Aldehyde dehydrogenase family 2 member C4
Oxygen + [Reduced NADPH---hemoprotein reductase] + trans-Cinnamic acid → 4-Hydroxycinnamic acid + Water + [Oxidized NADPH---hemoprotein reductase]
[Oxidized NADPH---hemoprotein reductase]
Adenosine triphosphate + Coenzyme A + trans-Cinnamic acid → Adenosine monophosphate + Cinnamoyl-CoA + Diphosphoric acid
Cinnamaldehyde + Coenzyme A + NADP ← Cinnamoyl-CoA + Hydrogen Ion + NADPH
Coenzyme A + NADP + p-Coumaraldehyde ← Coumaroyl-CoA + Hydrogen Ion + NADPH
Hydrogen Ion + NADPH + p-Coumaraldehyde → 4-Coumaryl alcohol + NADP
4-Coumaroylshikimic acid + Oxygen + [Reduced NADPH---hemoprotein reductase] → 5-O-Caffeoylshikimic acid + Water + [Oxidized NADPH---hemoprotein reductase]
5-O-Caffeoylshikimic acid + Coenzyme A → Caffeoyl-CoA + Shikimic acid
5-O-Caffeoylshikimic acid + Water → 3,4-Dihydroxy-trans-cinnamate + Shikimic acid
3,4-Dihydroxy-trans-cinnamate + Adenosine triphosphate + Coenzyme A → Adenosine monophosphate + Caffeoyl-CoA + Diphosphoric acid
3,4-Dihydroxy-trans-cinnamate + S-Adenosylmethionine → S-Adenosylhomocysteine + trans-Ferulic acid
Caffeic aldehyde + Coenzyme A + NADP ← Caffeoyl-CoA + Hydrogen Ion + NADPH
Sinapyl alcohol (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Extracellular Space
1-O-Sinapoyl-beta-D-glucose (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Plant-Type Vacuole
1-O-Sinapoyl-beta-D-glucose (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Extracellular Space
Caffeic aldehyde + Hydrogen Ion + NADPH → Caffeyl alcohol + NADP
4-Coumaryl alcohol (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Nucleus
Sinapyl alcohol (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Nucleus
5-Hydroxyconiferyl alcohol (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Extracellular Space
4-Coumaryl alcohol → Caffeyl alcohol
Adenosine triphosphate + Coenzyme A + trans-Ferulic acid → Adenosine monophosphate + Diphosphoric acid + Feruloyl-CoA
Coniferyl alcohol (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Nucleus
3-(3,4-Dihydroxy-5-methoxy)-2-propenoic acid
Hydroxycinnamoyl-CoA shikimate/quinate hydroxycinnamoyl transferase
Coumaroyl-CoA + Shikimic acid → 4-Coumaroylshikimic acid + Coenzyme A
Caffeoyl-CoA + Quinate ← Chlorogenic acid + Coenzyme A
Cinnamoyl-CoA + Oxygen + [Reduced NADPH---hemoprotein reductase] → Coumaroyl-CoA + Water + [Oxidized NADPH---hemoprotein reductase]
4-Hydroxycinnamic acid + Adenosine triphosphate + Coenzyme A → Adenosine monophosphate + Coumaroyl-CoA + Pyrophosphate
4-Coumaryl alcohol → p-Hydroxyphenyl lignin
Coniferyl alcohol → Guaiacyl lignin
5-Hydroxyconiferyl alcohol → 5-Hydroxy-guaiacyl lignin
Coumaroyl-CoA + Quinate → Coenzyme A + p-Coumaroyl quinic acid
N1,N5,N10-Tri(hydroxyferuloyl) spermidine
Oxygen + [Reduced NADPH---hemoprotein reductase] + p-Coumaroyl quinic acid → Chlorogenic acid + Water + [Oxidized NADPH---hemoprotein reductase]
Caffeoyl-CoA + S-Adenosylmethionine → Feruloyl-CoA + S-Adenosylhomocysteine
Coniferyl alcohol (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Extracellular Space
