Reference/ChEBI CHEBI 16015
type: UnificationXref
id: CHEBI:16015
db: ChEBI

tryptophan aminotransferase
type: Protein
cellular location: Cytosol
entity reference: tryptophan aminotransferase

Reference/ChemSpider 30572
type: UnificationXref
id: 30572
db: ChemSpider

Compound/PW C000749 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: S-Adenosylhomocysteine
stoichiometric coefficient: 1.0

Reference/TAXONOMY 3702
type: UnificationXref
id: 3702
db: TAXONOMY

Compound/PW C000170 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Pyrophosphate
stoichiometric coefficient: 1.0

ReactionCatalysis37680
type: Catalysis
controller: 4-hydroxyphenylpyruvic acid dioxygenase
controlled: 1.13.11.27
control type: ACTIVATION

ReactionCatalysis37682
type: Catalysis
controller: 2-methyl-6-phytyl-1,4-hydroquinone methyltransferase
controlled: 2.1.1.295
control type: ACTIVATION

ReactionCatalysis37681
type: Catalysis
controller: homogentisate solanesyltransferase
controlled: 2.5.1.117
control type: ACTIVATION

Reference/BioCyc P-HYDROXY-PHENYLPYRUVATE
type: UnificationXref
id: P-HYDROXY-PHENYLPYRUVATE
db: BioCyc

Reference/CAS 6699-20-3
type: UnificationXref
id: 6699-20-3
db: CAS

Compound/PW C000103 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: L-Tyrosine
stoichiometric coefficient: 1.0

L-Tyrosine
type: SmallMolecule
cellular location: Cytosol
entity reference: L-Tyrosine
name: SubPathwayOutput

Pyrophosphate
type: SmallMolecule
cellular location: Chloroplast
entity reference: Pyrophosphate

Reference/ChemSpider 50
type: UnificationXref
id: 50
db: ChemSpider

Reference/HMDB HMDB0001185
type: UnificationXref
id: HMDB0001185
db: HMDB

Reference/UniProt Q8S948
type: UnificationXref
id: Q8S948
db: UniProt

Hydrogen Ion
type: SmallMolecule
cellular location: Chloroplast
entity reference: Hydrogen Ion

ReactionCatalysis37679
type: Catalysis
controller: solanesyl diphosphate synthase 1
controlled: 2.5.1.85
control type: ACTIVATION

ReactionCatalysis37678
type: Catalysis
controller: tryptophan aminotransferase
controlled: 2.6.1.5
control type: ACTIVATION

Reference/ChemSpider 5833
type: UnificationXref
id: 5833
db: ChemSpider

Compound/PW C001065 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: Oxygen
stoichiometric coefficient: 1.0

Compound/PW C001598 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: Solanesyl-PP
stoichiometric coefficient: 1.0

Compound/PW C040034 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Hydrogen Ion
stoichiometric coefficient: 1.0

ChemicalStructure/PW C000103
type: ChemicalStructure
structure format: SMILES
structure data: N[C@@H](CC1=CC=C(O)C=C1)C(O)=O

Reference/PubChem-compound 51
type: UnificationXref
id: 51
db: PubChem-compound

Reference/CAS 146340-00-3
type: UnificationXref
id: 146340-00-3
db: CAS

Reference/ChemSpider 559142
type: UnificationXref
id: 559142
db: ChemSpider

Reference/KEGG Compound C17438
type: UnificationXref
id: C17438
db: KEGG Compound

ChemicalStructure/PW C057909
type: ChemicalStructure
structure format: SMILES

solanesyl diphosphate synthase 1
type: ProteinReference
xref: Reference/UniProt Q8S948
organism: Arabidopsis thaliana

tryptophan aminotransferase
type: ProteinReference
xref: Reference/UniProt Q9S7N2
organism: Arabidopsis thaliana

S-Adenosylmethionine
type: SmallMoleculeReference
xref: Reference/PubChem-compound 24762165
xref: Reference/KEGG Compound C00019
xref: Reference/ChemSpider 31983
xref: Reference/ChEBI CHEBI 15414
xref: Reference/CAS 485-80-3
xref: Reference/BioCyc S-ADENOSYLMETHIONINE
xref: Reference/HMDB HMDB0001185
chemical formula: C15H23N6O5S
molecular weight: 399.14505
structure: ChemicalStructure/PW C000921

