Reference/BioCyc CPD-14649
type: UnificationXref
id: CPD-14649
db: BioCyc

Reference/BioCyc CPD-14647
type: UnificationXref
id: CPD-14647
db: BioCyc

Reference/CAS 7722-84-1
type: UnificationXref
id: 7722-84-1
db: CAS

Reference/BioCyc PHYTOENE
type: UnificationXref
id: PHYTOENE
db: BioCyc

Reference/BioCyc CPD-14646
type: UnificationXref
id: CPD-14646
db: BioCyc

Reference/PubChem-compound 70678813
type: UnificationXref
id: 70678813
db: PubChem-compound

Abscisic alcohol
type: SmallMolecule
entity reference: Abscisic alcohol

Compound/PW C040034 Endoplasmic Reticulum/Stoichiometry/1.0
type: Stoichiometry
physical entity: Hydrogen Ion
stoichiometric coefficient: 1.0

ChemicalStructure/PW C019503
type: ChemicalStructure
structure format: SMILES

Compound/PW C016588 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: β-Zeacarotene
stoichiometric coefficient: 1.0

Reference/ChemSpider 937
type: UnificationXref
id: 937
db: ChemSpider

Compound/PW C001754 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Lycopene
stoichiometric coefficient: 1.0

Reference/CAS 6699-20-3
type: UnificationXref
id: 6699-20-3
db: CAS

Reference/HMDB HMDB0003125
type: UnificationXref
id: HMDB0003125
db: HMDB

Reference/UniProt O81077
type: UnificationXref
id: O81077
db: UniProt

Compound/PW C001065/Stoichiometry/1.0
type: Stoichiometry
physical entity: Oxygen
stoichiometric coefficient: 1.0

Reference/PubChem-compound 439153
type: UnificationXref
id: 439153
db: PubChem-compound

Reference/ChemSpider 4478601
type: UnificationXref
id: 4478601
db: ChemSpider

Pyrophosphate
type: SmallMolecule
cellular location: Chloroplast
entity reference: Pyrophosphate

Reference/HMDB HMDB0003000
type: UnificationXref
id: HMDB0003000
db: HMDB

Compound/PW C040034/Stoichiometry/1.0
type: Stoichiometry
physical entity: Hydrogen Ion
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0003364
type: UnificationXref
id: HMDB0003364
db: HMDB

abscisic acid glucose ester beta-glucosidase
type: ProteinReference
xref: Reference/UniProt Q9SE50
organism: Arabidopsis thaliana

beta-carotene 3-hydroxylase 1
type: ProteinReference
xref: Reference/UniProt Q9SZZ8
organism: Arabidopsis thaliana

Compound/PW C001065 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Oxygen
stoichiometric coefficient: 1.0

Abscisic acid
type: SmallMoleculeReference
xref: Reference/CAS 7773-56-0
xref: Reference/PubChem-compound 5375200
xref: Reference/HMDB HMDB0036093
xref: Reference/ChEBI CHEBI 62426
xref: Reference/ChemSpider 4524740
chemical formula: C15H20O4
molecular weight: 264.13617
structure: ChemicalStructure/PW C017036

Reference/ChemSpider 58238
type: UnificationXref
id: 58238
db: ChemSpider

lycopene beta cyclase
type: ProteinReference
xref: Reference/UniProt Q38933
organism: Arabidopsis thaliana

violaxanthin deepoxidase / antheraxanthin deepoxidase
type: ProteinReference
xref: Reference/UniProt Q39249
organism: Arabidopsis thaliana

zeaxanthin epoxidase
type: ProteinReference
xref: Reference/UniProt Q9FGC7
organism: Arabidopsis thaliana

ChemicalStructure/PW C017456
type: ChemicalStructure
structure format: SMILES
structure data: CC(=O)\C=C\C1=C(C)CCCC1(C)C

Phytofluene
type: SmallMolecule
cellular location: Chloroplast
entity reference: Phytofluene

Compound/PW C108662 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 9,9',15-Tri-cis-zeta-carotene
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 17594
type: UnificationXref
id: CHEBI:17594
db: ChEBI

ChemicalStructure/PW C057902
type: ChemicalStructure
structure format: SMILES

Compound/PW C108667 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: 9-cis-Violaxanthin
stoichiometric coefficient: 1.0

ChemicalStructure/PW C057905
type: ChemicalStructure
structure format: SMILES

ChemicalStructure/PW C057900
type: ChemicalStructure
structure format: SMILES

Reference/ChemSpider 559142
type: UnificationXref
id: 559142
db: ChemSpider

ChemicalStructure/PW C057901
type: ChemicalStructure
structure format: SMILES

ChemicalStructure/PW C057906
type: ChemicalStructure
structure format: SMILES

ReactionCatalysis37587
type: Catalysis
controller: carlactone synthase
controlled: 1.13.11.69
control type: ACTIVATION

Compound/PW C057905 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: γ-Carotene
stoichiometric coefficient: 1.0

ReactionCatalysis37586
type: Catalysis
controller: 9-cis-beta-carotene 9',10'-cleavage dioxygenase
controlled: 1.13.11.68
control type: ACTIVATION

Reference/PubChem-compound 70678836
type: UnificationXref
id: 70678836
db: PubChem-compound

Zeaxanthin
type: SmallMolecule
cellular location: Chloroplast
entity reference: Zeaxanthin

Compound/PW C000031 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Ascorbic acid
stoichiometric coefficient: 2.0

Reference/ChemSpider 952
type: UnificationXref
id: 952
db: ChemSpider

Compound/PW C001860 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Quinone
stoichiometric coefficient: 2.0

ChemicalStructure/PW C057910
type: ChemicalStructure
structure format: SMILES

Reference/UniProt Q9SZZ8
type: UnificationXref
id: Q9SZZ8
db: UniProt

Reference/GENE ONTOLOGY GO 0009507
type: UnificationXref
id: GO:0009507
db: GENE ONTOLOGY

Reference/BioCyc GERANYLGERANYL-PP
type: UnificationXref
id: GERANYLGERANYL-PP
db: BioCyc

Reference/ChemSpider 14797235
type: UnificationXref
id: 14797235
db: ChemSpider

Reference/HMDB HMDB0003023
type: UnificationXref
id: HMDB0003023
db: HMDB

Reference/ChEBI CHEBI 17579
type: UnificationXref
id: CHEBI:17579
db: ChEBI

Reference/CAS 144-68-3
type: UnificationXref
id: 144-68-3
db: CAS

Reference/HMDB HMDB0002181
type: UnificationXref
id: HMDB0002181
db: HMDB

ChemicalStructure/PW C016588
type: ChemicalStructure
structure format: SMILES
structure data: CC(C\C=C/C=C(\C)/C=C/C=C(\C)/C=C\C=C(\C)CCC=C(C)C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C

Reference/KEGG Compound C00221
type: UnificationXref
id: C00221
db: KEGG Compound

Compound/PW C016735 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Prolycopene
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 16240
type: UnificationXref
id: CHEBI:16240
db: ChEBI

Reference/BioCyc CPD-14650
type: UnificationXref
id: CPD-14650
db: BioCyc

Reference/ChemSpider 4524740
type: UnificationXref
id: 4524740
db: ChemSpider

Reference/ChemSpider 1010
type: UnificationXref
id: 1010
db: ChemSpider

Oxygen
type: SmallMolecule
cellular location: Chloroplast
entity reference: Oxygen

Reference/PubChem-compound 446925
type: UnificationXref
id: 446925
db: PubChem-compound

Reference/BioCyc PPI
type: UnificationXref
id: PPI
db: BioCyc

Reference/BioCyc NEUROSPORENE
type: UnificationXref
id: NEUROSPORENE
db: BioCyc

Reference/PubChem-compound 4369188
type: UnificationXref
id: 4369188
db: PubChem-compound

Reference/CAS 5666-16-0
type: UnificationXref
id: 5666-16-0
db: CAS

Reference/KEGG Compound C10385
type: UnificationXref
id: C10385
db: KEGG Compound

Reference/HMDB HMDB0004486
type: UnificationXref
id: HMDB0004486
db: HMDB

Reaction212455
type: BiochemicalReaction
participant stoichiometry: Compound/PW C016588 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108664 Chloroplast/Stoichiometry/1.0
right: 7,8-Dihydro-beta-carotene
spontaneous: false
left: β-Zeacarotene
name: β-Zeacarotene → 7,8-Dihydro-beta-carotene
conversion direction: LEFT_TO_RIGHT

5.5.1.18
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001754 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C017812 Chloroplast/Stoichiometry/1.0
right: δ-Carotene
spontaneous: false
EC number: 5.5.1.18
left: Lycopene
name: Lycopene → δ-Carotene
conversion direction: LEFT_TO_RIGHT

Reaction212457
type: BiochemicalReaction
participant stoichiometry: Compound/PW C108665 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C017812 Chloroplast/Stoichiometry/1.0
right: epsilon,epsilon-Carotene
spontaneous: false
left: δ-Carotene
name: δ-Carotene → epsilon,epsilon-Carotene
conversion direction: LEFT_TO_RIGHT

Reference/UniProt Q6TBX7
type: UnificationXref
id: Q6TBX7
db: UniProt

Reaction212458
type: BiochemicalReaction
participant stoichiometry: Compound/PW C002025 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C017812 Chloroplast/Stoichiometry/1.0
right: α-Carotene
spontaneous: false
left: δ-Carotene
name: δ-Carotene → α-Carotene
conversion direction: LEFT_TO_RIGHT

1.4.13.129
type: BiochemicalReaction
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C041102 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C108666 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C002025 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C041101 Chloroplast/Stoichiometry/4.0
right: Water
right: Oxidized ferredoxin
right: Zeinoxanthin
spontaneous: false
EC number: 1.4.13.129
left: Oxygen
left: Reduced ferredoxin
left: Hydrogen Ion
left: α-Carotene
name: 4 Hydrogen Ion + 2 Oxygen + 4 Reduced ferredoxin + α-Carotene → 4 Oxidized ferredoxin + 2 Water + Zeinoxanthin
conversion direction: LEFT_TO_RIGHT

xanthoxin dehydrogenase
type: Protein
cellular location: Cytoplasm
entity reference: xanthoxin dehydrogenase

Compound/PW C001632 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Hydroquinone
stoichiometric coefficient: 2.0

Lutein
type: SmallMolecule
cellular location: Chloroplast
entity reference: Lutein

Hydrogen Ion
type: SmallMolecule
entity reference: Hydrogen Ion

Reference/ChemSpider 21864822
type: UnificationXref
id: 21864822
db: ChemSpider

Reference/CAS 540-04-5
type: UnificationXref
id: 540-04-5
db: CAS

Reference/KEGG Compound C00353
type: UnificationXref
id: C00353
db: KEGG Compound

Reference/KEGG Compound C00472
type: UnificationXref
id: C00472
db: KEGG Compound

Reaction212451
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001766 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057910 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001722 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C011346 Chloroplast/Stoichiometry/2.0
right: (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene
right: plastoquinol-9
spontaneous: false
left: Plastoquinone 9
left: Phytofluene
name: Phytofluene + 2 Plastoquinone 9 → (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene + 2 plastoquinol-9
conversion direction: LEFT_TO_RIGHT

Reaction212452
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001860 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001780 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001632 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001766 Chloroplast/Stoichiometry/1.0
right: Neurosporene
right: Hydroquinone
spontaneous: false
left: (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene
left: Quinone
name: (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene + 2 Quinone → 2 Hydroquinone + Neurosporene
conversion direction: LEFT_TO_RIGHT

Reaction212453
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001860 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001780 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001632 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001754 Chloroplast/Stoichiometry/1.0
right: Lycopene
right: Hydroquinone
spontaneous: false
left: Neurosporene
left: Quinone
name: Neurosporene + 2 Quinone → 2 Hydroquinone + Lycopene
conversion direction: LEFT_TO_RIGHT

Reaction212454
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001780 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C016588 Chloroplast/Stoichiometry/1.0
right: β-Zeacarotene
spontaneous: false
left: Neurosporene
name: Neurosporene → β-Zeacarotene
conversion direction: LEFT_TO_RIGHT

Reference/UniProt P37271
type: UnificationXref
id: P37271
db: UniProt

lycopene beta cyclase
type: Protein
cellular location: Chloroplast
entity reference: lycopene beta cyclase

β-Cryptoxanthin
type: SmallMoleculeReference
xref: Reference/ChemSpider 4904571
xref: Reference/HMDB HMDB0033844
xref: Reference/PubChem-compound 6384256
xref: Reference/CAS 472-70-8
chemical formula: C40H56O
molecular weight: 552.4331
structure: ChemicalStructure/PW C014903

plastoquinol-9
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 28026
xref: Reference/ChemSpider 4945177
xref: Reference/KEGG Compound C16695
xref: Reference/BioCyc CPD-12829
xref: Reference/PubChem-compound 6440941
chemical formula: C53H82O2
molecular weight: 750.6315
structure: ChemicalStructure/PW C057910

FMNH2
type: SmallMolecule
entity reference: FMNH2

Reference/UniProt Q38933
type: UnificationXref
id: Q38933
db: UniProt

Reference/UniProt Q38932
type: UnificationXref
id: Q38932
db: UniProt

Reference/ChEBI CHEBI 62466
type: UnificationXref
id: CHEBI:62466
db: ChEBI

zeaxanthin epoxidase
type: Protein
cellular location: Chloroplast
entity reference: zeaxanthin epoxidase