4-Coumaryl alcohol (→) Transport: Arabidopsis thaliana, Cell, Cytosol to Arabidopsis thaliana, Cell, Extracellular Space
Stillbenoid Diarylhe Ptanoid and Gingerol Biosynthesis
Caffeic aldehyde + S-Adenosylmethionine → Coniferyl aldehyde + S-Adenosylhomocysteine
Coniferyl alcohol + NADP ← Coniferyl aldehyde + Hydrogen Ion + NADPH
Caffeyl alcohol + S-Adenosylmethionine → Coniferyl alcohol + S-Adenosylhomocysteine
Coniferyl aldehyde + NADP + Water → Hydrogen Ion + NADPH + trans-Ferulic acid
Hydrogen Ion + NADPH + Oxygen + trans-Ferulic acid → 3-(3,4-Dihydroxy-5-methoxy)-2-propenoic acid + NADP + Water
3-(3,4-Dihydroxy-5-methoxy)-2-propenoic acid + Adenosine triphosphate + Coenzyme A → 5-Hydroxyferuloyl-CoA + Adenosine monophosphate + Diphosphoric acid
5-Hydroxyferuloyl-CoA + Hydrogen Ion + NADPH → 5-Hydroxyconiferaldehyde + Coenzyme A + NADP
5-Hydroxyconiferaldehyde + Hydrogen Ion + NADPH ? 5-Hydroxyconiferyl alcohol + NADP
Coenzyme A + Coniferyl aldehyde + NADP ← Feruloyl-CoA + Hydrogen Ion + NADPH
Feruloyl-CoA → 5-Hydroxyferuloyl-CoA
Coniferyl alcohol + Hydrogen Ion + NADPH + Oxygen → 5-Hydroxyconiferyl alcohol + NADP + Water
3-(3,4-Dihydroxy-5-methoxy)-2-propenoic acid + S-Adenosylmethionine → S-Adenosylhomocysteine + Sinapic acid
Adenosine triphosphate + Coenzyme A + Sinapic acid → Adenosine monophosphate + Diphosphoric acid + Sinapoyl-CoA
5-Hydroxyferuloyl-CoA + S-Adenosylmethionine → S-Adenosylhomocysteine + Sinapoyl-CoA
Coenzyme A + NADP + Sinapoyl aldehyde ← Hydrogen Ion + NADPH + Sinapoyl-CoA
NADP + Sinapyl alcohol ← Hydrogen Ion + NADPH + Sinapoyl aldehyde
5-Hydroxyconiferaldehyde + S-Adenosylmethionine → S-Adenosylhomocysteine + Sinapoyl aldehyde
5-Hydroxyconiferyl alcohol + S-Adenosylmethionine → S-Adenosylhomocysteine + Sinapyl alcohol
Coniferyl aldehyde + Hydrogen Ion + NADPH + Oxygen → 5-Hydroxyconiferaldehyde + NADP + Water
NADP + Sinapoyl aldehyde + Water → Hydrogen Ion + NADPH + Sinapic acid
Feruloyl-CoA + Oxoglutaric acid + Oxygen → 6-Hydroxyferuloyl-CoA + Carbon dioxide + Succinic acid
N1,N5-Di(hydroxyferuloyl)-N10-sinapoyl spermidine
Coumaroyl-CoA → N1,N5,N10-Tricoumaroyl spermidine
N1,N5,N10-Tricoumaroyl spermidine → N1,N5,N10-Tricaffeoyl spermidine
N1,N5,N10-Tricaffeoyl spermidine → N1,N5,N10-Triferuloyl spermidine
N1,N5,N10-Triferuloyl spermidine → N1,N5,N10-Tri(hydroxyferuloyl) spermidine
N1,N5,N10-Tri(hydroxyferuloyl) spermidine + S-Adenosylmethionine → N1,N5-Di(hydroxyferuloyl)-N10-sinapoyl spermidine + S-Adenosylhomocysteine
4-Coumaryl alcohol + Uridine diphosphate glucose → 4-Hydroxycinnamyl alcohol 4-D-glucoside + Uridine 5'-diphosphate
Coniferyl alcohol + Uridine diphosphate glucose → Coniferin + Uridine 5'-diphosphate
Sinapyl alcohol + Uridine diphosphate glucose → Syringin + Uridine 5'-diphosphate
Sinapic acid + Uridine diphosphate glucose → 1-O-Sinapoyl-beta-D-glucose + Uridine 5'-diphosphate
1-O-Sinapoyl-beta-D-glucose + L-Malic acid → D-Glucose + Sinapoyl malate
D-Glucose + Sinapine ← 1-O-Sinapoyl-beta-D-glucose + Choline
L-Phenylalanine → Ammonium + trans-Cinnamic acid