Reference/KEGG Compound C17570
type: UnificationXref
id: C17570
db: KEGG Compound

Reference/ChEBI CHEBI 44747
type: UnificationXref
id: CHEBI:44747
db: ChEBI

Reference/PubChem-compound 1038
type: UnificationXref
id: 1038
db: PubChem-compound

Reference/ChemSpider 954
type: UnificationXref
id: 954
db: ChemSpider

Reference/ChemSpider 952
type: UnificationXref
id: 952
db: ChemSpider

Reference/GENE ONTOLOGY GO 0005829
type: UnificationXref
id: GO:0005829
db: GENE ONTOLOGY

4-hydroxyphenylpyruvic acid dioxygenase
type: Complex
component stoichiometry: Protein/11555 Cytosol/Stoichiometry/2.0
cellular location: Cytosol
component: 4-hydroxyphenylpyruvate dioxygenase

Compound/PW C001598 Endoplasmic Reticulum/Stoichiometry/1.0
type: Stoichiometry
physical entity: Solanesyl-PP
stoichiometric coefficient: 1.0

ChemicalStructure/PW C057910
type: ChemicalStructure
structure format: SMILES

Reference/ChemSpider 274
type: UnificationXref
id: 274
db: ChemSpider

Reference/GENE ONTOLOGY GO 0009507
type: UnificationXref
id: GO:0009507
db: GENE ONTOLOGY

Compound/PW C000921 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: S-Adenosylmethionine
stoichiometric coefficient: 1.0

Oxoglutaric acid
type: SmallMoleculeReference
xref: Reference/CAS 328-50-7
xref: Reference/PubChem-compound 51
xref: Reference/BioCyc 2-KETOGLUTARATE
xref: Reference/HMDB HMDB0000208
xref: Reference/ChEBI CHEBI 30915
xref: Reference/KEGG Compound C00026
xref: Reference/ChemSpider 50
chemical formula: C5H6O5
molecular weight: 146.02153
structure: ChemicalStructure/PW C000134

Reference/BioCyc TYR
type: UnificationXref
id: TYR
db: BioCyc

Reference/BioCyc GERANYLGERANYL-PP
type: UnificationXref
id: GERANYLGERANYL-PP
db: BioCyc

homogentisate solanesyltransferase
type: ProteinReference
xref: Reference/UniProt Q1ACB3
organism: Arabidopsis thaliana

4-hydroxyphenylpyruvate dioxygenase
type: ProteinReference
xref: Reference/UniProt P93836
organism: Arabidopsis thaliana

solanesyl diphosphate transporter
type: ProteinReference
xref: Reference/UniProt Z0Z000

2-methyl-6-phytyl-1,4-hydroquinone methyltransferase
type: ProteinReference
xref: Reference/UniProt Q9LY74
organism: Arabidopsis thaliana

Plastoquinol-9 Biosynthesis
type: Pathway
pathway order: PathwayEnzymeReaction/224396
pathway order: PathwayEnzymeReaction/224395
pathway order: PathwayTransport/224394
pathway order: PathwayEnzymeReaction/224393
pathway order: PathwayEnzymeReaction/224392
pathway order: PathwayEnzymeReaction/224391
pathway order: PathwaySubPathway/4457
pathway component: ReactionCatalysis37679
pathway component: ReactionCatalysis37678
pathway component: 2.6.1.5
pathway component: ReactionCatalysis37680
pathway component: 2.5.1.85
pathway component: L-tyrosine Biosynthesis
pathway component: 1.13.11.27
pathway component: ReactionCatalysis37682
pathway component: 2.5.1.117
pathway component: ReactionCatalysis37681
pathway component: 2.1.1.295
pathway component: TransportCatalysis797
pathway component: Transport897
xref: Reference/SMPDB SMP0012043
xref: Reference/PathWhiz PW012904
organism: Arabidopsis thaliana

Reference/BioCyc ADENOSYL-HOMO-CYS
type: UnificationXref
id: ADENOSYL-HOMO-CYS
db: BioCyc

ChemicalStructure/PW C000558
type: ChemicalStructure
structure format: SMILES
structure data: OC(=O)C(=O)CC1=CC=C(O)C=C1

