
conversion direction: LEFT_TO_RIGHT

ChemicalStructure/PW C001149
type: ChemicalStructure
structure format: SMILES

Reference/HMDB HMDB0000939
type: UnificationXref
id: HMDB0000939
db: HMDB

Reference/HMDB HMDB0000148
type: UnificationXref
id: HMDB0000148
db: HMDB

Compound/PW C108886 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Diphosphoric acid
stoichiometric coefficient: 1.0

Reference/ChemSpider 4445514
type: UnificationXref
id: 4445514
db: ChemSpider

γ-Tocopherol
type: SmallMolecule
cellular location: Chloroplast
entity reference: γ-Tocopherol

Reference/CAS 54432-31-4
type: UnificationXref
id: 54432-31-4
db: CAS

Reference/BioCyc 2-METHYL-6-SOLANYL-14-BENZOQUINONE
type: UnificationXref
id: 2-METHYL-6-SOLANYL-14-BENZOQUINONE
db: BioCyc

Reference/KEGG Compound C02477
type: UnificationXref
id: C02477
db: KEGG Compound

Reference/ChEBI CHEBI 75407
type: UnificationXref
id: CHEBI:75407
db: ChEBI

Reference/ChEBI CHEBI 75406
type: UnificationXref
id: CHEBI:75406
db: ChEBI

Reference/HMDB HMDB0000707
type: UnificationXref
id: HMDB0000707
db: HMDB

Reference/PubChem-compound 780
type: UnificationXref
id: 780
db: PubChem-compound

4-Hydroxyphenylpyruvic acid
type: SmallMolecule
entity reference: 4-Hydroxyphenylpyruvic acid

Reference/PubChem-compound 44237185
type: UnificationXref
id: 44237185
db: PubChem-compound

Reference/ChEBI CHEBI 75402
type: UnificationXref
id: CHEBI:75402
db: ChEBI

4-Hydroxyphenylpyruvic acid
type: SmallMolecule
cellular location: Cytosol
entity reference: 4-Hydroxyphenylpyruvic acid

Oxygen
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0001377
xref: Reference/ChemSpider 952
xref: Reference/KEGG Compound C00007
xref: Reference/ChEBI CHEBI 15379
xref: Reference/PubChem-compound 977
xref: Reference/BioCyc CPD-6641
xref: Reference/CAS 7782-44-7
chemical formula: O2
molecular weight: 31.98983
structure: ChemicalStructure/PW C001065

Reference/HMDB HMDB0000158
type: UnificationXref
id: HMDB0000158
db: HMDB

γ-Tocotrienol
type: SmallMoleculeReference
xref: Reference/CAS 14101-61-2
xref: Reference/PubChem-compound 5282349
xref: Reference/ChEBI CHEBI 33277
xref: Reference/HMDB HMDB0012958
xref: Reference/KEGG Compound C14155
xref: Reference/ChemSpider 4445514
chemical formula: C28H42O2
molecular weight: 410.31848
structure: ChemicalStructure/PW C008136

Compound/PW C008136 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: γ-Tocotrienol
stoichiometric coefficient: 1.0

Reference/PubChem-compound 23724601
type: UnificationXref
id: 23724601
db: PubChem-compound

Reference/CAS 56-86-0
type: UnificationXref
id: 56-86-0
db: CAS

ChemicalStructure/PW C108886
type: ChemicalStructure
structure format: SMILES
structure data: OP(O)(=O)OP(O)(O)=O

L-Glutamic acid
type: SmallMoleculeReference
xref: Reference/PubChem-compound 33032
xref: Reference/ChEBI CHEBI 16015
xref: Reference/ChemSpider 30572
xref: Reference/HMDB HMDB0000148
xref: Reference/CAS 56-86-0
xref: Reference/BioCyc GLT
xref: Reference/KEGG Compound C00025
chemical formula: C5H9NO4
molecular weight: 147.05316
structure: ChemicalStructure/PW C000095

Compound/PW C104757 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Phytyl pyrophosphate
stoichiometric coefficient: 1.0

Reference/PubChem-compound 33032
type: UnificationXref
id: 33032
db: PubChem-compound

Reference/CAS 60-18-4
type: UnificationXref
id: 60-18-4
db: CAS

Reference/ChEBI CHEBI 16526
type: UnificationXref
id: CHEBI:16526
db: ChEBI

Compound/PW C000084 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Homogentisic acid
stoichiometric coefficient: 1.0

Compound/PW C000134/Stoichiometry/1.0
type: Stoichiometry
physical entity: Oxoglutaric acid
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 18144
type: UnificationXref
id: CHEBI:18144
db: ChEBI

