FMNH2 + Oxygen + trans-Cinnamic acid → FMN + Hydrogen Ion + Water + trans-4-coumarate
L-Phenylalanine (→) Transport: Arabidopsis thaliana, Cell, Chloroplast to Arabidopsis thaliana, Cell, Cytosol
Oxoglutaric acid + Oxygen + trans-4-coumaroyl-CoA → Carbon dioxide + Succinic acid + trans-caffeate
S-adenosyl-L-methionine zwitterion + trans-caffeate → Hydrogen Ion + S-adenosyl-L-homocysteine zwitterion + ferulic acid
Adenosine triphosphate + Coenzyme A + trans-4-coumarate → Adenosine monophosphate + diphosphate(3−) + trans-4-coumaroyl-CoA
FMNH2 + Fraxetin + Oxygen → FMN + Hydrogen Ion + Sideretin + Water
Oxoglutaric acid + Oxygen + Scopoletin → Carbon dioxide + Fraxetin + Succinic acid
Esculetin + S-adenosyl-L-methionine zwitterion → Hydrogen Ion + S-adenosyl-L-homocysteine zwitterion + Scopoletin
trans-6-hydroxyferuloyl-CoA → Scopoletin
L-Phenylalanine → Ammonium + trans-Cinnamic acid
Oxoglutaric acid + Oxygen + trans-feruloyl-CoA(4−) → Carbon dioxide + Succinic acid + trans-6-hydroxyferuloyl-CoA
Adenosine triphosphate + Coenzyme A + trans-caffeate → Adenosine monophosphate + diphosphate(3−) + trans-caffeoyl-CoA
Adenosine triphosphate + Coenzyme A + ferulic acid → Adenosine monophosphate + diphosphate(3−) + trans-feruloyl-CoA(4−)