Reference/CAS 485-80-3
type: UnificationXref
id: 485-80-3
db: CAS

Isopentenyl pyrophosphate
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: Isopentenyl pyrophosphate

Reference/ChemSpider 1010
type: UnificationXref
id: 1010
db: ChemSpider

Solanesyl-PP
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0002367
xref: Reference/CAS 146340-00-3
xref: Reference/ChemSpider 13628341
xref: Reference/KEGG Compound C17438
xref: Reference/PubChem-compound 21252289
chemical formula: C45H76O7P2
molecular weight: 790.50665
structure: ChemicalStructure/PW C001598

Reference/BioCyc PPI
type: UnificationXref
id: PPI
db: BioCyc

Reference/HMDB HMDB0004486
type: UnificationXref
id: HMDB0004486
db: HMDB

Reference/HMDB HMDB0000208
type: UnificationXref
id: HMDB0000208
db: HMDB

Reference/KEGG Compound C00353
type: UnificationXref
id: C00353
db: KEGG Compound

ChemicalStructure/PW C000921
type: ChemicalStructure
structure format: SMILES

Reference/CAS 979-92-0
type: UnificationXref
id: 979-92-0
db: CAS

Carbon dioxide
type: SmallMolecule
cellular location: Cytosol
entity reference: Carbon dioxide

Isopentenyl pyrophosphate
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00129
xref: Reference/ChemSpider 1158
xref: Reference/PubChem-compound 1195
xref: Reference/CAS 358-71-4
xref: Reference/HMDB HMDB0001347
xref: Reference/ChEBI CHEBI 16584
chemical formula: C5H12O7P2
molecular weight: 246.00583
structure: ChemicalStructure/PW C001039

Cytosol
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0005829

Reference/BioCyc CPD-6641
type: UnificationXref
id: CPD-6641
db: BioCyc

Carbon dioxide
type: SmallMolecule
cellular location: Chloroplast
entity reference: Carbon dioxide

S-Adenosylhomocysteine
type: SmallMoleculeReference
xref: Reference/PubChem-compound 25246222
xref: Reference/ChemSpider 388301
xref: Reference/BioCyc ADENOSYL-HOMO-CYS
xref: Reference/CAS 979-92-0
xref: Reference/KEGG Compound C00021
xref: Reference/ChEBI CHEBI 16680
xref: Reference/HMDB HMDB0000939
chemical formula: C14H20N6O5S
molecular weight: 384.12158
structure: ChemicalStructure/PW C000749

plastoquinol-9
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 28026
xref: Reference/ChemSpider 4945177
xref: Reference/KEGG Compound C16695
xref: Reference/BioCyc CPD-12829
xref: Reference/PubChem-compound 6440941
chemical formula: C53H82O2
molecular weight: 750.6315
structure: ChemicalStructure/PW C057910

ChemicalStructure/PW C000134
type: ChemicalStructure
structure format: SMILES
structure data: OC(=O)CCC(=O)C(O)=O

Reference/ChEBI CHEBI 30915
type: UnificationXref
id: CHEBI:30915
db: ChEBI

Reference/CAS 124-38-9
type: UnificationXref
id: 124-38-9
db: CAS

Compound/PW C000084 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: Homogentisic acid
stoichiometric coefficient: 1.0

Reference/KEGG Compound C00129
type: UnificationXref
id: C00129
db: KEGG Compound

Reference/ChemSpider 1158
type: UnificationXref
id: 1158
db: ChemSpider

Reference/KEGG Compound C00007
type: UnificationXref
id: C00007
db: KEGG Compound

Reference/CAS 451-13-8
type: UnificationXref
id: 451-13-8
db: CAS

Reference/ChEBI CHEBI 15414
type: UnificationXref
id: CHEBI:15414
db: ChEBI

Reference/PubChem-compound 447277
type: UnificationXref
id: 447277
db: PubChem-compound

Reference/ChEBI CHEBI 18361
type: UnificationXref
id: CHEBI:18361
db: ChEBI

Compound/PW C000170 Endoplasmic Reticulum/Stoichiometry/5.0
type: Stoichiometry
physical entity: Pyrophosphate
stoichiometric coefficient: 5.0