Compound/PW C017036/Stoichiometry/1.0
type: Stoichiometry
physical entity: Abscisic acid
stoichiometric coefficient: 1.0

Reaction212466
type: BiochemicalReaction
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C041102 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001707 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057906 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C041101 Chloroplast/Stoichiometry/4.0
right: Water
right: Oxidized ferredoxin
right: antheraxanthin
spontaneous: false
left: Oxygen
left: Reduced ferredoxin
left: Hydrogen Ion
left: Zeaxanthin
name: 4 Hydrogen Ion + 2 Oxygen + 4 Reduced ferredoxin + Zeaxanthin → 4 Oxidized ferredoxin + 2 Water + antheraxanthin
conversion direction: LEFT_TO_RIGHT

Reference/UniProt Q7G9P4
type: UnificationXref
id: Q7G9P4
db: UniProt

Oxidized ferredoxin
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00139
xref: Reference/ChEBI CHEBI 17908

Reaction212467
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001707 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057906 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000031 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C000977 Chloroplast/Stoichiometry/2.0
right: Water
right: Zeaxanthin
right: Dehydroascorbic acid
spontaneous: false
left: Ascorbic acid
left: antheraxanthin
name: 2 Ascorbic acid + antheraxanthin → 2 Dehydroascorbic acid + 2 Water + Zeaxanthin
conversion direction: LEFT_TO_RIGHT

Reference/KEGG Compound C00007
type: UnificationXref
id: C00007
db: KEGG Compound

Reduced ferredoxin
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 17513
xref: Reference/KEGG Compound C00138

Reaction212468
type: BiochemicalReaction
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C041102 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001778 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057906 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C041101 Chloroplast/Stoichiometry/4.0
right: Violaxanthin
right: Water
right: Oxidized ferredoxin
spontaneous: false
left: Oxygen
left: Reduced ferredoxin
left: Hydrogen Ion
left: antheraxanthin
name: 4 Hydrogen Ion + 2 Oxygen + 4 Reduced ferredoxin + antheraxanthin → 4 Oxidized ferredoxin + Violaxanthin + 2 Water
conversion direction: LEFT_TO_RIGHT

Reaction212469
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001778 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057906 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000031 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C000977 Chloroplast/Stoichiometry/2.0
right: Water
right: antheraxanthin
right: Dehydroascorbic acid
spontaneous: false
left: Violaxanthin
left: Ascorbic acid
name: 2 Ascorbic acid + Violaxanthin → 2 Dehydroascorbic acid + 2 Water + antheraxanthin
conversion direction: LEFT_TO_RIGHT

Abscisic alcohol
type: SmallMoleculeReference
xref: Reference/CAS 113472-20-1
xref: Reference/HMDB HMDB0039635
xref: Reference/ChemSpider 14797235
chemical formula: C15H22O3
molecular weight: 250.15689
structure: ChemicalStructure/PW C020466

Reference/KEGG Compound C00001
type: UnificationXref
id: C00001
db: KEGG Compound

Reference/CAS 50-81-7
type: UnificationXref
id: 50-81-7
db: CAS

Phytofluene
type: SmallMoleculeReference
xref: Reference/CAS 27664-65-9
xref: Reference/PubChem-compound 5320546
xref: Reference/ChemSpider 4478601
xref: Reference/KEGG Compound C05414
xref: Reference/HMDB HMDB0002871
xref: Reference/ChEBI CHEBI 35165
chemical formula: C40H62
molecular weight: 542.48517
structure: ChemicalStructure/PW C001722

1.14.14.158
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001813 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C104784 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108666 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000891 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/1.0
right: FMN
right: Hydrogen Ion
right: Water
right: Lutein
spontaneous: false
EC number: 1.14.14.158
left: Oxygen
left: Zeinoxanthin
left: FMNH2
name: FMNH2 + Oxygen + Zeinoxanthin → FMN + Hydrogen Ion + Lutein + Water
conversion direction: LEFT_TO_RIGHT

Reference/ChEBI CHEBI 18361
type: UnificationXref
id: CHEBI:18361
db: ChEBI

Reaction212461
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001531 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C104784 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000891 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C002025 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/1.0
right: α-Cryptoxanthin
right: FMN
right: Hydrogen Ion
right: Water
spontaneous: false
left: Oxygen
left: α-Carotene
left: FMNH2
name: FMNH2 + Oxygen + α-Carotene → FMN + Hydrogen Ion + Water + α-Cryptoxanthin
conversion direction: LEFT_TO_RIGHT

Reaction212462
type: BiochemicalReaction
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001531 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001813 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C041102 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C041101 Chloroplast/Stoichiometry/4.0
right: Water
right: Lutein
right: Oxidized ferredoxin
spontaneous: false
left: α-Cryptoxanthin
left: Oxygen
left: Reduced ferredoxin
left: Hydrogen Ion
name: 4 Hydrogen Ion + 2 Oxygen + 4 Reduced ferredoxin + α-Cryptoxanthin → Lutein + 4 Oxidized ferredoxin + 2 Water
conversion direction: LEFT_TO_RIGHT

Reference/PathWhiz PW122504
type: UnificationXref
id: PW122504
db: PathWhiz

Reaction212463
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057881 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000437 Chloroplast/Stoichiometry/1.0
right: 9-cis-β-Carotene
spontaneous: false
left: B-Carotene
name: B-Carotene → 9-cis-β-Carotene
conversion direction: LEFT_TO_RIGHT

Reference/KEGG Compound C00004
type: UnificationXref
id: C00004
db: KEGG Compound

1.4.13.129
type: BiochemicalReaction
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C014903 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C041102 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C000437 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C041101 Chloroplast/Stoichiometry/4.0
right: β-Cryptoxanthin
right: Water
right: Oxidized ferredoxin
spontaneous: false
EC number: 1.4.13.129
left: Oxygen
left: B-Carotene
left: Reduced ferredoxin
left: Hydrogen Ion
name: B-Carotene + 4 Hydrogen Ion + 2 Oxygen + 4 Reduced ferredoxin → 4 Oxidized ferredoxin + 2 Water + β-Cryptoxanthin
conversion direction: LEFT_TO_RIGHT

Reference/KEGG Compound C00003
type: UnificationXref
id: C00003
db: KEGG Compound

Reaction212465
type: BiochemicalReaction
participant stoichiometry: Compound/PW C014903 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001420 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C041102 Chloroplast/Stoichiometry/4.0
participant stoichiometry: Compound/PW C001707 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C041101 Chloroplast/Stoichiometry/4.0
right: Water
right: Oxidized ferredoxin
right: Zeaxanthin
spontaneous: false
left: Oxygen
left: Reduced ferredoxin
left: Hydrogen Ion
left: β-Cryptoxanthin
name: 4 Hydrogen Ion + 2 Oxygen + 4 Reduced ferredoxin + β-Cryptoxanthin → 4 Oxidized ferredoxin + 2 Water + Zeaxanthin
conversion direction: LEFT_TO_RIGHT

Reference/KEGG Compound C15858
type: UnificationXref
id: C15858
db: KEGG Compound

Reference/KEGG Compound C15857
type: UnificationXref
id: C15857
db: KEGG Compound

Reference/ChemSpider 182283
type: UnificationXref
id: 182283
db: ChemSpider

Compound/PW C001707 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Zeaxanthin
stoichiometric coefficient: 1.0

Reference/KEGG Compound C13455
type: UnificationXref
id: C13455
db: KEGG Compound

Reference/KEGG Compound C15971
type: UnificationXref
id: C15971
db: KEGG Compound

Reference/KEGG Compound C15970
type: UnificationXref
id: C15970
db: KEGG Compound

δ-Carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: δ-Carotene

ReactionCatalysis37662
type: Catalysis
controller: lycopene beta cyclase
controlled: 5.5.1.19
control type: ACTIVATION

Reaction212477
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057900/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057901/Stoichiometry/1.0
right: phaseic acid
spontaneous: false
left: 8'-hydroxyabscisate
name: 8'-hydroxyabscisate ↔ phaseic acid
conversion direction: REVERSIBLE

Reference/PubChem-compound 53477762
type: UnificationXref
id: 53477762
db: PubChem-compound

Reaction212478
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057901/Stoichiometry/1.0
participant stoichiometry: Compound/PW C019503/Stoichiometry/1.0
right: Dihydrophaseic acid
spontaneous: false
left: phaseic acid
name: phaseic acid → Dihydrophaseic acid
conversion direction: LEFT_TO_RIGHT

Reference/KEGG Compound C00139
type: UnificationXref
id: C00139
db: KEGG Compound

ReactionCatalysis37664
type: Catalysis
controller: beta-carotene 3-hydroxylase 1
controlled: 1.4.13.129
control type: ACTIVATION

Reaction212479
type: BiochemicalReaction
participant stoichiometry: Compound/PW C040034 Endoplasmic Reticulum/Stoichiometry/1.0
participant stoichiometry: Compound/PW C017036 Endoplasmic Reticulum/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001420 Endoplasmic Reticulum/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057902 Endoplasmic Reticulum/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000395 Endoplasmic Reticulum/Stoichiometry/1.0
right: Water
right: abscisic acid glucose ester
spontaneous: false
left: Abscisic acid
left: Hydrogen Ion
left: β-D-Glucose
name: Abscisic acid + Hydrogen Ion + β-D-Glucose ← Water + abscisic acid glucose ester
conversion direction: RIGHT_TO_LEFT

Reference/CAS 10467-46-6
type: UnificationXref
id: 10467-46-6
db: CAS

Reference/KEGG Compound C00138
type: UnificationXref
id: C00138
db: KEGG Compound

ReactionCatalysis37663
type: Catalysis
controller: lycopene beta cyclase
controlled: Reaction47519
control type: ACTIVATION

Compound/PW C057900/Stoichiometry/1.0
type: Stoichiometry
physical entity: 8'-hydroxyabscisate
stoichiometric coefficient: 1.0

NAD
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 15846
xref: Reference/HMDB HMDB0000902
xref: Reference/CAS 53-84-9
xref: Reference/KEGG Compound C00003
xref: Reference/PubChem-compound 5893
xref: Reference/BioCyc NAD
xref: Reference/ChemSpider 5682
chemical formula: C21H28N7O14P2
molecular weight: 664.11694
structure: ChemicalStructure/PW C000721

Abscisic acid
type: SmallMolecule
entity reference: Abscisic acid

Reaction212471
type: BiochemicalReaction
participant stoichiometry: Compound/PW C108667/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001778/Stoichiometry/1.0
right: 9-cis-Violaxanthin
spontaneous: false
left: Violaxanthin
name: Violaxanthin → 9-cis-Violaxanthin
conversion direction: LEFT_TO_RIGHT

Reaction212472
type: BiochemicalReaction
participant stoichiometry: Compound/PW C108667 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000721 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001144 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057889 Cytoplasm/Stoichiometry/1.0
right: Hydrogen Ion
right: abscisic aldehyde
right: NADH
spontaneous: false
left: 9-cis-Violaxanthin
left: NAD
name: 9-cis-Violaxanthin + NAD → Hydrogen Ion + NADH + abscisic aldehyde
conversion direction: LEFT_TO_RIGHT

Reference/HMDB HMDB0000902
type: UnificationXref
id: HMDB0000902
db: HMDB

Reaction212473
type: BiochemicalReaction
participant stoichiometry: Compound/PW C017036 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001783 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001065 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001420 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057889 Cytoplasm/Stoichiometry/1.0
right: Abscisic acid
right: Hydrogen Ion
right: Hydrogen peroxide
spontaneous: false
left: Oxygen
left: Water
left: abscisic aldehyde
name: Oxygen + Water + abscisic aldehyde → Abscisic acid + Hydrogen Ion + Hydrogen peroxide
conversion direction: LEFT_TO_RIGHT

Lutein
type: SmallMoleculeReference
xref: Reference/BioCyc CPD1F-119
xref: Reference/ChemSpider 4938343
xref: Reference/CAS 127-40-2
xref: Reference/ChEBI CHEBI 28838
xref: Reference/HMDB HMDB0003233
xref: Reference/PubChem-compound 6433159
xref: Reference/KEGG Compound C08601
chemical formula: C40H56O2
molecular weight: 568.42804
structure: ChemicalStructure/PW C001813

Reference/BioCyc CPD-7196
type: UnificationXref
id: CPD-7196
db: BioCyc

Reaction212474
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057889 Cytoplasm/Stoichiometry/1.0
participant stoichiometry: Compound/PW C020466 Cytoplasm/Stoichiometry/1.0
right: Abscisic alcohol
spontaneous: false
left: abscisic aldehyde
name: abscisic aldehyde → Abscisic alcohol
conversion direction: LEFT_TO_RIGHT

Reference/ChEBI CHEBI 17242
type: UnificationXref
id: CHEBI:17242
db: ChEBI

Reaction212475
type: BiochemicalReaction
participant stoichiometry: Compound/PW C020466/Stoichiometry/1.0
participant stoichiometry: Compound/PW C017036/Stoichiometry/1.0
right: Abscisic acid
spontaneous: false
left: Abscisic alcohol
name: Abscisic alcohol → Abscisic acid
conversion direction: LEFT_TO_RIGHT

Reference/KEGG Compound C00013
type: UnificationXref
id: C00013
db: KEGG Compound