Reference/CAS 7782-44-7
type: UnificationXref
id: 7782-44-7
db: CAS

Reference/ChEBI CHEBI 18145
type: UnificationXref
id: CHEBI:18145
db: ChEBI

Reference/HMDB HMDB0001377
type: UnificationXref
id: HMDB0001377
db: HMDB

Reference/KEGG Compound C20738
type: UnificationXref
id: C20738
db: KEGG Compound

α-Tocotrienol
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 33270
xref: Reference/ChemSpider 4445512
xref: Reference/PubChem-compound 5282347
xref: Reference/HMDB HMDB0006327
xref: Reference/KEGG Compound C14153
xref: Reference/CAS 1721-51-3
chemical formula: C29H44O2
molecular weight: 424.33414
structure: ChemicalStructure/PW C002720

Reference/ChEBI CHEBI 298402
type: UnificationXref
id: CHEBI:298402
db: ChEBI

Reference/HMDB HMDB0001492
type: UnificationXref
id: HMDB0001492
db: HMDB

2-methyl-6-solanesyl-1,4-benzoquinol
type: SmallMoleculeReference
xref: Reference/BioCyc 2-METHYL-6-SOLANYL-14-BENZOQUINONE
xref: Reference/KEGG Compound C17570
xref: Reference/PubChem-compound 44237185
xref: Reference/ChEBI CHEBI 75402
chemical formula: C52H80O2
molecular weight: 736.61584
structure: ChemicalStructure/PW C057909

Reference/ChemSpider 31983
type: UnificationXref
id: 31983
db: ChemSpider

Reference/BioCyc 2-KETOGLUTARATE
type: UnificationXref
id: 2-KETOGLUTARATE
db: BioCyc

L-Tyrosine
type: SmallMoleculeReference
xref: Reference/CAS 60-18-4
xref: Reference/PubChem-compound 6057
xref: Reference/HMDB HMDB0000158
xref: Reference/ChEBI CHEBI 17895
xref: Reference/KEGG Compound C00082
xref: Reference/ChemSpider 5833
xref: Reference/BioCyc TYR
chemical formula: C9H11NO3
molecular weight: 181.0739
structure: ChemicalStructure/PW C000103

Carbon dioxide
type: SmallMoleculeReference
xref: Reference/PubChem-compound 280
xref: Reference/ChEBI CHEBI 16526
xref: Reference/ChemSpider 274
xref: Reference/HMDB HMDB0001967
xref: Reference/CAS 124-38-9
xref: Reference/KEGG Compound C00011
chemical formula: CO2
molecular weight: 43.98983
structure: ChemicalStructure/PW C001316

Reference/CAS 10191-41-0
type: UnificationXref
id: 10191-41-0
db: CAS

Reference/PubChem-compound 5282349
type: UnificationXref
id: 5282349
db: PubChem-compound

ChemicalStructure/PW C001065
type: ChemicalStructure
structure format: SMILES
structure data: O=O

Reference/PubChem-compound 5282347
type: UnificationXref
id: 5282347
db: PubChem-compound

Oxoglutaric acid
type: SmallMolecule
entity reference: Oxoglutaric acid

2-methyl-6-solanesyl-1,4-benzoquinol
type: SmallMolecule
cellular location: Chloroplast
entity reference: 2-methyl-6-solanesyl-1,4-benzoquinol

Reference/KEGG Compound C00082
type: UnificationXref
id: C00082
db: KEGG Compound

ChemicalStructure/PW C008136
type: ChemicalStructure
structure format: SMILES

Reference/BioCyc CPD-12829
type: UnificationXref
id: CPD-12829
db: BioCyc

ChemicalStructure/PW C000095
type: ChemicalStructure
structure format: SMILES
structure data: N[C@@H](CCC(O)=O)C(O)=O

Phytyl pyrophosphate
type: SmallMolecule
cellular location: Chloroplast
entity reference: Phytyl pyrophosphate

Reaction214007
type: BiochemicalReaction
participant stoichiometry: Compound/PW C008136 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C109091 Chloroplast/Stoichiometry/1.0
right: γ-Tocotrienol
spontaneous: false
left: 6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol
name: 6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol → γ-Tocotrienol
conversion direction: LEFT_TO_RIGHT

Reaction214006
type: BiochemicalReaction
participant stoichiometry: Compound/PW C000749 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C109091 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C109089 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000921 Chloroplast/Stoichiometry/1.0
right: 6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol
right: S-Adenosylhomocysteine
spontaneous: false
left: 6-Geranylgeranyl-2-methylbenzene-1,4-diol
left: S-Adenosylmethionine
name: 6-Geranylgeranyl-2-methylbenzene-1,4-diol + S-Adenosylmethionine → 6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol + S-Adenosylhomocysteine
conversion direction: LEFT_TO_RIGHT

Reference/PubChem-compound 6057
type: UnificationXref
id: 6057
db: PubChem-compound