Geranylgeranyl-PP
type: SmallMoleculeReference
xref: Reference/CAS 6699-20-3
xref: Reference/ChemSpider 394418
xref: Reference/PubChem-compound 447277
xref: Reference/KEGG Compound C00353
xref: Reference/BioCyc GERANYLGERANYL-PP
xref: Reference/ChEBI CHEBI 48861
xref: Reference/HMDB HMDB0004486
chemical formula: C20H36O7P2
molecular weight: 450.19363
structure: ChemicalStructure/PW C002145

ChemicalStructure/PW C001598
type: ChemicalStructure
structure format: SMILES
structure data: CC(C)=CCC\C(C)=C\CC\C(C)=C\CC\C(C)=C/CC\C(C)=C/CC\C(C)=C/CC\C(C)=C/CC\C(C)=C/CC\C(C)=C/COP(O)(=O)OP(O)(O)=O

Reference/UniProt P93836
type: UnificationXref
id: P93836
db: UniProt

Reference/BioCyc GLT
type: UnificationXref
id: GLT
db: BioCyc

Reference/ChEBI CHEBI 48861
type: UnificationXref
id: CHEBI:48861
db: ChEBI

Homogentisic acid
type: SmallMoleculeReference
xref: Reference/CAS 451-13-8
xref: Reference/ChEBI CHEBI 44747
xref: Reference/ChemSpider 759
xref: Reference/HMDB HMDB0000130
xref: Reference/KEGG Compound C00544
xref: Reference/PubChem-compound 780
chemical formula: C8H8O4
molecular weight: 168.04225
structure: ChemicalStructure/PW C000084

Reference/KEGG Compound C00019
type: UnificationXref
id: C00019
db: KEGG Compound

Oxoglutaric acid
type: SmallMolecule
cellular location: Cytosol
entity reference: Oxoglutaric acid

Reference/ChemSpider 394418
type: UnificationXref
id: 394418
db: ChemSpider

Compound/PW C001598 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Solanesyl-PP
stoichiometric coefficient: 1.0

Reference/KEGG Compound C00011
type: UnificationXref
id: C00011
db: KEGG Compound

ChemicalStructure/PW C001316
type: ChemicalStructure
structure format: SMILES
structure data: O=C=O

Reference/UniProt Q9LY74
type: UnificationXref
id: Q9LY74
db: UniProt

Reference/BioCyc S-ADENOSYLMETHIONINE
type: UnificationXref
id: S-ADENOSYLMETHIONINE
db: BioCyc

Reference/KEGG Compound C00013
type: UnificationXref
id: C00013
db: KEGG Compound

Reference/ChEBI CHEBI 28026
type: UnificationXref
id: CHEBI:28026
db: ChEBI

Reference/ChemSpider 4945177
type: UnificationXref
id: 4945177
db: ChemSpider

Pyrophosphate
type: SmallMoleculeReference
xref: Reference/PubChem-compound 644102
xref: Reference/BioCyc PPI
xref: Reference/ChemSpider 559142
xref: Reference/ChEBI CHEBI 18361
xref: Reference/HMDB HMDB0000250
xref: Reference/CAS 14000-31-8
xref: Reference/KEGG Compound C00013
chemical formula: H4O7P2
molecular weight: 177.94322
structure: ChemicalStructure/PW C000170

Compound/PW C057910 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: plastoquinol-9
stoichiometric coefficient: 1.0

Pyrophosphate
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: Pyrophosphate

Hydrogen Ion
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00080
xref: Reference/ChEBI CHEBI 15378
xref: Reference/HMDB HMDB0059597
xref: Reference/PubChem-compound 1038
xref: Reference/ChemSpider 1010
chemical formula: H
molecular weight: 1.007825
structure: ChemicalStructure/PW C040034

Reference/ChemSpider 388301
type: UnificationXref
id: 388301
db: ChemSpider

Reference/ChEBI CHEBI 15999
type: UnificationXref
id: CHEBI:15999
db: ChEBI

S-Adenosylmethionine
type: SmallMolecule
cellular location: Chloroplast
entity reference: S-Adenosylmethionine

Reference/KEGG Compound C00021
type: UnificationXref
id: C00021
db: KEGG Compound

Reference/SMPDB SMP0012043
type: UnificationXref
id: SMP0012043
db: SMPDB

L-Glutamic acid
type: SmallMolecule
cellular location: Cytosol
entity reference: L-Glutamic acid