1.14.14.137
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001420/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057900/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001065/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000891/Stoichiometry/1.0
participant stoichiometry: Compound/PW C104784/Stoichiometry/1.0
participant stoichiometry: Compound/PW C017036/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034/Stoichiometry/1.0
right: 8'-hydroxyabscisate
right: Water
right: Hydrogen Ion
right: FMN
spontaneous: false
EC number: 1.14.14.137
left: Abscisic acid
left: FMNH2
left: Oxygen
name: Abscisic acid + FMNH2 + Oxygen → 8'-hydroxyabscisate + FMN + Hydrogen Ion + Water
conversion direction: LEFT_TO_RIGHT

Reference/ChEBI CHEBI 28026
type: UnificationXref
id: CHEBI:28026
db: ChEBI

Reference/CAS 472-92-4
type: UnificationXref
id: 472-92-4
db: CAS

Reference/PubChem-compound 25244322
type: UnificationXref
id: 25244322
db: PubChem-compound

Compound/PW C019503/Stoichiometry/1.0
type: Stoichiometry
physical entity: Dihydrophaseic acid
stoichiometric coefficient: 1.0

Reference/CAS 126-29-4
type: UnificationXref
id: 126-29-4
db: CAS

Reference/HMDB HMDB0003063
type: UnificationXref
id: HMDB0003063
db: HMDB

Reference/KEGG Compound C15981
type: UnificationXref
id: C15981
db: KEGG Compound

Compound/PW C002025 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: α-Carotene
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 16048
type: UnificationXref
id: CHEBI:16048
db: ChEBI

Hydrogen Ion
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00080
xref: Reference/ChEBI CHEBI 15378
xref: Reference/HMDB HMDB0059597
xref: Reference/PubChem-compound 1038
xref: Reference/ChemSpider 1010
chemical formula: H
molecular weight: 1.007825
structure: ChemicalStructure/PW C040034

Zeaxanthin
type: SmallMoleculeReference
xref: Reference/ChemSpider 4444421
xref: Reference/CAS 144-68-3
xref: Reference/KEGG Compound C06098
xref: Reference/ChEBI CHEBI 27547
xref: Reference/HMDB HMDB0002789
xref: Reference/BioCyc CPD1F-130
xref: Reference/PubChem-compound 5280899
chemical formula: C40H56O2
molecular weight: 568.42804
structure: ChemicalStructure/PW C001707

Dehydroascorbic acid
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00425
xref: Reference/BioCyc L-DEHYDRO-ASCORBATE
xref: Reference/CAS 490-83-5
xref: Reference/ChemSpider 182283
xref: Reference/PubChem-compound 210328
xref: Reference/ChEBI CHEBI 17242
xref: Reference/HMDB HMDB0001264
chemical formula: C6H6O6
molecular weight: 174.01643
structure: ChemicalStructure/PW C000977

Compound/PW C057883 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: carlactone
stoichiometric coefficient: 1.0

Compound/PW C000891 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: FMNH2
stoichiometric coefficient: 1.0

Reference/CAS 53-84-9
type: UnificationXref
id: 53-84-9
db: CAS

Reference/KEGG Compound C00027
type: UnificationXref
id: C00027
db: KEGG Compound

Compound/PW C017812 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: δ-Carotene
stoichiometric coefficient: 1.0

Reference/PubChem-compound 25245404
type: UnificationXref
id: 25245404
db: PubChem-compound

Compound/PW C001420 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Water
stoichiometric coefficient: 2.0

Reference/CAS 41756-77-8
type: UnificationXref
id: 41756-77-8
db: CAS

Reference/ChemSpider 4944750
type: UnificationXref
id: 4944750
db: ChemSpider

Reference/HMDB HMDB0036093
type: UnificationXref
id: HMDB0036093
db: HMDB

Reference/PubChem-compound 54670067
type: UnificationXref
id: 54670067
db: PubChem-compound

Reference/KEGG Compound C15514
type: UnificationXref
id: C15514
db: KEGG Compound

Abscisic acid 8'-hydroxylase 2
type: Protein
entity reference: Abscisic acid 8'-hydroxylase 2

Reference/KEGG Compound C03427
type: UnificationXref
id: C03427
db: KEGG Compound

ReactionCatalysis202117
type: Catalysis
controller: xanthoxin dehydrogenase
controlled: Reaction212472
control type: ACTIVATION

ReactionCatalysis202118
type: Catalysis
controller: Abscisic-aldehyde oxidase
controlled: Reaction212473
control type: ACTIVATION

ReactionCatalysis202119
type: Catalysis
controller: Abscisic acid 8'-hydroxylase 2
controlled: 1.14.14.137
control type: ACTIVATION

Hydroquinone
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0002434
xref: Reference/ChemSpider 764
xref: Reference/PubChem-compound 785
xref: Reference/CAS 123-31-9
xref: Reference/BioCyc 236-TRICHLOROHYDROQUINONE
xref: Reference/ChEBI CHEBI 17594
xref: Reference/KEGG Compound C00530
chemical formula: C6H6O2
molecular weight: 110.03678
structure: ChemicalStructure/PW C001632

ReactionCatalysis202113
type: Catalysis
controller: violaxanthin deepoxidase / antheraxanthin deepoxidase
controlled: Reaction212467
control type: ACTIVATION

Lycopene
type: SmallMoleculeReference
xref: Reference/CAS 502-65-8
xref: Reference/PubChem-compound 446925
xref: Reference/BioCyc CPD1F-114
xref: Reference/ChEBI CHEBI 15948
xref: Reference/ChemSpider 394156
xref: Reference/KEGG Compound C05432
xref: Reference/HMDB HMDB0003000
chemical formula: C40H56
molecular weight: 536.4382
structure: ChemicalStructure/PW C001754

ReactionCatalysis202114
type: Catalysis
controller: zeaxanthin epoxidase
controlled: Reaction212468
control type: ACTIVATION

ReactionCatalysis202115
type: Catalysis
controller: violaxanthin deepoxidase / antheraxanthin deepoxidase
controlled: Reaction212469
control type: ACTIVATION

Prephytoene diphosphate
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 17090
xref: Reference/KEGG Compound C03427
xref: Reference/BioCyc PHYTOENE
xref: Reference/ChemSpider 21864822
xref: Reference/PubChem-compound 24883415
xref: Reference/HMDB HMDB0003023
chemical formula: C40H68O7P2
molecular weight: 722.44403
structure: ChemicalStructure/PW C001758

ReactionCatalysis202110
type: Catalysis
controller: beta-carotene 3-hydroxylase 1
controlled: Reaction212465
control type: ACTIVATION

Reference/CAS 472-93-5
type: UnificationXref
id: 472-93-5
db: CAS

Reference/HMDB HMDB0036565
type: UnificationXref
id: HMDB0036565
db: HMDB

ReactionCatalysis202111
type: Catalysis
controller: Protein LUTEIN DEFICIENT 5, chloroplastic
controlled: Reaction212465
control type: ACTIVATION

Compound/PW C011346 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Plastoquinone 9
stoichiometric coefficient: 2.0

Reference/CAS 472-70-8
type: UnificationXref
id: 472-70-8
db: CAS

ReactionCatalysis202112
type: Catalysis
controller: zeaxanthin epoxidase
controlled: Reaction212466
control type: ACTIVATION

Reference/HMDB HMDB0002434
type: UnificationXref
id: HMDB0002434
db: HMDB

ChemicalStructure/PW C001144
type: ChemicalStructure
structure format: SMILES

Water
type: SmallMolecule
entity reference: Water

Reference/BioCyc HYDROGEN-PEROXIDE
type: UnificationXref
id: HYDROGEN-PEROXIDE
db: BioCyc

FMN
type: SmallMolecule
entity reference: FMN

Reference/CAS 492-61-5
type: UnificationXref
id: 492-61-5
db: CAS

Reference/HMDB HMDB0000250
type: UnificationXref
id: HMDB0000250
db: HMDB

ChemicalStructure/PW C000170
type: ChemicalStructure
structure format: SMILES
structure data: [O-]P([O-])(=O)OP([O-])([O-])=O

Dehydroascorbic acid
type: SmallMolecule
cellular location: Chloroplast
entity reference: Dehydroascorbic acid

B-Carotene
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 17579
xref: Reference/PubChem-compound 5280489
xref: Reference/BioCyc CPD1F-129
xref: Reference/KEGG Compound C02094
xref: Reference/ChemSpider 4444129
xref: Reference/CAS 7235-40-7
xref: Reference/HMDB HMDB0000561
chemical formula: C40H56
molecular weight: 536.4382
structure: ChemicalStructure/PW C000437

Abscisic alcohol
type: SmallMolecule
cellular location: Cytoplasm
entity reference: Abscisic alcohol

Violaxanthin
type: SmallMolecule
entity reference: Violaxanthin

(9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene
type: SmallMoleculeReference
xref: Reference/ChemSpider 4944750
xref: Reference/KEGG Compound C15857
xref: Reference/ChEBI CHEBI 48716
xref: Reference/PubChem-compound 6440490
xref: Reference/HMDB HMDB0003063
xref: Reference/CAS 72746-33-9
chemical formula: C40H60
molecular weight: 540.4695
structure: ChemicalStructure/PW C001766

ReactionCatalysis202120
type: Catalysis
controller: abscisic acid glucose ester beta-glucosidase
controlled: Reaction212479
control type: ACTIVATION

Reference/ChemSpider 764
type: UnificationXref
id: 764
db: ChemSpider

Reference/ChemSpider 763
type: UnificationXref
id: 763
db: ChemSpider

Reference/ChEBI CHEBI 32325
type: UnificationXref
id: CHEBI:32325
db: ChEBI

α-Cryptoxanthin
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0002268
xref: Reference/ChemSpider 30791985
xref: Reference/CAS 24480-38-4
xref: Reference/ChEBI CHEBI 10223
xref: Reference/KEGG Compound C15981
xref: Reference/PubChem-compound 23724629
chemical formula: C40H56O
molecular weight: 552.4331
structure: ChemicalStructure/PW C001531

Compound/PW C001144 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: NADH
stoichiometric coefficient: 1.0

Compound/PW C057889 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: abscisic aldehyde
stoichiometric coefficient: 1.0

Reference/UniProt Q9SAC0
type: UnificationXref
id: Q9SAC0
db: UniProt

Compound/PW C057882 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 9-cis-10'-apo-β-carotenal
stoichiometric coefficient: 1.0

Reference/PubChem-compound 64689
type: UnificationXref
id: 64689
db: PubChem-compound

Reference/UniProt Q39249
type: UnificationXref
id: Q39249
db: UniProt

Reference/PubChem-compound 784
type: UnificationXref
id: 784
db: PubChem-compound

Reference/PubChem-compound 46173811
type: UnificationXref
id: 46173811
db: PubChem-compound

Reference/PubChem-compound 785
type: UnificationXref
id: 785
db: PubChem-compound

ChemicalStructure/PW C016735
type: ChemicalStructure
structure format: SMILES
structure data: CC(C)=CCC\C(C)=C\C=C/C(/C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(\C)/C=C\C=C(/C)CCC=C(C)C

Reference/SMPDB SMP0121210
type: UnificationXref
id: SMP0121210
db: SMPDB

9-cis-10'-apo-β-carotenal
type: SmallMolecule
cellular location: Chloroplast
entity reference: 9-cis-10'-apo-β-carotenal

9-cis-β-Carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: 9-cis-β-Carotene

Hydroquinone
type: SmallMolecule
cellular location: Chloroplast
entity reference: Hydroquinone

Reference/CAS 7732-18-5
type: UnificationXref
id: 7732-18-5
db: CAS

Reference/PathWhiz PW123846
type: UnificationXref
id: PW123846
db: PathWhiz

α-Cryptoxanthin
type: SmallMolecule
cellular location: Chloroplast
entity reference: α-Cryptoxanthin

Reference/HMDB HMDB0001487
type: UnificationXref
id: HMDB0001487
db: HMDB

Compound/PW C017036 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: Abscisic acid
stoichiometric coefficient: 1.0

Reduced ferredoxin
type: SmallMolecule
cellular location: Chloroplast
entity reference: Reduced ferredoxin

ChemicalStructure/PW C000395
type: ChemicalStructure
structure format: SMILES

ChemicalStructure/PW C000031
type: ChemicalStructure
structure format: SMILES
structure data: [H][C@@]1(OC(=O)C(O)=C1O)[C@@H](O)CO

(9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene

Quinone
type: SmallMoleculeReference
xref: Reference/ChemSpider 4489
xref: Reference/CAS 106-51-4
xref: Reference/KEGG Compound C00472
xref: Reference/ChEBI CHEBI 16509
xref: Reference/BioCyc CPD-8130
xref: Reference/PubChem-compound 4650
xref: Reference/HMDB HMDB0003364
chemical formula: C6H4O2
molecular weight: 108.021126
structure: ChemicalStructure/PW C001860

Oxidized ferredoxin
type: SmallMolecule
cellular location: Chloroplast
entity reference: Oxidized ferredoxin

Reference/KEGG Compound C00061
type: UnificationXref
id: C00061
db: KEGG Compound

Compound/PW C001778 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Violaxanthin
stoichiometric coefficient: 1.0

FMNH2
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 16048
xref: Reference/BioCyc FMNH2
xref: Reference/KEGG Compound C01847
xref: Reference/PubChem-compound 445395
xref: Reference/CAS 5666-16-0
xref: Reference/ChemSpider 393046
xref: Reference/HMDB HMDB0001142
chemical formula: C17H23N4O9P
molecular weight: 458.12027
structure: ChemicalStructure/PW C000891

Reference/UniProt Q93VK5
type: UnificationXref
id: Q93VK5
db: UniProt

Reference/PubChem-compound 44229199
type: UnificationXref
id: 44229199
db: PubChem-compound