Reference/ChEBI CHEBI 15379
type: UnificationXref
id: CHEBI:15379
db: ChEBI

Reaction214009
type: BiochemicalReaction
participant stoichiometry: Compound/PW C000095/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000558/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000134/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000103/Stoichiometry/1.0
right: L-Glutamic acid
right: 4-Hydroxyphenylpyruvic acid
spontaneous: false
left: Oxoglutaric acid
left: L-Tyrosine
name: L-Tyrosine + Oxoglutaric acid → 4-Hydroxyphenylpyruvic acid + L-Glutamic acid
conversion direction: LEFT_TO_RIGHT

Chloroplast
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0009507

Reaction214008
type: BiochemicalReaction
participant stoichiometry: Compound/PW C008136 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000749 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000921 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C002720 Chloroplast/Stoichiometry/1.0
right: S-Adenosylhomocysteine
right: α-Tocotrienol
spontaneous: false
left: γ-Tocotrienol
left: S-Adenosylmethionine
name: S-Adenosylmethionine + γ-Tocotrienol → S-Adenosylhomocysteine + α-Tocotrienol
conversion direction: LEFT_TO_RIGHT

Reference/BioCyc CPD-1125
type: UnificationXref
id: CPD-1125
db: BioCyc

2.5.1.115
type: BiochemicalReaction
participant stoichiometry: Compound/PW C104757 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C019799 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001316 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000084 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108886 Chloroplast/Stoichiometry/1.0
right: 2-Methyl-6-phytylhydroquinone
right: Diphosphoric acid
right: Carbon dioxide
spontaneous: false
EC number: 2.5.1.115
left: Phytyl pyrophosphate
left: Homogentisic acid
name: Homogentisic acid + Phytyl pyrophosphate → 2-Methyl-6-phytylhydroquinone + Carbon dioxide + Diphosphoric acid
conversion direction: LEFT_TO_RIGHT

Reaction214000
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057909 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C019799 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057910 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C109089 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000921 Chloroplast/Stoichiometry/1.0
right: plastoquinol-9
spontaneous: false
left: 6-Geranylgeranyl-2-methylbenzene-1,4-diol
left: 2-methyl-6-solanesyl-1,4-benzoquinol
left: 2-Methyl-6-phytylhydroquinone
left: S-Adenosylmethionine
name: 2-Methyl-6-phytylhydroquinone + 2-methyl-6-solanesyl-1,4-benzoquinol + 6-Geranylgeranyl-2-methylbenzene-1,4-diol + S-Adenosylmethionine → plastoquinol-9
conversion direction: LEFT_TO_RIGHT

5.5.1.24
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001149 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C109093 Chloroplast/Stoichiometry/1.0
right: γ-Tocopherol
spontaneous: false
EC number: 5.5.1.24
left: 2,3-Dimethyl-5-phytyl-1,4-hydroquinone
name: 2,3-Dimethyl-5-phytyl-1,4-hydroquinone → γ-Tocopherol
conversion direction: LEFT_TO_RIGHT

Reaction214002
type: BiochemicalReaction
participant stoichiometry: Compound/PW C019799 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000749 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000921 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C109093 Chloroplast/Stoichiometry/1.0
right: S-Adenosylhomocysteine
right: 2,3-Dimethyl-5-phytyl-1,4-hydroquinone
spontaneous: false
left: 2-Methyl-6-phytylhydroquinone
left: S-Adenosylmethionine
name: 2-Methyl-6-phytylhydroquinone + S-Adenosylmethionine → 2,3-Dimethyl-5-phytyl-1,4-hydroquinone + S-Adenosylhomocysteine
conversion direction: LEFT_TO_RIGHT

Compound/PW C109093 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 2,3-Dimethyl-5-phytyl-1,4-hydroquinone
stoichiometric coefficient: 1.0

Reaction214005
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001316 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C002145 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C109089 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000084 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108886 Chloroplast/Stoichiometry/1.0
right: 6-Geranylgeranyl-2-methylbenzene-1,4-diol
right: Diphosphoric acid
right: Carbon dioxide
spontaneous: false
left: Geranylgeranyl-PP
left: Homogentisic acid
name: Geranylgeranyl-PP + Homogentisic acid → 6-Geranylgeranyl-2-methylbenzene-1,4-diol + Carbon dioxide + Diphosphoric acid
conversion direction: LEFT_TO_RIGHT

Reference/KEGG Compound C01179
type: UnificationXref
id: C01179
db: KEGG Compound

Reaction214004
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001261 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000749 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000921 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001149 Chloroplast/Stoichiometry/1.0
right: α-Tocopherol
right: S-Adenosylhomocysteine
spontaneous: false
left: S-Adenosylmethionine
left: γ-Tocopherol
name: S-Adenosylmethionine + γ-Tocopherol → S-Adenosylhomocysteine + α-Tocopherol
conversion direction: LEFT_TO_RIGHT