Reference/KEGG Compound C00026
type: UnificationXref
id: C00026
db: KEGG Compound

Reference/KEGG Compound C00025
type: UnificationXref
id: C00025
db: KEGG Compound

Reference/UniProt Q1ACB3
type: UnificationXref
id: Q1ACB3
db: UniProt

Endoplasmic Reticulum
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0005783

S-Adenosylhomocysteine
type: SmallMolecule
cellular location: Chloroplast
entity reference: S-Adenosylhomocysteine

Reference/CAS 328-50-7
type: UnificationXref
id: 328-50-7
db: CAS

Geranylgeranyl-PP
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: Geranylgeranyl-PP

Reference/HMDB HMDB0001347
type: UnificationXref
id: HMDB0001347
db: HMDB

Reference/HMDB HMDB0000130
type: UnificationXref
id: HMDB0000130
db: HMDB

Compound/PW C002145 Endoplasmic Reticulum/Stoichiometry/1.0
type: Stoichiometry
physical entity: Geranylgeranyl-PP
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0000250
type: UnificationXref
id: HMDB0000250
db: HMDB

ChemicalStructure/PW C000170
type: ChemicalStructure
structure format: SMILES
structure data: OP(O)(=O)OP(O)(O)=O

Reference/PubChem-compound 21252289
type: UnificationXref
id: 21252289
db: PubChem-compound

Reference/CAS 14000-31-8
type: UnificationXref
id: 14000-31-8
db: CAS

Compound/PW C057909 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 2-methyl-6-solanesyl-1,4-benzoquinol
stoichiometric coefficient: 1.0

4-Hydroxyphenylpyruvic acid
type: SmallMoleculeReference
xref: Reference/BioCyc P-HYDROXY-PHENYLPYRUVATE
xref: Reference/CAS 156-39-8
xref: Reference/ChEBI CHEBI 15999
xref: Reference/PubChem-compound 979
xref: Reference/HMDB HMDB0000707
xref: Reference/ChemSpider 954
xref: Reference/KEGG Compound C01179
chemical formula: C9H8O4
molecular weight: 180.04225
structure: ChemicalStructure/PW C000558

2-methyl-6-phytyl-1,4-hydroquinone methyltransferase
type: Protein
cellular location: Chloroplast
entity reference: 2-methyl-6-phytyl-1,4-hydroquinone methyltransferase

L-tyrosine Biosynthesis
type: Pathway
pathway order: SubPathwayInteractionSteps/SubPathway4457
pathway component: SubPathwayInteraction4457
name: SubPathway

homogentisate solanesyltransferase
type: Protein
cellular location: Chloroplast
entity reference: homogentisate solanesyltransferase

Reference/HMDB HMDB0000939
type: UnificationXref
id: HMDB0000939
db: HMDB

Compound/PW C000134 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: Oxoglutaric acid
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0000148
type: UnificationXref
id: HMDB0000148
db: HMDB

Reference/BioCyc 2-METHYL-6-SOLANYL-14-BENZOQUINONE
type: UnificationXref
id: 2-METHYL-6-SOLANYL-14-BENZOQUINONE
db: BioCyc

solanesyl diphosphate synthase 1
type: Protein
cellular location: Endoplasmic Reticulum
entity reference: solanesyl diphosphate synthase 1

Arabidopsis thaliana
type: BioSource
xref: Reference/TAXONOMY 3702

SubPathwayInteraction4457
type: Interaction
name: SubPathway4457Reaction
name: SubPathwayReaction
participant: L-Tyrosine

Reference/HMDB HMDB0000707
type: UnificationXref
id: HMDB0000707
db: HMDB

Reference/PubChem-compound 780
type: UnificationXref
id: 780
db: PubChem-compound

Reference/PathWhiz PW012904
type: UnificationXref
id: PW012904
db: PathWhiz

Reference/PubChem-compound 44237185
type: UnificationXref
id: 44237185
db: PubChem-compound

Reference/ChEBI CHEBI 75402
type: UnificationXref
id: CHEBI:75402
db: ChEBI

4-Hydroxyphenylpyruvic acid
type: SmallMolecule
cellular location: Cytosol
entity reference: 4-Hydroxyphenylpyruvic acid

