[Oxidized NADPH---hemoprotein reductase]
Bifunctional dihydrocamalexate synthase/camalexin synthase
Glutathione γ-glutamyl hydrolase/transpeptidase 4
2-hydroxy-2-(1H-indol-3-yl)acetonitrile → Dehydro(indole-3-yl)acetonitrile + Water
(Z)-indol-3-ylacetaldoxime → 3-Indoleacetonitrile + Water
3-Indoleacetonitrile + Oxygen + [Reduced NADPH---hemoprotein reductase] → 2-hydroxy-2-(1H-indol-3-yl)acetonitrile + Water + [Oxidized NADPH---hemoprotein reductase]
(E)-indol-3-ylacetaldoxime ↔ (Z)-indol-3-ylacetaldoxime
Hydrogen Ion + N,N-dihydroxy-L-tryptophan → (E)-indol-3-ylacetaldoxime + Carbon dioxide + Water
L-Tryptophan + Oxygen + [Reduced NADPH---hemoprotein reductase] → Hydrogen Ion + N-hydroxy-L-tryptophan + Water + [Oxidized NADPH---hemoprotein reductase]
N-hydroxy-L-tryptophan + Oxygen + [Reduced NADPH---hemoprotein reductase] → N,N-dihydroxy-L-tryptophan + Water + [Oxidized NADPH---hemoprotein reductase]
(R)-dihydrocamalexate + Hydrogen Ion + Oxygen + [Reduced NADPH---hemoprotein reductase] → Camalexin + Carbon dioxide + 2 Water + [Oxidized NADPH---hemoprotein reductase]
2-(cystein-S-yl)-2-(1H-indol-3-yl)-acetonitrile + Oxygen + [Reduced NADPH---hemoprotein reductase] → (R)-dihydrocamalexate + Hydrogen Ion + Hydrogen cyanide + 2 Water
(glutathion-S-yl)(1H-indol-3-yl)acetonitrile + Water → (L-cysteinylglycin-S-yl)(1H-indol-3-yl)acetonitrile + L-Glutamic acid
(L-cysteinylglycin-S-yl)(1H-indol-3-yl)acetonitrile + Water → 2-(cystein-S-yl)-2-(1H-indol-3-yl)-acetonitrile + Glycine
Dehydro(indole-3-yl)acetonitrile + Glutathione → (glutathion-S-yl)(1H-indol-3-yl)acetonitrile