Reaction212444
type: BiochemicalReaction
participant stoichiometry: Compound/PW C108661 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057910 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001470 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C011346 Chloroplast/Stoichiometry/2.0
right: 15,9'-Di-cis-phytofluene
right: plastoquinol-9
spontaneous: false
left: Phytoene
left: Plastoquinone 9
name: Phytoene + 2 Plastoquinone 9 → 15,9'-Di-cis-phytofluene + 2 plastoquinol-9
conversion direction: LEFT_TO_RIGHT

Reference/PubChem-compound 10918539
type: UnificationXref
id: 10918539
db: PubChem-compound

Reaction212445
type: BiochemicalReaction
participant stoichiometry: Compound/PW C108661 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057910 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C108662 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C011346 Chloroplast/Stoichiometry/2.0
right: plastoquinol-9
right: 9,9',15-Tri-cis-zeta-carotene
spontaneous: false
left: 15,9'-Di-cis-phytofluene
left: Plastoquinone 9
name: 15,9'-Di-cis-phytofluene + 2 Plastoquinone 9 → 9,9',15-Tri-cis-zeta-carotene + 2 plastoquinol-9
conversion direction: LEFT_TO_RIGHT

15-cis-zeta-carotene isomerase, chloroplastic
type: Protein
cellular location: Chloroplast
entity reference: 15-cis-zeta-carotene isomerase, chloroplastic

Reference/BioCyc CPD-7725
type: UnificationXref
id: CPD-7725
db: BioCyc

5.2.1.12
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001766 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108662 Chloroplast/Stoichiometry/1.0
right: (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene
spontaneous: false
EC number: 5.2.1.12
left: 9,9',15-Tri-cis-zeta-carotene
name: 9,9',15-Tri-cis-zeta-carotene → (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene
conversion direction: LEFT_TO_RIGHT

1.3.5.6
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001860 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001632 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001766 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C019928 Chloroplast/Stoichiometry/1.0
right: (9Z,7'Z,9'Z)-7,8-Dihydrolycopene
right: Hydroquinone
spontaneous: false
EC number: 1.3.5.6
left: (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene
left: Quinone
name: (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene + 2 Quinone → (9Z,7'Z,9'Z)-7,8-Dihydrolycopene + 2 Hydroquinone
conversion direction: LEFT_TO_RIGHT

β-Cryptoxanthin
type: SmallMolecule
cellular location: Chloroplast
entity reference: β-Cryptoxanthin

Reference/BioCyc CPD-7727
type: UnificationXref
id: CPD-7727
db: BioCyc

Reaction212448
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001860 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001632 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C016735 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C019928 Chloroplast/Stoichiometry/1.0
right: Prolycopene
right: Hydroquinone
spontaneous: false
left: (9Z,7'Z,9'Z)-7,8-Dihydrolycopene
left: Quinone
name: (9Z,7'Z,9'Z)-7,8-Dihydrolycopene + 2 Quinone → 2 Hydroquinone + Prolycopene
conversion direction: LEFT_TO_RIGHT

ReactionCatalysis202106
type: Catalysis
controller: beta-carotene 3-hydroxylase 1
controlled: Reaction212462
control type: ACTIVATION

Reference/PubChem-compound 5375200
type: UnificationXref
id: 5375200
db: PubChem-compound

5.2.1.13
type: BiochemicalReaction
participant stoichiometry: Compound/PW C016735 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001754 Chloroplast/Stoichiometry/1.0
right: Lycopene
spontaneous: false
EC number: 5.2.1.13
left: Prolycopene
name: Prolycopene → Lycopene
conversion direction: LEFT_TO_RIGHT

ReactionCatalysis202107
type: Catalysis
controller: beta-carotene isomerase
controlled: Reaction212463
control type: ACTIVATION

Reference/ChEBI CHEBI 48716
type: UnificationXref
id: CHEBI:48716
db: ChEBI

ReactionCatalysis202109
type: Catalysis
controller: Protein LUTEIN DEFICIENT 5, chloroplastic
controlled: 1.4.13.129
control type: ACTIVATION

ReactionCatalysis202102
type: Catalysis
controller: beta-carotene 3-hydroxylase 1
controlled: 1.4.13.129
control type: ACTIVATION

ReactionCatalysis202103
type: Catalysis
controller: Protein LUTEIN DEFICIENT 5, chloroplastic
controlled: 1.4.13.129
control type: ACTIVATION

ReactionCatalysis202104
type: Catalysis
controller: Carotene epsilon-monooxygenase, chloroplastic
controlled: 1.14.14.158
control type: ACTIVATION

ReactionCatalysis202105
type: Catalysis
controller: Carotene epsilon-monooxygenase, chloroplastic
controlled: Reaction212461
control type: ACTIVATION

Reference/PubChem-compound 6384256
type: UnificationXref
id: 6384256
db: PubChem-compound

2.5.1.32
type: BiochemicalReaction
participant stoichiometry: Compound/PW C000170 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C002145 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001758 Chloroplast/Stoichiometry/1.0
right: Prephytoene diphosphate
right: Pyrophosphate
spontaneous: false
EC number: 2.5.1.32
left: Geranylgeranyl-PP
name: 2 Geranylgeranyl-PP → Prephytoene diphosphate + 2 Pyrophosphate
conversion direction: LEFT_TO_RIGHT

15-cis-phytoene desaturase, chloroplastic/chromoplastic
type: Protein
cellular location: Chloroplast
entity reference: 15-cis-phytoene desaturase, chloroplastic/chromoplastic

Reaction212442
type: BiochemicalReaction
participant stoichiometry: Compound/PW C000170 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001758 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001470 Chloroplast/Stoichiometry/1.0
right: Phytoene
right: Pyrophosphate
spontaneous: false
left: Prephytoene diphosphate
name: Prephytoene diphosphate → Phytoene + 2 Pyrophosphate
conversion direction: LEFT_TO_RIGHT

ReactionCatalysis202100
type: Catalysis
controller: Lycopene epsilon cyclase, chloroplastic
controlled: Reaction212457
control type: ACTIVATION

1.3.5.5
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057910 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C001722 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001470 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C011346 Chloroplast/Stoichiometry/2.0
right: Phytofluene
right: plastoquinol-9
spontaneous: false
EC number: 1.3.5.5
left: Phytoene
left: Plastoquinone 9
name: Phytoene + 2 Plastoquinone 9 → Phytofluene + 2 plastoquinol-9
conversion direction: LEFT_TO_RIGHT

ReactionCatalysis202101
type: Catalysis
controller: lycopene beta cyclase
controlled: Reaction212458
control type: ACTIVATION

Reference/HMDB HMDB0001377
type: UnificationXref
id: HMDB0001377
db: HMDB

Reference/ChEBI CHEBI 80427
type: UnificationXref
id: CHEBI:80427
db: ChEBI

Compound/PW C041102 Chloroplast/Stoichiometry/4.0
type: Stoichiometry
physical entity: Reduced ferredoxin
stoichiometric coefficient: 4.0

Compound/PW C001065 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: Oxygen
stoichiometric coefficient: 1.0

Reference/CAS 7773-56-0
type: UnificationXref
id: 7773-56-0
db: CAS

Reference/KEGG Compound C00072
type: UnificationXref
id: C00072
db: KEGG Compound

Reference/KEGG Compound C12287
type: UnificationXref
id: C12287
db: KEGG Compound

Reference/SMPDB SMP0122535
type: UnificationXref
id: SMP0122535
db: SMPDB

Compound/PW C104784/Stoichiometry/1.0
type: Stoichiometry
physical entity: FMN
stoichiometric coefficient: 1.0

Lycopene epsilon cyclase, chloroplastic
type: Protein
cellular location: Chloroplast
entity reference: Lycopene epsilon cyclase, chloroplastic

Reference/HMDB HMDB0000044
type: UnificationXref
id: HMDB0000044
db: HMDB

Reference/PubChem-compound 962
type: UnificationXref
id: 962
db: PubChem-compound

9-cis-Violaxanthin
type: SmallMolecule
cellular location: Cytoplasm
entity reference: 9-cis-Violaxanthin

Reference/HMDB HMDB0038660
type: UnificationXref
id: HMDB0038660
db: HMDB

Reference/UniProt Q07356
type: UnificationXref
id: Q07356
db: UniProt

9-cis-β-Carotene
type: SmallMoleculeReference
xref: Reference/PubChem-compound 9828626
xref: Reference/KEGG Compound C20484
xref: Reference/BioCyc CPD-14646
xref: Reference/HMDB HMDB0112264
xref: Reference/ChEBI CHEBI 67188
xref: Reference/CAS 13312-52-2
chemical formula: C40H56
molecular weight: 536.4382
structure: ChemicalStructure/PW C057881

Ascorbic acid
type: SmallMolecule
cellular location: Chloroplast
entity reference: Ascorbic acid

Reference/CAS 432-70-2
type: UnificationXref
id: 432-70-2
db: CAS

carlactone
type: SmallMoleculeReference
xref: Reference/BioCyc CPD-14649
xref: Reference/ChEBI CHEBI 67190
xref: Reference/KEGG Compound C20693
xref: Reference/PubChem-compound 66559276
chemical formula: C19H26O3
molecular weight: 302.1882
structure: ChemicalStructure/PW C057883

Compound/PW C019928 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: (9Z,7'Z,9'Z)-7,8-Dihydrolycopene
stoichiometric coefficient: 1.0

9-cis-10'-apo-β-carotenal
type: SmallMoleculeReference
xref: Reference/BioCyc CPD-14647
xref: Reference/ChEBI CHEBI 67192
xref: Reference/KEGG Compound C20692
xref: Reference/PubChem-compound 70678813
chemical formula: C27H36O
molecular weight: 376.2766
structure: ChemicalStructure/PW C057882

Reference/HMDB HMDB0039635
type: UnificationXref
id: HMDB0039635
db: HMDB

(2E,4E,6E)-7-hydroxy-4-methylhepta-2,4,6-trienal
type: SmallMoleculeReference
xref: Reference/KEGG Compound C20694
xref: Reference/ChEBI CHEBI 67191
xref: Reference/BioCyc CPD-14650
xref: Reference/PubChem-compound 70678836
chemical formula: C8H10O2
molecular weight: 138.06808
structure: ChemicalStructure/PW C057884

Terpenoid Backbone Biosynthesis
type: Pathway
pathway order: SubPathwayInteractionSteps/SubPathway112684
pathway component: SubPathwayInteraction112684
xref: Reference/SMPDB SMP0121210
xref: Reference/PathWhiz PW122504
name: SubPathway

ChemicalStructure/PW C108661
type: ChemicalStructure
structure format: SMILES

Compound/PW C014903 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: β-Cryptoxanthin
stoichiometric coefficient: 1.0

Compound/PW C108661 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 15,9'-Di-cis-phytofluene
stoichiometric coefficient: 1.0

beta-carotene 3-hydroxylase 1
type: Protein
cellular location: Chloroplast
entity reference: beta-carotene 3-hydroxylase 1

Reference/KEGG Compound C00080
type: UnificationXref
id: C00080
db: KEGG Compound

Phytoene
type: SmallMolecule
cellular location: Chloroplast
entity reference: Phytoene

ChemicalStructure/PW C001065
type: ChemicalStructure
structure format: SMILES
structure data: O=O

ChemicalStructure/PW C108665
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C=C(/C)\C=C\[C@H]1C(C)=CCCC1(C)C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/[C@H]1C(C)=CCCC1(C)C

ChemicalStructure/PW C108664
type: ChemicalStructure
structure format: SMILES
structure data: C\C(CCC1=C(C)CCCC1(C)C)=C/C=C/C(/C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)CCCC1(C)C

Reference/PubChem-compound 5282224
type: UnificationXref
id: 5282224
db: PubChem-compound

Reference/PubChem-compound 5320546
type: UnificationXref
id: 5320546
db: PubChem-compound

ChemicalStructure/PW C108662
type: ChemicalStructure
structure format: SMILES
structure data: CC(C)=CCC\C(C)=C\CC\C(C)=C/C=C/C(/C)=C/C=C\C=C(/C)\C=C\C=C(\C)CC\C=C(/C)CCC=C(C)C

ChemicalStructure/PW C108667
type: ChemicalStructure
structure format: SMILES

ChemicalStructure/PW C108666
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C=C(/C)\C=C\[C@H]1C(C)=CCCC1(C)C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)C[C@@H](O)CC1(C)C

Reference/ChemSpider 394156
type: UnificationXref
id: 394156
db: ChemSpider

Reference/HMDB HMDB0002111
type: UnificationXref
id: HMDB0002111
db: HMDB

Reference/HMDB HMDB0001142
type: UnificationXref
id: HMDB0001142
db: HMDB

Compound/PW C057902 Endoplasmic Reticulum/Stoichiometry/1.0
type: Stoichiometry
physical entity: abscisic acid glucose ester
stoichiometric coefficient: 1.0

Reference/PubChem-compound 6433159
type: UnificationXref
id: 6433159
db: PubChem-compound

Reference/HMDB HMDB0001264
type: UnificationXref
id: HMDB0001264
db: HMDB

Compound/PW C001065 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Oxygen
stoichiometric coefficient: 2.0

Neurosporene
type: SmallMolecule
cellular location: Chloroplast
entity reference: Neurosporene

Reference/KEGG Compound C05414
type: UnificationXref
id: C05414
db: KEGG Compound