Reference/HMDB HMDB0000158
type: UnificationXref
id: HMDB0000158
db: HMDB

Oxygen
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0001377
xref: Reference/ChemSpider 952
xref: Reference/KEGG Compound C00007
xref: Reference/ChEBI CHEBI 15379
xref: Reference/PubChem-compound 977
xref: Reference/BioCyc CPD-6641
xref: Reference/CAS 7782-44-7
chemical formula: O2
molecular weight: 31.98983
structure: ChemicalStructure/PW C001065

Reference/CAS 56-86-0
type: UnificationXref
id: 56-86-0
db: CAS

Solanesyl-PP
type: SmallMolecule
cellular location: Chloroplast
entity reference: Solanesyl-PP

Reference/GENE ONTOLOGY GO 0005783
type: UnificationXref
id: GO:0005783
db: GENE ONTOLOGY

Transport897
type: Transport
participant stoichiometry: Compound/PW C001598 Endoplasmic Reticulum/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001598 Cytosol/Stoichiometry/1.0
right: Solanesyl-PP
spontaneous: false
left: Solanesyl-PP
name: Solanesyl-PP (→) Transport: Arabidopsis thaliana, Cell, Endoplasmic Reticulum to Arabidopsis thaliana, Cell, Cytosol
conversion direction: LEFT_TO_RIGHT

L-Glutamic acid
type: SmallMoleculeReference
xref: Reference/PubChem-compound 33032
xref: Reference/ChEBI CHEBI 16015
xref: Reference/ChemSpider 30572
xref: Reference/HMDB HMDB0000148
xref: Reference/CAS 56-86-0
xref: Reference/BioCyc GLT
xref: Reference/KEGG Compound C00025
chemical formula: C5H9NO4
molecular weight: 147.05316
structure: ChemicalStructure/PW C000095

Reference/PubChem-compound 33032
type: UnificationXref
id: 33032
db: PubChem-compound

Reference/CAS 60-18-4
type: UnificationXref
id: 60-18-4
db: CAS

solanesyl diphosphate transporter
type: Protein
entity reference: solanesyl diphosphate transporter

Compound/PW C000095 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: L-Glutamic acid
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 16526
type: UnificationXref
id: CHEBI:16526
db: ChEBI

Compound/PW C000084 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Homogentisic acid
stoichiometric coefficient: 1.0

Reference/CAS 7782-44-7
type: UnificationXref
id: 7782-44-7
db: CAS

Reference/HMDB HMDB0001377
type: UnificationXref
id: HMDB0001377
db: HMDB

Reference/UniProt Q9S7N2
type: UnificationXref
id: Q9S7N2
db: UniProt

2-methyl-6-solanesyl-1,4-benzoquinol
type: SmallMoleculeReference
xref: Reference/BioCyc 2-METHYL-6-SOLANYL-14-BENZOQUINONE
xref: Reference/KEGG Compound C17570
xref: Reference/PubChem-compound 44237185
xref: Reference/ChEBI CHEBI 75402
chemical formula: C52H80O2
molecular weight: 736.61584
structure: ChemicalStructure/PW C057909

Reference/ChemSpider 31983
type: UnificationXref
id: 31983
db: ChemSpider

Reference/CAS 358-71-4
type: UnificationXref
id: 358-71-4
db: CAS

Reference/BioCyc 2-KETOGLUTARATE
type: UnificationXref
id: 2-KETOGLUTARATE
db: BioCyc

L-Tyrosine
type: SmallMoleculeReference
xref: Reference/CAS 60-18-4
xref: Reference/PubChem-compound 6057
xref: Reference/HMDB HMDB0000158
xref: Reference/ChEBI CHEBI 17895
xref: Reference/KEGG Compound C00082
xref: Reference/ChemSpider 5833
xref: Reference/BioCyc TYR
chemical formula: C9H11NO3
molecular weight: 181.0739
structure: ChemicalStructure/PW C000103

Reference/ChemSpider 13628341
type: UnificationXref
id: 13628341
db: ChemSpider

Carbon dioxide
type: SmallMoleculeReference
xref: Reference/PubChem-compound 280
xref: Reference/ChEBI CHEBI 16526
xref: Reference/ChemSpider 274
xref: Reference/HMDB HMDB0001967
xref: Reference/CAS 124-38-9
xref: Reference/KEGG Compound C00011
chemical formula: CO2
molecular weight: 43.98983
structure: ChemicalStructure/PW C001316

