(3R)-3-Hydroxyacyl-[acyl-carrier protein]
3-(3-Hydroxydecanoyloxy)decanoate synthase
Glucose-1-phosphate thymidylyltransferase
Rhamnolipid Biosynthesis RL(10:0(3-OH)/10:0(3-OH)) old
dTDP-D-glucose → Water + dTDP-4-dehydro-6-deoxy-D-glucose
Hydrogen Ion + NADPH + dTDP-4-dehydro-β-L-rhamnose → NADP + dTDP-β-L-rhamnose
Glucose 1-phosphate + Thymidine 5'-triphosphate → Pyrophosphate + dTDP-D-glucose
dTDP-4-dehydro-6-deoxy-D-glucose ↔ dTDP-4-dehydro-β-L-rhamnose
2 (3R)-3-Hydroxyacyl-[acyl-carrier protein] + Water → HAA(10:0(3-OH)/10:0(3-OH)) + Hydrogen Ion + 2 [Acyl-carrier protein]
HAA(10:0(3-OH)/10:0(3-OH)) + dTDP-β-L-rhamnose → Hydrogen Ion + dTDP + monoRL(10:0(3-OH)/10:0(3-OH))
dTDP-β-L-rhamnose + monoRL(10:0(3-OH)/10:0(3-OH)) → Hydrogen Ion + dTDP + diRL(10:0(3-OH)/10:0(3-OH))
Glucose 6-phosphate ↔ Glucose 1-phosphate