Reference/CAS 2361-24-2
type: UnificationXref
id: 2361-24-2
db: CAS

Reference/KEGG Compound C05413
type: UnificationXref
id: C05413
db: KEGG Compound

Reference/PubChem-compound 5282218
type: UnificationXref
id: 5282218
db: PubChem-compound

abscisic aldehyde
type: SmallMoleculeReference
xref: Reference/PubChem-compound 5282224
xref: Reference/KEGG Compound C13455
xref: Reference/BioCyc CPD-692
xref: Reference/ChEBI CHEBI 31157
xref: Reference/ChemSpider 4445405
chemical formula: C15H20O3
molecular weight: 248.14125
structure: ChemicalStructure/PW C057889

Prolycopene
type: SmallMolecule
cellular location: Chloroplast
entity reference: Prolycopene

Reference/CAS 490-83-5
type: UnificationXref
id: 490-83-5
db: CAS

Compound/PW C057901/Stoichiometry/1.0
type: Stoichiometry
physical entity: phaseic acid
stoichiometric coefficient: 1.0

Compound/PW C001758 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Prephytoene diphosphate
stoichiometric coefficient: 1.0

Reference/PubChem-compound 644102
type: UnificationXref
id: 644102
db: PubChem-compound

Reference/ChEBI CHEBI 29073
type: UnificationXref
id: CHEBI:29073
db: ChEBI

Reference/CAS 113472-20-1
type: UnificationXref
id: 113472-20-1
db: CAS

Abscisic acid
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: Abscisic acid

Compound/PW C000721 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: NAD
stoichiometric coefficient: 1.0

Violaxanthin
type: SmallMoleculeReference
xref: Reference/PubChem-compound 53477762
xref: Reference/CAS 126-29-4
xref: Reference/HMDB HMDB0003101
xref: Reference/KEGG Compound C08614
xref: Reference/BioCyc CPD-7196
chemical formula: C40H56O4
molecular weight: 600.41785
structure: ChemicalStructure/PW C001778

Reference/ChEBI CHEBI 31157
type: UnificationXref
id: CHEBI:31157
db: ChEBI

Reference/PubChem-compound 446439
type: UnificationXref
id: 446439
db: PubChem-compound

Reference/PubChem-compound 6440941
type: UnificationXref
id: 6440941
db: PubChem-compound

Neurosporene
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0003114
xref: Reference/KEGG Compound C05431
xref: Reference/ChemSpider 4444347
xref: Reference/ChEBI CHEBI 16833
xref: Reference/BioCyc NEUROSPORENE
xref: Reference/CAS 502-64-7
xref: Reference/PubChem-compound 5280789
chemical formula: C40H58
molecular weight: 538.45386
structure: ChemicalStructure/PW C001780

Reference/KEGG Compound C05431
type: UnificationXref
id: C05431
db: KEGG Compound

Water
type: SmallMoleculeReference
xref: Reference/PubChem-compound 962
xref: Reference/ChEBI CHEBI 15377
xref: Reference/KEGG Compound C00001
xref: Reference/ChemSpider 937
xref: Reference/HMDB HMDB0002111
xref: Reference/CAS 7732-18-5
chemical formula: H2O
molecular weight: 18.010565
structure: ChemicalStructure/PW C001420

Hydrogen peroxide
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0003125
xref: Reference/PubChem-compound 784
xref: Reference/ChemSpider 763
xref: Reference/CAS 7722-84-1
xref: Reference/BioCyc HYDROGEN-PEROXIDE
xref: Reference/ChEBI CHEBI 16240
xref: Reference/KEGG Compound C00027
chemical formula: H2O2
molecular weight: 34.005478
structure: ChemicalStructure/PW C001783

Compound/PW C000437 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: B-Carotene
stoichiometric coefficient: 1.0

Reference/ChemSpider 393046
type: UnificationXref
id: 393046
db: ChemSpider

Reference/HMDB HMDB0003101
type: UnificationXref
id: HMDB0003101
db: HMDB

Reference/BioCyc NADH
type: UnificationXref
id: NADH
db: BioCyc

Reference/BioCyc NAD
type: UnificationXref
id: NAD
db: BioCyc

β-Zeacarotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: β-Zeacarotene

Reference/KEGG Compound C16695
type: UnificationXref
id: C16695
db: KEGG Compound

Compound/PW C104784 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: FMN
stoichiometric coefficient: 1.0

7,8-Dihydro-beta-carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: 7,8-Dihydro-beta-carotene

Reference/PubChem-compound 977
type: UnificationXref
id: 977
db: PubChem-compound

Carotenoid BIosynthesis
type: Pathway
pathway order: PathwayEnzymeReaction/2459891
pathway order: PathwayEnzymeReaction/2459892
pathway order: PathwayEnzymeReaction/2459893
pathway order: PathwayEnzymeReaction/2459850
pathway order: PathwayEnzymeReaction/2459859
pathway order: PathwayEnzymeReaction/2459855
pathway order: PathwayEnzymeReaction/2459899
pathway order: PathwayEnzymeReaction/2459857
pathway order: PathwayEnzymeReaction/2459858
pathway order: PathwayEnzymeReaction/2459851
pathway order: PathwayEnzymeReaction/2459852
pathway order: PathwayEnzymeReaction/2459896
pathway order: PathwaySubPathway/112684
pathway order: PathwayEnzymeReaction/2459853
pathway order: PathwayEnzymeReaction/2459897
pathway order: PathwayEnzymeReaction/2459898
pathway order: PathwayEnzymeReaction/2459880
pathway order: PathwayEnzymeReaction/2459881
pathway order: PathwayEnzymeReaction/2459860
pathway order: PathwayEnzymeReaction/2459882
pathway order: PathwayEnzymeReaction/2459861
pathway order: PathwayEnzymeReaction/2459883
pathway order: PathwayEnzymeReaction/2459848
pathway order: PathwayEnzymeReaction/2459903
pathway order: PathwayEnzymeReaction/2459849
pathway order: PathwayEnzymeReaction/2459904
pathway order: PathwayEnzymeReaction/2459866
pathway order: PathwayEnzymeReaction/2459888
pathway order: PathwayEnzymeReaction/2459867
pathway order: PathwayEnzymeReaction/2459889
pathway order: PathwayEnzymeReaction/2459900
pathway order: PathwayEnzymeReaction/2459846
pathway order: PathwayEnzymeReaction/2459868
pathway order: PathwayEnzymeReaction/2459901
pathway order: PathwayEnzymeReaction/2459847
pathway order: PathwayEnzymeReaction/2459869
pathway order: PathwayEnzymeReaction/2459902
pathway order: PathwayEnzymeReaction/2459862
pathway order: PathwayEnzymeReaction/2459884
pathway order: PathwayEnzymeReaction/2459863
pathway order: PathwayEnzymeReaction/2459885
pathway order: PathwayEnzymeReaction/2459864
pathway order: PathwayEnzymeReaction/2459886
pathway order: PathwayEnzymeReaction/2459865
pathway order: PathwayEnzymeReaction/2459887
pathway component: Reaction212455
pathway component: 5.5.1.18
pathway component: Reaction212457
pathway component: Reaction212458
pathway component: 1.4.13.129
pathway component: ReactionCatalysis202117
pathway component: ReactionCatalysis202118
pathway component: ReactionCatalysis202119
pathway component: ReactionCatalysis202113
pathway component: ReactionCatalysis202114
pathway component: ReactionCatalysis202115
pathway component: Reaction212451
pathway component: Reaction212452
pathway component: ReactionCatalysis202110
pathway component: Reaction212453
pathway component: ReactionCatalysis202111
pathway component: Reaction212454
pathway component: ReactionCatalysis202112
pathway component: Terpenoid Backbone Biosynthesis
pathway component: Reaction212466
pathway component: Reaction212467
pathway component: Reaction212468
pathway component: Reaction212469
pathway component: 1.14.14.158
pathway component: Reaction212461
pathway component: ReactionCatalysis202087
pathway component: Reaction212462
pathway component: ReactionCatalysis202120
pathway component: ReactionCatalysis202088
pathway component: Reaction212463
pathway component: ReactionCatalysis202089
pathway component: Reaction212465
pathway component: ReactionCatalysis202084

Reference/HMDB HMDB0059597
type: UnificationXref
id: HMDB0059597
db: HMDB

Reference/ChEBI CHEBI 23758
type: UnificationXref
id: CHEBI:23758
db: ChEBI

Reference/ChEBI CHEBI 10223
type: UnificationXref
id: CHEBI:10223
db: ChEBI

Reference/KEGG Compound C05433
type: UnificationXref
id: C05433
db: KEGG Compound

Reference/KEGG Compound C05432
type: UnificationXref
id: C05432
db: KEGG Compound

Reference/KEGG Compound C05435
type: UnificationXref
id: C05435
db: KEGG Compound

ChemicalStructure/PW C002025
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C=C(/C)\C=C\C1C(C)=CCCC1(C)C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)CCCC1(C)C

Reference/ChEBI CHEBI 17090
type: UnificationXref
id: CHEBI:17090
db: ChEBI

Compound/PW C001813 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Lutein
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0003114
type: UnificationXref
id: HMDB0003114
db: HMDB

Reference/HMDB HMDB0002268
type: UnificationXref
id: HMDB0002268
db: HMDB

ChemicalStructure/PW C002145
type: ChemicalStructure
structure format: SMILES

Plastoquinone 9
type: SmallMoleculeReference
xref: Reference/ChemSpider 10627857
xref: Reference/KEGG Compound C10385
xref: Reference/HMDB HMDB0030130
xref: Reference/CAS 4299-57-4
chemical formula: C53H80O2
molecular weight: 748.61584
structure: ChemicalStructure/PW C011346

NAD
type: SmallMolecule
cellular location: Cytoplasm
entity reference: NAD

Reference/ChEBI CHEBI 15903
type: UnificationXref
id: CHEBI:15903
db: ChEBI

Reference/HMDB HMDB0003233
type: UnificationXref
id: HMDB0003233
db: HMDB

ChemicalStructure/PW C019928
type: ChemicalStructure
structure format: SMILES

Reference/PubChem-compound 9828626
type: UnificationXref
id: 9828626
db: PubChem-compound

Abscisic acid
type: SmallMolecule
cellular location: Cytoplasm
entity reference: Abscisic acid

Reference/ChemSpider 10627857
type: UnificationXref
id: 10627857
db: ChemSpider

Reference/ChemSpider 4904571
type: UnificationXref
id: 4904571
db: ChemSpider

Abscisic-aldehyde oxidase
type: Protein
cellular location: Cytoplasm
entity reference: Abscisic-aldehyde oxidase

Reference/TAXONOMY 3702
type: UnificationXref
id: 3702
db: TAXONOMY

Reference/ChemSpider 4938343
type: UnificationXref
id: 4938343
db: ChemSpider

Reference/CAS 27664-65-9
type: UnificationXref
id: 27664-65-9
db: CAS

Reference/ChEBI CHEBI 27705
type: UnificationXref
id: CHEBI:27705
db: ChEBI

ChemicalStructure/PW C001778
type: ChemicalStructure
structure format: SMILES

Reference/ChemSpider 9093791
type: UnificationXref
id: 9093791
db: ChemSpider

Reference/ChEBI CHEBI 58210
type: UnificationXref
id: CHEBI:58210
db: ChEBI

B-Carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: B-Carotene

ChemicalStructure/PW C001780
type: ChemicalStructure
structure format: SMILES

Reference/PubChem-compound 5280489
type: UnificationXref
id: 5280489
db: PubChem-compound

Reference/PubChem-compound 66559276
type: UnificationXref
id: 66559276
db: PubChem-compound

ChemicalStructure/PW C001420
type: ChemicalStructure
structure format: SMILES
structure data: O

ChemicalStructure/PW C001783
type: ChemicalStructure
structure format: SMILES
structure data: OO

ChemicalStructure/PW C104784
type: ChemicalStructure
structure format: SMILES

Reference/CAS 13312-52-2
type: UnificationXref
id: 13312-52-2
db: CAS

β-D-Glucose
type: SmallMoleculeReference
xref: Reference/PubChem-compound 64689
xref: Reference/ChemSpider 58238
xref: Reference/HMDB HMDB0000516
xref: Reference/KEGG Compound C00221
xref: Reference/CAS 492-61-5
xref: Reference/ChEBI CHEBI 15903
chemical formula: C6H12O6
molecular weight: 180.06339
structure: ChemicalStructure/PW C000395

Ascorbic acid
type: SmallMoleculeReference
xref: Reference/BioCyc ASCORBATE
xref: Reference/ChemSpider 10189562
xref: Reference/KEGG Compound C00072
xref: Reference/ChEBI CHEBI 29073
xref: Reference/CAS 50-81-7
xref: Reference/PubChem-compound 54670067
xref: Reference/HMDB HMDB0000044
chemical formula: C6H8O6
molecular weight: 176.03209
structure: ChemicalStructure/PW C000031

Reference/CAS 72746-33-9
type: UnificationXref
id: 72746-33-9
db: CAS

Hydrogen Ion
type: SmallMolecule
cellular location: Chloroplast
entity reference: Hydrogen Ion

Reference/HMDB HMDB0035623
type: UnificationXref
id: HMDB0035623
db: HMDB

ReactionCatalysis202087
type: Catalysis
controller: 15-cis-phytoene desaturase, chloroplastic/chromoplastic
controlled: Reaction212444
control type: ACTIVATION