Reference/KEGG Compound C00080
type: UnificationXref
id: C00080
db: KEGG Compound

ChemicalStructure/PW C001065
type: ChemicalStructure
structure format: SMILES
structure data: O=O

2-methyl-6-solanesyl-1,4-benzoquinol
type: SmallMolecule
cellular location: Chloroplast
entity reference: 2-methyl-6-solanesyl-1,4-benzoquinol

Reference/KEGG Compound C00082
type: UnificationXref
id: C00082
db: KEGG Compound

4-hydroxyphenylpyruvate dioxygenase
type: Protein
cellular location: Cytosol
entity reference: 4-hydroxyphenylpyruvate dioxygenase

Reference/BioCyc CPD-12829
type: UnificationXref
id: CPD-12829
db: BioCyc

TransportCatalysis797
type: Catalysis
controller: solanesyl diphosphate transporter
controlled: Transport897
control type: ACTIVATION

ChemicalStructure/PW C000095
type: ChemicalStructure
structure format: SMILES
structure data: N[C@@H](CCC(O)=O)C(O)=O

Reference/PubChem-compound 6057
type: UnificationXref
id: 6057
db: PubChem-compound

Reference/ChEBI CHEBI 15379
type: UnificationXref
id: CHEBI:15379
db: ChEBI

Chloroplast
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0009507

Reference/ChEBI CHEBI 15378
type: UnificationXref
id: CHEBI:15378
db: ChEBI

ChemicalStructure/PW C040034
type: ChemicalStructure
structure format: SMILES
structure data: [H+]

Reference/KEGG Compound C01179
type: UnificationXref
id: C01179
db: KEGG Compound

Reference/ChEBI CHEBI 16584
type: UnificationXref
id: CHEBI:16584
db: ChEBI

Oxygen
type: SmallMolecule
cellular location: Cytosol
entity reference: Oxygen

Reference/HMDB HMDB0002367
type: UnificationXref
id: HMDB0002367
db: HMDB

Solanesyl-PP
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: Solanesyl-PP

Reference/PubChem-compound 280
type: UnificationXref
id: 280
db: PubChem-compound

Compound/PW C001316 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Carbon dioxide
stoichiometric coefficient: 1.0

Homogentisic acid
type: SmallMolecule
cellular location: Cytosol
entity reference: Homogentisic acid

Reference/CAS 156-39-8
type: UnificationXref
id: 156-39-8
db: CAS

Reference/PubChem-compound 1195
type: UnificationXref
id: 1195
db: PubChem-compound

Reference/PubChem-compound 644102
type: UnificationXref
id: 644102
db: PubChem-compound

Reference/ChemSpider 759
type: UnificationXref
id: 759
db: ChemSpider

ChemicalStructure/PW C001039
type: ChemicalStructure
structure format: SMILES
structure data: CC(=C)CCOP(O)(=O)OP(O)(O)=O

ChemicalStructure/PW C000749
type: ChemicalStructure
structure format: SMILES

Homogentisic acid
type: SmallMolecule
cellular location: Chloroplast
entity reference: Homogentisic acid

Reference/PubChem-compound 6440941
type: UnificationXref
id: 6440941
db: PubChem-compound

Reference/PubChem-compound 25246222
type: UnificationXref
id: 25246222
db: PubChem-compound

Reference/UniProt Z0Z000
type: UnificationXref
id: Z0Z000
db: UniProt

Compound/PW C000558 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: 4-Hydroxyphenylpyruvic acid
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 17895
type: UnificationXref
id: CHEBI:17895
db: ChEBI

Compound/PW C001039 Endoplasmic Reticulum/Stoichiometry/5.0
type: Stoichiometry
physical entity: Isopentenyl pyrophosphate
stoichiometric coefficient: 5.0

Reference/KEGG Compound C16695
type: UnificationXref
id: C16695
db: KEGG Compound

Reference/PubChem-compound 977
type: UnificationXref
id: 977
db: PubChem-compound

Reference/HMDB HMDB0059597
type: UnificationXref
id: HMDB0059597
db: HMDB

Compound/PW C001316 Cytosol/Stoichiometry/1.0
type: Stoichiometry
physical entity: Carbon dioxide
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0001967
type: UnificationXref
id: HMDB0001967
db: HMDB

