Glucose-1-phosphate thymidylyltransferase
(3R)-3-Hydroxyacyl-[acyl-carrier protein]
3-(3-Hydroxydecanoyloxy)decanoate synthase
Hydrogen Ion + NADPH + dTDP-4-dehydro-β-L-rhamnose → NADP + dTDP-β-L-rhamnose
Glucose 1-phosphate + Thymidine 5'-triphosphate → Pyrophosphate + dTDP-D-glucose
dTDP-4-dehydro-6-deoxy-D-glucose ↔ dTDP-4-dehydro-β-L-rhamnose
2 (3R)-3-Hydroxyacyl-[acyl-carrier protein] + Water → (3R)-(3-Hydroxyalkanoyloxy)alkanoate + Hydrogen Ion + 2 [Acyl-carrier protein]
(3R)-(3-Hydroxyalkanoyloxy)alkanoate + dTDP-β-L-rhamnose → Hydrogen Ion + Mono-rhamnolipid + dTDP
Mono-rhamnolipid + dTDP-β-L-rhamnose → Di-rhamnolipid + Hydrogen Ion + dTDP
Glucose 6-phosphate ↔ Glucose 1-phosphate
dTDP-D-glucose → Water + dTDP-4-dehydro-6-deoxy-D-glucose