ReactionCatalysis202088
type: Catalysis
controller: 15-cis-phytoene desaturase, chloroplastic/chromoplastic
controlled: Reaction212445
control type: ACTIVATION

ReactionCatalysis202089
type: Catalysis
controller: 15-cis-zeta-carotene isomerase, chloroplastic
controlled: 5.2.1.12
control type: ACTIVATION

Reference/KEGG Compound C08601
type: UnificationXref
id: C08601
db: KEGG Compound

Compound/PW C040034 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Hydrogen Ion
stoichiometric coefficient: 1.0

ReactionCatalysis202084
type: Catalysis
controller: Phytoene synthase, chloroplastic
controlled: 2.5.1.32
control type: ACTIVATION

ReactionCatalysis202085
type: Catalysis
controller: Phytoene synthase, chloroplastic
controlled: Reaction212442
control type: ACTIVATION

5.5.1.19
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057905 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001754 Chloroplast/Stoichiometry/1.0
right: γ-Carotene
spontaneous: false
EC number: 5.5.1.19
left: Lycopene
name: Lycopene → γ-Carotene
conversion direction: LEFT_TO_RIGHT

SubPathwayInteraction112684
type: Interaction
name: SubPathwayReaction
name: SubPathway112684Reaction
participant: Geranylgeranyl-PP

ReactionCatalysis202086
type: Catalysis
controller: 15-cis-phytoene desaturase, chloroplastic/chromoplastic
controlled: 1.3.5.5
control type: ACTIVATION

Reaction47519
type: BiochemicalReaction
participant stoichiometry: Compound/PW C057905 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000437 Chloroplast/Stoichiometry/1.0
right: B-Carotene
spontaneous: false
left: γ-Carotene
name: γ-Carotene → B-Carotene
conversion direction: LEFT_TO_RIGHT

Water
type: SmallMolecule
cellular location: Cytoplasm
entity reference: Water

Compound/PW C108665 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: epsilon,epsilon-Carotene
stoichiometric coefficient: 1.0

Prolycopene
type: SmallMoleculeReference
xref: Reference/PubChem-compound 10918539
xref: Reference/KEGG Compound C15858
xref: Reference/ChemSpider 9093791
xref: Reference/ChEBI CHEBI 62466
xref: Reference/CAS 2361-24-2
xref: Reference/HMDB HMDB0035776
chemical formula: C40H56
molecular weight: 536.4382
structure: ChemicalStructure/PW C016735

ChemicalStructure/PW C011346
type: ChemicalStructure
structure format: SMILES

Reference/ChEBI CHEBI 15846
type: UnificationXref
id: CHEBI:15846
db: ChEBI

Reference/CAS 502-64-7
type: UnificationXref
id: 502-64-7
db: CAS

Reference/ChEBI CHEBI 17908
type: UnificationXref
id: CHEBI:17908
db: ChEBI

Compound/PW C000170 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Pyrophosphate
stoichiometric coefficient: 2.0

Compound/PW C001531 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: α-Cryptoxanthin
stoichiometric coefficient: 1.0

Reference/KEGG Compound C09707
type: UnificationXref
id: C09707
db: KEGG Compound

ChemicalStructure/PW C001754
type: ChemicalStructure
structure format: SMILES

Reference/PubChem-compound 1038
type: UnificationXref
id: 1038
db: PubChem-compound

Reference/KEGG Compound C08614
type: UnificationXref
id: C08614
db: KEGG Compound

Reference/HMDB HMDB0035776
type: UnificationXref
id: HMDB0035776
db: HMDB

ChemicalStructure/PW C001758
type: ChemicalStructure
structure format: SMILES

Reference/ChEBI CHEBI 67190
type: UnificationXref
id: CHEBI:67190
db: ChEBI

Reference/ChemSpider 10189562
type: UnificationXref
id: 10189562
db: ChemSpider

Reference/ChEBI CHEBI 67191
type: UnificationXref
id: CHEBI:67191
db: ChEBI

Reference/ChEBI CHEBI 67192
type: UnificationXref
id: CHEBI:67192
db: ChEBI

Reference/PubChem-compound 5281234
type: UnificationXref
id: 5281234
db: PubChem-compound

Compound/PW C057881 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 9-cis-β-Carotene
stoichiometric coefficient: 1.0

Reference/BioCyc CPD1F-114
type: UnificationXref
id: CPD1F-114
db: BioCyc

Reference/ChemSpider 24808182
type: UnificationXref
id: 24808182
db: ChemSpider

FMNH2
type: SmallMolecule
cellular location: Chloroplast
entity reference: FMNH2

Compound/PW C020466 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: Abscisic alcohol
stoichiometric coefficient: 1.0

Compound/PW C000395 Endoplasmic Reticulum/Stoichiometry/1.0
type: Stoichiometry
physical entity: β-D-Glucose
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 16908
type: UnificationXref
id: CHEBI:16908
db: ChEBI

γ-Carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: γ-Carotene

δ-Carotene
type: SmallMoleculeReference
xref: Reference/CAS 472-92-4
xref: Reference/KEGG Compound C08586
xref: Reference/HMDB HMDB0036925
xref: Reference/ChEBI CHEBI 27705
chemical formula: C40H56
molecular weight: 536.4382
structure: ChemicalStructure/PW C017812

Reference/PubChem-compound 445395
type: UnificationXref
id: 445395
db: PubChem-compound

ChemicalStructure/PW C000437
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)CCCC1(C)C

Reference/CAS 127-40-2
type: UnificationXref
id: 127-40-2
db: CAS

ChemicalStructure/PW C001766
type: ChemicalStructure
structure format: SMILES
structure data: CC(C)=CCC\C(C)=C\CC\C(C)=C/C=C/C(/C)=C/C=C/C=C(\C)/C=C/C=C(/C)CC\C=C(/C)CCC=C(C)C

Reference/PubChem-compound 4650
type: UnificationXref
id: 4650
db: PubChem-compound

Phytoene
type: SmallMoleculeReference
xref: Reference/ChemSpider 4444344
xref: Reference/ChEBI CHEBI 8191
xref: Reference/HMDB HMDB0002181
xref: Reference/PubChem-compound 5280784
xref: Reference/CAS 540-04-5
xref: Reference/KEGG Compound C05413
chemical formula: C40H64
molecular weight: 544.5008
structure: ChemicalStructure/PW C001470

Compound/PW C020466/Stoichiometry/1.0
type: Stoichiometry
physical entity: Abscisic alcohol
stoichiometric coefficient: 1.0

beta-carotene isomerase
type: Protein
cellular location: Chloroplast
entity reference: beta-carotene isomerase

9-cis-beta-carotene 9',10'-cleavage dioxygenase
type: Protein
cellular location: Chloroplast
entity reference: 9-cis-beta-carotene 9',10'-cleavage dioxygenase

carlactone synthase
type: Protein
cellular location: Chloroplast
entity reference: carlactone synthase

ChemicalStructure/PW C001531
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C=C(/C)\C=C\C1C(C)=C[C@H](O)CC1(C)C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)CCCC1(C)C

Reference/KEGG Compound C02094
type: UnificationXref
id: C02094
db: KEGG Compound

Hydrogen Ion
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: Hydrogen Ion

Reference/ChEBI CHEBI 15948
type: UnificationXref
id: CHEBI:15948
db: ChEBI

Reference/ChemSpider 4444129
type: UnificationXref
id: 4444129
db: ChemSpider

Reference/ChEBI CHEBI 67188
type: UnificationXref
id: CHEBI:67188
db: ChEBI

Reference/HMDB HMDB0000561
type: UnificationXref
id: HMDB0000561
db: HMDB

β-D-Glucose
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: β-D-Glucose

Compound/PW C040034 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: Hydrogen Ion
stoichiometric coefficient: 1.0

Reference/BioCyc 236-TRICHLOROHYDROQUINONE
type: UnificationXref
id: 236-TRICHLOROHYDROQUINONE
db: BioCyc

Reference/ChEBI CHEBI 28838
type: UnificationXref
id: CHEBI:28838
db: ChEBI

Reference/BioCyc CPD-6641
type: UnificationXref
id: CPD-6641
db: BioCyc

Reference/BioCyc CPD-692
type: UnificationXref
id: CPD-692
db: BioCyc

abscisic acid glucose ester
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: abscisic acid glucose ester

Reference/CAS 58-68-4
type: UnificationXref
id: 58-68-4
db: CAS

Violaxanthin
type: SmallMolecule
cellular location: Chloroplast
entity reference: Violaxanthin

Compound/PW C002145 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Geranylgeranyl-PP
stoichiometric coefficient: 2.0

Oxygen
type: SmallMolecule
entity reference: Oxygen

Compound/PW C057910 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: plastoquinol-9
stoichiometric coefficient: 2.0

Compound/PW C000977 Chloroplast/Stoichiometry/2.0
type: Stoichiometry
physical entity: Dehydroascorbic acid
stoichiometric coefficient: 2.0

Reference/HMDB HMDB0002871
type: UnificationXref
id: HMDB0002871
db: HMDB

antheraxanthin
type: SmallMolecule
cellular location: Chloroplast
entity reference: antheraxanthin

Compound/PW C108664 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: 7,8-Dihydro-beta-carotene
stoichiometric coefficient: 1.0

9-cis-Violaxanthin
type: SmallMolecule
entity reference: 9-cis-Violaxanthin

ChemicalStructure/PW C017812
type: ChemicalStructure
structure format: SMILES
structure data: CC(C)=CCC\C(C)=C/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(\C)/C=C/C=C(/C)\C=C\C1C(C)=CCCC1(C)C

FMN
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00061
xref: Reference/ChEBI CHEBI 58210
xref: Reference/PubChem-compound 44229199
chemical formula: C17H18N4O9P
molecular weight: 453.0828
structure: ChemicalStructure/PW C104784

Reference/PubChem-compound 447277
type: UnificationXref
id: 447277
db: PubChem-compound

Reference/UniProt Q9M9Y8
type: UnificationXref
id: Q9M9Y8
db: UniProt

Reference/PubChem-compound 5280791
type: UnificationXref
id: 5280791
db: PubChem-compound

Reference/ChEBI CHEBI 27740
type: UnificationXref
id: CHEBI:27740
db: ChEBI

Geranylgeranyl-PP
type: SmallMolecule
entity reference: Geranylgeranyl-PP
name: SubPathwayOutput

Geranylgeranyl-PP
type: SmallMoleculeReference
xref: Reference/CAS 6699-20-3
xref: Reference/ChemSpider 394418
xref: Reference/PubChem-compound 447277
xref: Reference/KEGG Compound C00353
xref: Reference/BioCyc GERANYLGERANYL-PP
xref: Reference/ChEBI CHEBI 48861
xref: Reference/HMDB HMDB0004486
chemical formula: C20H36O7P2
molecular weight: 450.19363
structure: ChemicalStructure/PW C002145

α-Carotene
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 28425
xref: Reference/ChemSpider 3571861
xref: Reference/BioCyc CPD1F-118
xref: Reference/PubChem-compound 4369188
xref: Reference/CAS 432-70-2
xref: Reference/KEGG Compound C05433
xref: Reference/HMDB HMDB0003993
chemical formula: C40H56
molecular weight: 536.4382
structure: ChemicalStructure/PW C002025

Reference/ChEBI CHEBI 27867
type: UnificationXref
id: CHEBI:27867
db: ChEBI

(9Z,7'Z,9'Z)-7,8-Dihydrolycopene
type: SmallMoleculeReference
xref: Reference/ChemSpider 30777317
xref: Reference/CAS 10467-46-6
xref: Reference/HMDB HMDB0039089
chemical formula: C40H58
molecular weight: 538.45386
structure: ChemicalStructure/PW C019928

Reference/ChEBI CHEBI 48861
type: UnificationXref
id: CHEBI:48861
db: ChEBI

ChemicalStructure/PW C001470
type: ChemicalStructure
structure format: SMILES

Compound/PW C108667/Stoichiometry/1.0
type: Stoichiometry
physical entity: 9-cis-Violaxanthin
stoichiometric coefficient: 1.0

Oxygen
type: SmallMolecule
cellular location: Cytoplasm
entity reference: Oxygen

Reference/ChemSpider 394418
type: UnificationXref
id: 394418
db: ChemSpider

Reference/ChEBI CHEBI 16833
type: UnificationXref
id: CHEBI:16833
db: ChEBI

Compound/PW C017036 Endoplasmic Reticulum/Stoichiometry/1.0
type: Stoichiometry
physical entity: Abscisic acid
stoichiometric coefficient: 1.0

ReactionCatalysis202098
type: Catalysis
controller: lycopene beta cyclase
controlled: Reaction212455
control type: ACTIVATION

Compound/PW C001722 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Phytofluene
stoichiometric coefficient: 1.0

ReactionCatalysis202099
type: Catalysis
controller: Lycopene epsilon cyclase, chloroplastic
controlled: 5.5.1.18
control type: ACTIVATION

Reference/ChemSpider 4945177
type: UnificationXref
id: 4945177
db: ChemSpider

ReactionCatalysis202094
type: Catalysis
controller: 15-cis-phytoene desaturase, chloroplastic/chromoplastic
controlled: Reaction212451
control type: ACTIVATION

Pyrophosphate
type: SmallMoleculeReference
xref: Reference/PubChem-compound 644102
xref: Reference/BioCyc PPI
xref: Reference/ChemSpider 559142
xref: Reference/ChEBI CHEBI 18361
xref: Reference/HMDB HMDB0000250
xref: Reference/CAS 14000-31-8
xref: Reference/KEGG Compound C00013
chemical formula: O7P2
molecular weight: 173.91193
structure: ChemicalStructure/PW C000170