Reference/ChEBI CHEBI 16680
type: UnificationXref
id: CHEBI:16680
db: ChEBI

Solanesyl-PP
type: SmallMolecule
cellular location: Cytosol
entity reference: Solanesyl-PP

2.6.1.5
type: BiochemicalReaction
participant stoichiometry: Compound/PW C000103 Cytosol/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000134 Cytosol/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000095 Cytosol/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000558 Cytosol/Stoichiometry/1.0
right: 4-Hydroxyphenylpyruvic acid
right: L-Glutamic acid
spontaneous: false
EC number: 2.6.1.5
left: Oxoglutaric acid
left: L-Tyrosine
name: L-Tyrosine + Oxoglutaric acid ↔ 4-Hydroxyphenylpyruvic acid + L-Glutamic acid
conversion direction: REVERSIBLE

Reference/KEGG Compound C00544
type: UnificationXref
id: C00544
db: KEGG Compound

2.5.1.85
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001039 Endoplasmic Reticulum/Stoichiometry/5.0
participant stoichiometry: Compound/PW C001598 Endoplasmic Reticulum/Stoichiometry/1.0
participant stoichiometry: Compound/PW C002145 Endoplasmic Reticulum/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000170 Endoplasmic Reticulum/Stoichiometry/5.0
right: Solanesyl-PP
right: Pyrophosphate
spontaneous: false
EC number: 2.5.1.85
left: Geranylgeranyl-PP
left: Isopentenyl pyrophosphate
name: Geranylgeranyl-PP + 5 Isopentenyl pyrophosphate → 5 Pyrophosphate + Solanesyl-PP
conversion direction: LEFT_TO_RIGHT

1.13.11.27
type: BiochemicalReaction
participant stoichiometry: Compound/PW C000084 Cytosol/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001316 Cytosol/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001065 Cytosol/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000558 Cytosol/Stoichiometry/1.0
right: Carbon dioxide
right: Homogentisic acid
spontaneous: false
EC number: 1.13.11.27
left: 4-Hydroxyphenylpyruvic acid
left: Oxygen
name: 4-Hydroxyphenylpyruvic acid + Oxygen → Carbon dioxide + Homogentisic acid
conversion direction: LEFT_TO_RIGHT

2.5.1.117
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057909 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001598 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001316 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000170 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000084 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/1.0
right: 2-methyl-6-solanesyl-1,4-benzoquinol
right: Carbon dioxide
right: Pyrophosphate
spontaneous: false
EC number: 2.5.1.117
left: Hydrogen Ion
left: Solanesyl-PP
left: Homogentisic acid
name: Homogentisic acid + Hydrogen Ion + Solanesyl-PP → 2-methyl-6-solanesyl-1,4-benzoquinol + Carbon dioxide + Pyrophosphate
conversion direction: LEFT_TO_RIGHT

2.1.1.295
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057909 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000749 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057910 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000921 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/1.0
right: Hydrogen Ion
right: S-Adenosylhomocysteine
right: plastoquinol-9
spontaneous: false
EC number: 2.1.1.295
left: 2-methyl-6-solanesyl-1,4-benzoquinol
left: S-Adenosylmethionine
name: 2-methyl-6-solanesyl-1,4-benzoquinol + S-Adenosylmethionine → Hydrogen Ion + S-Adenosylhomocysteine + plastoquinol-9
conversion direction: LEFT_TO_RIGHT

Reference/PubChem-compound 24762165
type: UnificationXref
id: 24762165
db: PubChem-compound

ChemicalStructure/PW C002145
type: ChemicalStructure
structure format: SMILES

plastoquinol-9
type: SmallMolecule
cellular location: Chloroplast
entity reference: plastoquinol-9

Reference/PubChem-compound 979
type: UnificationXref
id: 979
db: PubChem-compound

ChemicalStructure/PW C000084
type: ChemicalStructure
structure format: SMILES
structure data: OC(=O)CC1=C(O)C=CC(O)=C1

Protein/11555 Cytosol/Stoichiometry/2.0
type: Stoichiometry
physical entity: 4-hydroxyphenylpyruvate dioxygenase
stoichiometric coefficient: 2.0