Compound/PW C019799 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 2-Methyl-6-phytylhydroquinone
stoichiometric coefficient: 1.0

Oxygen
type: SmallMolecule
cellular location: Cytosol
entity reference: Oxygen

Reference/ChEBI CHEBI 29888
type: UnificationXref
id: CHEBI:29888
db: ChEBI

ChemicalStructure/PW C002720
type: ChemicalStructure
structure format: SMILES

γ-Tocotrienol
type: SmallMolecule
cellular location: Chloroplast
entity reference: γ-Tocotrienol

Reference/PubChem-compound 280
type: UnificationXref
id: 280
db: PubChem-compound

ChemicalStructure/PW C109089
type: ChemicalStructure
structure format: SMILES

Compound/PW C001316 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Carbon dioxide
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0012958
type: UnificationXref
id: HMDB0012958
db: HMDB

Homogentisic acid
type: SmallMolecule
cellular location: Cytosol
entity reference: Homogentisic acid

ChemicalStructure/PW C104757
type: ChemicalStructure
structure format: SMILES

ChemicalStructure/PW C104756
type: ChemicalStructure
structure format: SMILES

Unknown
type: Protein
entity reference: Unknown

Geranylgeranyl-PP
type: SmallMolecule
cellular location: Chloroplast
entity reference: Geranylgeranyl-PP

Reference/CAS 156-39-8
type: UnificationXref
id: 156-39-8
db: CAS

Reference/CAS 2466-09-3
type: UnificationXref
id: 2466-09-3
db: CAS

Reference/ChemSpider 759
type: UnificationXref
id: 759
db: ChemSpider

Reference/KEGG Compound C05427
type: UnificationXref
id: C05427
db: KEGG Compound

ChemicalStructure/PW C000749
type: ChemicalStructure
structure format: SMILES

ChemicalStructure/PW C109091
type: ChemicalStructure
structure format: SMILES

2,3-Dimethyl-5-phytyl-1,4-hydroquinone
type: SmallMolecule
cellular location: Chloroplast
entity reference: 2,3-Dimethyl-5-phytyl-1,4-hydroquinone

Homogentisic acid
type: SmallMolecule
cellular location: Chloroplast
entity reference: Homogentisic acid

Reference/PubChem-compound 6440941
type: UnificationXref
id: 6440941
db: PubChem-compound

ChemicalStructure/PW C109093
type: ChemicalStructure
structure format: SMILES

Reference/PubChem-compound 25246222
type: UnificationXref
id: 25246222
db: PubChem-compound

Reference/ChemSpider 14265
type: UnificationXref
id: 14265
db: ChemSpider

6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol
type: SmallMolecule
cellular location: Chloroplast
entity reference: 6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol

Reference/ChemSpider 14266
type: UnificationXref
id: 14266
db: ChemSpider

Compound/PW C000558 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: 4-Hydroxyphenylpyruvic acid
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 17895
type: UnificationXref
id: CHEBI:17895
db: ChEBI

Reference/KEGG Compound C16695
type: UnificationXref
id: C16695
db: KEGG Compound

Reference/PubChem-compound 977
type: UnificationXref
id: 977
db: PubChem-compound

Compound/PW C109091 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 6-geranylgeranyl-2,3-dimethylbenzene-1,4-diol
stoichiometric coefficient: 1.0

Reference/KEGG Compound C14153
type: UnificationXref
id: C14153
db: KEGG Compound

Reference/ChEBI CHEBI 75837
type: UnificationXref
id: CHEBI:75837
db: ChEBI

Compound/PW C001316 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: Carbon dioxide
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0001967
type: UnificationXref
id: HMDB0001967
db: HMDB

Reference/ChEBI CHEBI 16680
type: UnificationXref
id: CHEBI:16680
db: ChEBI

L-Tyrosine
type: SmallMolecule
entity reference: L-Tyrosine

Reference/KEGG Compound C00544
type: UnificationXref
id: C00544
db: KEGG Compound

Reference/PubChem-compound 24762165
type: UnificationXref
id: 24762165
db: PubChem-compound

Compound/PW C001316 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Carbon dioxide
stoichiometric coefficient: 2.0

ChemicalStructure/PW C002145
type: ChemicalStructure
structure format: SMILES

plastoquinol-9
type: SmallMolecule
cellular location: Chloroplast
entity reference: plastoquinol-9

Reference/PubChem-compound 979
type: UnificationXref
id: 979
db: PubChem-compound

Reference/PubChem-compound 47205203
type: UnificationXref
id: 47205203
db: PubChem-compound

ChemicalStructure/PW C000084
type: ChemicalStructure
structure format: SMILES
structure data: OC(=O)CC1=C(O)C=CC(O)=C1

Compound/PW C002720 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: α-Tocotrienol
stoichiometric coefficient: 1.0