ReactionCatalysis202095
type: Catalysis
controller: Zeta-carotene desaturase, chloroplastic/chromoplastic
controlled: Reaction212452
control type: ACTIVATION

ReactionCatalysis202096
type: Catalysis
controller: Zeta-carotene desaturase, chloroplastic/chromoplastic
controlled: Reaction212453
control type: ACTIVATION

ReactionCatalysis202097
type: Catalysis
controller: lycopene beta cyclase
controlled: Reaction212454
control type: ACTIVATION

15,9'-Di-cis-phytofluene
type: SmallMoleculeReference
xref: Reference/PubChem-compound 51351778
chemical formula: C40H62
molecular weight: 542.48517
structure: ChemicalStructure/PW C108661

ReactionCatalysis202090
type: Catalysis
controller: Zeta-carotene desaturase, chloroplastic/chromoplastic
controlled: 1.3.5.6
control type: ACTIVATION

NADH
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0001487
xref: Reference/CAS 58-68-4
xref: Reference/PubChem-compound 439153
xref: Reference/BioCyc NADH
xref: Reference/ChemSpider 388299
xref: Reference/KEGG Compound C00004
xref: Reference/ChEBI CHEBI 16908
chemical formula: C21H29N7O14P2
molecular weight: 665.12476
structure: ChemicalStructure/PW C001144

Hydrogen peroxide
type: SmallMolecule
cellular location: Cytoplasm
entity reference: Hydrogen peroxide

9,9',15-Tri-cis-zeta-carotene
type: SmallMoleculeReference
xref: Reference/PubChem-compound 24755586
chemical formula: C40H60
molecular weight: 540.4695
structure: ChemicalStructure/PW C108662

ReactionCatalysis202091
type: Catalysis
controller: Zeta-carotene desaturase, chloroplastic/chromoplastic
controlled: Reaction212448
control type: ACTIVATION

ReactionCatalysis202092
type: Catalysis
controller: Prolycopene isomerase, chloroplastic
controlled: 5.2.1.13
control type: ACTIVATION

Compound/PW C001420 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: Water
stoichiometric coefficient: 1.0

7,8-Dihydro-beta-carotene
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 80427
chemical formula: C40H58
molecular weight: 538.45386
structure: ChemicalStructure/PW C108664

epsilon,epsilon-Carotene
type: SmallMoleculeReference
xref: Reference/PubChem-compound 446439
chemical formula: C40H56
molecular weight: 536.4382
structure: ChemicalStructure/PW C108665

Zeinoxanthin
type: SmallMoleculeReference
xref: Reference/PubChem-compound 5281234
chemical formula: C40H56O
molecular weight: 552.4331
structure: ChemicalStructure/PW C108666

9-cis-Violaxanthin
type: SmallMoleculeReference
xref: Reference/PubChem-compound 5282218
chemical formula: C40H56O4
molecular weight: 600.41785
structure: ChemicalStructure/PW C108667

Compound/PW C040034 Chloroplast/Stoichiometry/4.0
type: Stoichiometry
physical entity: Hydrogen Ion
stoichiometric coefficient: 4.0

Reference/CAS 502-65-8
type: UnificationXref
id: 502-65-8
db: CAS

15,9'-Di-cis-phytofluene
type: SmallMolecule
cellular location: Chloroplast
entity reference: 15,9'-Di-cis-phytofluene

Compound/PW C001780 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Neurosporene
stoichiometric coefficient: 1.0

abscisic acid glucose ester beta-glucosidase
type: Protein
cellular location: Endoplasmic Reticulum
entity reference: abscisic acid glucose ester beta-glucosidase

α-Carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: α-Carotene

Reference/UniProt Q9C826
type: UnificationXref
id: Q9C826
db: UniProt

Reference/CAS 4299-57-4
type: UnificationXref
id: 4299-57-4
db: CAS

Reference/ChEBI CHEBI 22151
type: UnificationXref
id: CHEBI:22151
db: ChEBI

Reference/ChemSpider 3571861
type: UnificationXref
id: 3571861
db: ChemSpider

Water
type: SmallMolecule
cellular location: Chloroplast
entity reference: Water

Reference/GENE ONTOLOGY GO 0005737
type: UnificationXref
id: GO:0005737
db: GENE ONTOLOGY

Reference/HMDB HMDB0002789
type: UnificationXref
id: HMDB0002789
db: HMDB

epsilon,epsilon-Carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: epsilon,epsilon-Carotene

Reference/HMDB HMDB0003993
type: UnificationXref
id: HMDB0003993
db: HMDB

xanthoxin dehydrogenase
type: ProteinReference
xref: Reference/UniProt Q9C826
organism: Arabidopsis thaliana

Reference/PubChem-compound 24755586
type: UnificationXref
id: 24755586
db: PubChem-compound

carlactone synthase
type: ProteinReference
xref: Reference/UniProt Q8VY26
organism: Arabidopsis thaliana

9-cis-beta-carotene 9',10'-cleavage dioxygenase
type: ProteinReference
xref: Reference/UniProt Q7XJM2
organism: Arabidopsis thaliana

Endoplasmic Reticulum
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0005783

NADH
type: SmallMolecule
cellular location: Cytoplasm
entity reference: NADH

beta-carotene isomerase
type: ProteinReference
xref: Reference/UniProt Q7XA78
organism: Arabidopsis thaliana

ChemicalStructure/PW C000721
type: ChemicalStructure
structure format: SMILES

β-Ionone
type: SmallMolecule
cellular location: Chloroplast
entity reference: β-Ionone

Reference/PubChem-compound 23724629
type: UnificationXref
id: 23724629
db: PubChem-compound

ChemicalStructure/PW C001813
type: ChemicalStructure
structure format: SMILES

Reference/ChemSpider 5682
type: UnificationXref
id: 5682
db: ChemSpider

Prephytoene diphosphate
type: SmallMolecule
cellular location: Chloroplast
entity reference: Prephytoene diphosphate

Protein LUTEIN DEFICIENT 5, chloroplastic
type: Protein
cellular location: Chloroplast
entity reference: Protein LUTEIN DEFICIENT 5, chloroplastic

Plastoquinone 9
type: SmallMolecule
cellular location: Chloroplast
entity reference: Plastoquinone 9

Reference/ChemSpider 30791985
type: UnificationXref
id: 30791985
db: ChemSpider

Reference/PubChem-compound 210328
type: UnificationXref
id: 210328
db: PubChem-compound

Reference/ChEBI CHEBI 62426
type: UnificationXref
id: CHEBI:62426
db: ChEBI

Compound/PW C000891/Stoichiometry/1.0
type: Stoichiometry
physical entity: FMNH2
stoichiometric coefficient: 1.0

Carotene epsilon-monooxygenase, chloroplastic
type: Protein
cellular location: Chloroplast
entity reference: Carotene epsilon-monooxygenase, chloroplastic

Reference/ChemSpider 4445405
type: UnificationXref
id: 4445405
db: ChemSpider

Reference/CAS 14000-31-8
type: UnificationXref
id: 14000-31-8
db: CAS

Reference/ChemSpider 4444421
type: UnificationXref
id: 4444421
db: ChemSpider

Reference/ChEBI CHEBI 17513
type: UnificationXref
id: CHEBI:17513
db: ChEBI

Reference/ChemSpider 30777317
type: UnificationXref
id: 30777317
db: ChemSpider

ChemicalStructure/PW C001707
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C=C(/C)\C=C\C1=C(C)C[C@@H](O)CC1(C)C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)C[C@@H](O)CC1(C)C

β-Zeacarotene
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0035623
xref: Reference/CAS 514-90-9
chemical formula: C40H58
molecular weight: 538.45386
structure: ChemicalStructure/PW C016588

Lycopene
type: SmallMolecule
cellular location: Chloroplast
entity reference: Lycopene

Reference/HMDB HMDB0033844
type: UnificationXref
id: HMDB0033844
db: HMDB

Reference/ChEBI CHEBI 35165
type: UnificationXref
id: CHEBI:35165
db: ChEBI

ChemicalStructure/PW C000977
type: ChemicalStructure
structure format: SMILES
structure data: [H][C@@]1(OC(=O)C(=O)C1=O)[C@H](O)CO

Compound/PW C001420 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Water
stoichiometric coefficient: 1.0

FMN
type: SmallMolecule
cellular location: Chloroplast
entity reference: FMN

Reference/ChEBI CHEBI 27547
type: UnificationXref
id: CHEBI:27547
db: ChEBI

Water
type: SmallMolecule
cellular location: Endoplasmic Reticulum
entity reference: Water

Reference/PubChem-compound 51351778
type: UnificationXref
id: 51351778
db: PubChem-compound

Compound/PW C057906 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: antheraxanthin
stoichiometric coefficient: 1.0

Cytoplasm
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0005737

Abscisic-aldehyde oxidase
type: ProteinReference
xref: Reference/UniProt Q7G9P4
organism: Arabidopsis thaliana

1.13.11.68
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057881 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C017456 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057882 Chloroplast/Stoichiometry/1.0
right: 9-cis-10'-apo-β-carotenal
right: β-Ionone
spontaneous: false
EC number: 1.13.11.68
left: Oxygen
left: 9-cis-β-Carotene
name: 9-cis-β-Carotene + Oxygen → 9-cis-10'-apo-β-carotenal + β-Ionone
conversion direction: LEFT_TO_RIGHT

1.13.11.69
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001065 Chloroplast/Stoichiometry/2.0
participant stoichiometry: Compound/PW C057883 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057884 Chloroplast/Stoichiometry/1.0
participant stoichiometry: Compound/PW C057882 Chloroplast/Stoichiometry/1.0
right: carlactone
right: (2E,4E,6E)-7-hydroxy-4-methylhepta-2,4,6-trienal
spontaneous: false
EC number: 1.13.11.69
left: Oxygen
left: 9-cis-10'-apo-β-carotenal
name: 9-cis-10'-apo-β-carotenal + 2 Oxygen → (2E,4E,6E)-7-hydroxy-4-methylhepta-2,4,6-trienal + carlactone
conversion direction: LEFT_TO_RIGHT

ChemicalStructure/PW C057883
type: ChemicalStructure
structure format: SMILES

ChemicalStructure/PW C057884
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C=O)=C/C=C/O

Compound/PW C108666 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Zeinoxanthin
stoichiometric coefficient: 1.0

Arabidopsis thaliana
type: BioSource
xref: Reference/TAXONOMY 3702

Reference/ChemSpider 388299
type: UnificationXref
id: 388299
db: ChemSpider

ChemicalStructure/PW C057881
type: ChemicalStructure
structure format: SMILES
structure data: C/C(/C=C/C=C(/C)\C=C\C1=C(C)CCCC1(C)C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C

Reference/KEGG Compound C08579
type: UnificationXref
id: C08579
db: KEGG Compound

ChemicalStructure/PW C057882
type: ChemicalStructure
structure format: SMILES
structure data: [H]C(=O)\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C

Hydrogen Ion
type: SmallMolecule
cellular location: Cytoplasm
entity reference: Hydrogen Ion

Reference/KEGG Compound C08586
type: UnificationXref
id: C08586
db: KEGG Compound

Oxygen
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0001377
xref: Reference/ChemSpider 952
xref: Reference/KEGG Compound C00007
xref: Reference/ChEBI CHEBI 15379
xref: Reference/PubChem-compound 977
xref: Reference/BioCyc CPD-6641
xref: Reference/CAS 7782-44-7
chemical formula: O2
molecular weight: 31.98983
structure: ChemicalStructure/PW C001065

Reference/PubChem-compound 5280784
type: UnificationXref
id: 5280784
db: PubChem-compound

Quinone
type: SmallMolecule
cellular location: Chloroplast
entity reference: Quinone

Reference/ChEBI CHEBI 16509
type: UnificationXref
id: CHEBI:16509
db: ChEBI

carlactone
type: SmallMolecule
cellular location: Chloroplast
entity reference: carlactone

Reference/PubChem-compound 638014
type: UnificationXref
id: 638014
db: PubChem-compound

Reference/UniProt Q8VY26
type: UnificationXref
id: Q8VY26
db: UniProt

Reference/GENE ONTOLOGY GO 0005783
type: UnificationXref
id: GO:0005783
db: GENE ONTOLOGY

Reference/PubChem-compound 5280789
type: UnificationXref
id: 5280789
db: PubChem-compound

(2E,4E,6E)-7-hydroxy-4-methylhepta-2,4,6-trienal
type: SmallMolecule
cellular location: Chloroplast
entity reference: (2E,4E,6E)-7-hydroxy-4-methylhepta-2,4,6-trienal

Zeta-carotene desaturase, chloroplastic/chromoplastic
type: Protein
cellular location: Chloroplast
entity reference: Zeta-carotene desaturase, chloroplastic/chromoplastic

Reference/KEGG Compound C20694
type: UnificationXref
id: C20694
db: KEGG Compound

Reference/KEGG Compound C20693
type: UnificationXref
id: C20693
db: KEGG Compound

Reference/KEGG Compound C20692
type: UnificationXref
id: C20692
db: KEGG Compound

ChemicalStructure/PW C017036
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C1(O)C(C)=CC(=O)CC1(C)C)=C/C(O)=O

Reference/ChemSpider 4489
type: UnificationXref
id: 4489
db: ChemSpider

Reference/BioCyc CPD-8130
type: UnificationXref
id: CPD-8130
db: BioCyc

Phytoene synthase, chloroplastic
type: Protein
cellular location: Chloroplast
entity reference: Phytoene synthase, chloroplastic

Reference/UniProt Q9FGC7
type: UnificationXref
id: Q9FGC7
db: UniProt

Compound/PW C017456 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: β-Ionone
stoichiometric coefficient: 1.0

Reference/CAS 7782-44-7
type: UnificationXref
id: 7782-44-7
db: CAS

phaseic acid
type: SmallMolecule
entity reference: phaseic acid

8'-hydroxyabscisate
type: SmallMolecule
entity reference: 8'-hydroxyabscisate

8'-hydroxyabscisate
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 58490
xref: Reference/BioCyc CPD-7234
xref: Reference/KEGG Compound C15514
xref: Reference/PubChem-compound 25245404
chemical formula: C15H19O5
molecular weight: 279.1238
structure: ChemicalStructure/PW C057900

abscisic acid glucose ester
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 22151
xref: Reference/PubChem-compound 46173811
xref: Reference/BioCyc CPD-7727
xref: Reference/KEGG Compound C15970
chemical formula: C21H30O9
molecular weight: 426.189
structure: ChemicalStructure/PW C057902

phaseic acid
type: SmallMoleculeReference
xref: Reference/BioCyc CPD-7725
xref: Reference/ChEBI CHEBI 28205
xref: Reference/KEGG Compound C09707
xref: Reference/PubChem-compound 25244821
chemical formula: C15H20O5
molecular weight: 280.13107
structure: ChemicalStructure/PW C057901

ChemicalStructure/PW C057889
type: ChemicalStructure
structure format: SMILES
structure data: [H]\C(C=O)=C(/C)\C(\[H])=C(/[H])[C@@]1(O)C(C)=CC(=O)CC1(C)C

Reference/CAS 123-31-9
type: UnificationXref
id: 123-31-9
db: CAS

antheraxanthin
type: SmallMoleculeReference
xref: Reference/PubChem-compound 25244322
xref: Reference/ChEBI CHEBI 27867
xref: Reference/BioCyc CPD1F-131
xref: Reference/KEGG Compound C08579
chemical formula: C40H56O3
molecular weight: 584.423
structure: ChemicalStructure/PW C057906

Reference/PubChem-compound 24883415
type: UnificationXref
id: 24883415
db: PubChem-compound

Reference/CAS 24480-38-4
type: UnificationXref
id: 24480-38-4
db: CAS

γ-Carotene
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 27740
xref: Reference/BioCyc CPD1F-126
xref: Reference/PubChem-compound 5280791
xref: Reference/ChemSpider 4444349
xref: Reference/HMDB HMDB0112262
xref: Reference/CAS 472-93-5
xref: Reference/KEGG Compound C05435
chemical formula: C40H56
molecular weight: 536.4382
structure: ChemicalStructure/PW C057905

Reference/UniProt Q7XJM2
type: UnificationXref
id: Q7XJM2
db: UniProt

Prolycopene isomerase, chloroplastic
type: Protein
cellular location: Chloroplast
entity reference: Prolycopene isomerase, chloroplastic

Compound/PW C001470 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: Phytoene
stoichiometric coefficient: 1.0

Reference/PubChem-compound 5280899
type: UnificationXref
id: 5280899
db: PubChem-compound

Compound/PW C001783 Cytoplasm/Stoichiometry/1.0
type: Stoichiometry
physical entity: Hydrogen peroxide
stoichiometric coefficient: 1.0

Reference/UniProt Q38893
type: UnificationXref
id: Q38893
db: UniProt

Reference/ChEBI CHEBI 58490
type: UnificationXref
id: CHEBI:58490
db: ChEBI

Reference/KEGG Compound C20484
type: UnificationXref
id: C20484
db: KEGG Compound

Reference/ChEBI CHEBI 8191
type: UnificationXref
id: CHEBI:8191
db: ChEBI

Reference/BioCyc CPD1F-129
type: UnificationXref
id: CPD1F-129
db: BioCyc

Reference/KEGG Compound C01847
type: UnificationXref
id: C01847
db: KEGG Compound

Reference/BioCyc CPD1F-126
type: UnificationXref
id: CPD1F-126
db: BioCyc

abscisic aldehyde
type: SmallMolecule
cellular location: Cytoplasm
entity reference: abscisic aldehyde

Reference/ChemSpider 553581
type: UnificationXref
id: 553581
db: ChemSpider

Reference/PubChem-compound 5893
type: UnificationXref
id: 5893
db: PubChem-compound

Reference/PubChem-compound 25244821
type: UnificationXref
id: 25244821
db: PubChem-compound

Reference/UniProt Q9SE50
type: UnificationXref
id: Q9SE50
db: UniProt

ChemicalStructure/PW C000891
type: ChemicalStructure
structure format: SMILES

Reference/ChEBI CHEBI 28205
type: UnificationXref
id: CHEBI:28205
db: ChEBI

violaxanthin deepoxidase / antheraxanthin deepoxidase
type: Protein
cellular location: Chloroplast
entity reference: violaxanthin deepoxidase / antheraxanthin deepoxidase

ChemicalStructure/PW C001860
type: ChemicalStructure
structure format: SMILES
structure data: O=C1C=CC(=O)C=C1

Reference/BioCyc CPD-12829
type: UnificationXref
id: CPD-12829
db: BioCyc

Reference/BioCyc CPD1F-131
type: UnificationXref
id: CPD1F-131
db: BioCyc

Reference/BioCyc CPD1F-130
type: UnificationXref
id: CPD1F-130
db: BioCyc

Compound/PW C041101 Chloroplast/Stoichiometry/4.0
type: Stoichiometry
physical entity: Oxidized ferredoxin
stoichiometric coefficient: 4.0

Compound/PW C001778/Stoichiometry/1.0
type: Stoichiometry
physical entity: Violaxanthin
stoichiometric coefficient: 1.0

Reference/ChemSpider 4444344
type: UnificationXref
id: 4444344
db: ChemSpider

Reference/ChEBI CHEBI 15377
type: UnificationXref
id: CHEBI:15377
db: ChEBI

Reference/ChEBI CHEBI 15379
type: UnificationXref
id: CHEBI:15379
db: ChEBI

Chloroplast
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0009507

Reference/ChemSpider 4444347
type: UnificationXref
id: 4444347
db: ChemSpider

Reference/ChEBI CHEBI 15378
type: UnificationXref
id: CHEBI:15378
db: ChEBI

ChemicalStructure/PW C040034
type: ChemicalStructure
structure format: SMILES
structure data: [H+]

Reference/BioCyc CPD1F-119
type: UnificationXref
id: CPD1F-119
db: BioCyc

Reference/BioCyc CPD1F-118
type: UnificationXref
id: CPD1F-118
db: BioCyc

Prolycopene isomerase, chloroplastic
type: ProteinReference
xref: Reference/UniProt Q9M9Y8
organism: Arabidopsis thaliana

(9Z,7'Z,9'Z)-7,8-Dihydrolycopene
type: SmallMolecule
cellular location: Chloroplast
entity reference: (9Z,7'Z,9'Z)-7,8-Dihydrolycopene

Lycopene epsilon cyclase, chloroplastic
type: ProteinReference
xref: Reference/UniProt Q38932
organism: Arabidopsis thaliana

Reference/HMDB HMDB0030130
type: UnificationXref
id: HMDB0030130
db: HMDB

Reference/CAS 514-90-9
type: UnificationXref
id: 514-90-9
db: CAS

Phytoene synthase, chloroplastic
type: ProteinReference
xref: Reference/UniProt P37271
organism: Arabidopsis thaliana

15-cis-phytoene desaturase, chloroplastic/chromoplastic
type: ProteinReference
xref: Reference/UniProt Q07356
organism: Arabidopsis thaliana

15-cis-zeta-carotene isomerase, chloroplastic
type: ProteinReference
xref: Reference/UniProt Q9SAC0
organism: Arabidopsis thaliana

Zeta-carotene desaturase, chloroplastic/chromoplastic
type: ProteinReference
xref: Reference/UniProt Q38893
organism: Arabidopsis thaliana

Compound/PW C001420/Stoichiometry/1.0
type: Stoichiometry
physical entity: Water
stoichiometric coefficient: 1.0

ChemicalStructure/PW C001632
type: ChemicalStructure
structure format: SMILES
structure data: OC1=CC=C(O)C=C1

Reference/BioCyc L-DEHYDRO-ASCORBATE
type: UnificationXref
id: L-DEHYDRO-ASCORBATE
db: BioCyc

Reference/ChemSpider 4444349
type: UnificationXref
id: 4444349
db: ChemSpider

Geranylgeranyl-PP
type: SmallMolecule
cellular location: Chloroplast
entity reference: Geranylgeranyl-PP

Dihydrophaseic acid
type: SmallMoleculeReference
xref: Reference/CAS 41756-77-8
xref: Reference/HMDB HMDB0038660
xref: Reference/ChEBI CHEBI 23758
xref: Reference/KEGG Compound C15971
xref: Reference/ChemSpider 24808182
chemical formula: C15H22O5
molecular weight: 282.14673
structure: ChemicalStructure/PW C019503

Reference/BioCyc CPD-7234
type: UnificationXref
id: CPD-7234
db: BioCyc

Compound/PW C001420 Endoplasmic Reticulum/Stoichiometry/1.0
type: Stoichiometry
physical entity: Water
stoichiometric coefficient: 1.0

Compound/PW C057884 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: (2E,4E,6E)-7-hydroxy-4-methylhepta-2,4,6-trienal
stoichiometric coefficient: 1.0

Reference/KEGG Compound C00530
type: UnificationXref
id: C00530
db: KEGG Compound

Carotene epsilon-monooxygenase, chloroplastic
type: ProteinReference
xref: Reference/UniProt Q6TBX7
organism: Arabidopsis thaliana

Reference/BioCyc FMNH2
type: UnificationXref
id: FMNH2
db: BioCyc

Reference/CAS 79-77-6
type: UnificationXref
id: 79-77-6
db: CAS

Abscisic acid 8'-hydroxylase 2
type: ProteinReference
xref: Reference/UniProt O81077

Reference/ChEBI CHEBI 28425
type: UnificationXref
id: CHEBI:28425
db: ChEBI

Protein LUTEIN DEFICIENT 5, chloroplastic
type: ProteinReference
xref: Reference/UniProt Q93VK5
organism: Arabidopsis thaliana

Reference/HMDB HMDB0112264
type: UnificationXref
id: HMDB0112264
db: HMDB

Reference/CAS 7235-40-7
type: UnificationXref
id: 7235-40-7
db: CAS

Reference/HMDB HMDB0112262
type: UnificationXref
id: HMDB0112262
db: HMDB

ChemicalStructure/PW C014903
type: ChemicalStructure
structure format: SMILES
structure data: C\C(\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C)=C/C=C/C=C(\C)/C=C/C=C(\C)/C=C/C1=C(C)CC(O)CC1(C)C

Dihydrophaseic acid
type: SmallMolecule
entity reference: Dihydrophaseic acid

β-Ionone
type: SmallMoleculeReference
xref: Reference/CAS 79-77-6
xref: Reference/ChEBI CHEBI 32325
xref: Reference/KEGG Compound C12287
xref: Reference/ChemSpider 553581
xref: Reference/PubChem-compound 638014
xref: Reference/HMDB HMDB0036565
chemical formula: C13H20O
molecular weight: 192.15141
structure: ChemicalStructure/PW C017456

Reference/KEGG Compound C00425
type: UnificationXref
id: C00425
db: KEGG Compound

Reference/HMDB HMDB0039089
type: UnificationXref
id: HMDB0039089
db: HMDB

ChemicalStructure/PW C020466
type: ChemicalStructure
structure format: SMILES
structure data: C\C(=C/CO)\C=C\C1(O)C(C)=CC(=O)CC1(C)C

Reference/HMDB HMDB0000516
type: UnificationXref
id: HMDB0000516
db: HMDB

Compound/PW C001766 Chloroplast/Stoichiometry/1.0
type: Stoichiometry
physical entity: (9-cis,9'-cis)-7,7',8,8'-Tetrahydro-psi,psi-carotene
stoichiometric coefficient: 1.0

Reference/CAS 106-51-4
type: UnificationXref
id: 106-51-4
db: CAS

ChemicalStructure/PW C001722
type: ChemicalStructure
structure format: SMILES
structure data: CC(C)=CCC\C(C)=C\CC\C(C)=C/CC\C(C)=C\C=C\C=C(/C)\C=C\C=C(/C)CC\C=C(/C)CCC=C(C)C

Reference/UniProt Q7XA78
type: UnificationXref
id: Q7XA78
db: UniProt

9,9',15-Tri-cis-zeta-carotene
type: SmallMolecule
cellular location: Chloroplast
entity reference: 9,9',15-Tri-cis-zeta-carotene

Reference/BioCyc ASCORBATE
type: UnificationXref
id: ASCORBATE
db: BioCyc

Reference/KEGG Compound C06098
type: UnificationXref
id: C06098
db: KEGG Compound

Reference/HMDB HMDB0036925
type: UnificationXref
id: HMDB0036925
db: HMDB

Reference/PubChem-compound 6440490
type: UnificationXref
id: 6440490
db: PubChem-compound

Zeinoxanthin
type: SmallMolecule
cellular location: Chloroplast
entity reference: Zeinoxanthin

plastoquinol-9
type: SmallMolecule
cellular location: Chloroplast
entity reference: plastoquinol-9