N-acetyl-α-D-glucosaminyl-diphospho-ditrans,octacis-undecaprenol + UDP-ManNAcA → Hydrogen Ion + Undecaprenyl N-acetyl-glucosaminyl-N-acetyl-mannosaminuronate pyrophosphate + Uridine 5'-diphosphate
Uridine diphosphate-N-acetylglucosamine + di-trans,octa-cis-undecaprenyl phosphate → N-acetyl-α-D-glucosaminyl-diphospho-ditrans,octacis-undecaprenol + Uridine 5'-monophosphate
undecaprenyl-phosphate α-N-acetylglucosaminyl transferase
TDP-Fuc4NAc + Undecaprenyl N-acetyl-glucosaminyl-N-acetyl-mannosaminuronate pyrophosphate → Hydrogen Ion + Undecaprenyl N-acetyl-glucosaminyl-N-acetyl-mannosaminuronate-4-acetamido-4,6-dideoxy-D-galactose pyrophosphate + dTDP
Secondary Metabolites: Methylerythritol Phosphate and Polyisoprenoid Biosynthesis
Glucose 1-phosphate + Hydrogen Ion + Thymidine 5'-triphosphate → Pyrophosphate + dTDP-D-glucose
L-Glutamic acid + dTDP-4-dehydro-6-deoxy-D-glucose → dTDP-thomosamine + Oxoglutaric acid
dTDP-4-dehydro-6-deoxy-D-glucose transaminase
dTDP-thomosamine + Acetyl-CoA → Coenzyme A + Hydrogen Ion + TDP-Fuc4NAc
Amino Sugar and Nucleotide Sugar Metabolism I
Undecaprenyl N-acetyl-glucosaminyl-N-acetyl-mannosaminuronate-4-acetamido-4,6-dideoxy-D-galactose pyrophosphate
Undecaprenyl N-acetyl-glucosaminyl-N-acetyl-mannosaminuronate pyrophosphate
Secondary Metabolites: Enterobacterial Common Antigen Biosynthesis
Undecaprenyl N-acetyl-glucosaminyl-N-acetyl-mannosaminuronate-4-acetamido-4,6-dideoxy-D-galactose pyrophosphate (→) Transport: Escherichia coli O157:H7 str. TW14359, Cytosol to Escherichia coli O157:H7 str. TW14359, Periplasmic Space
di-trans,octa-cis-undecaprenyl phosphate
dTDP-D-glucose → Water + dTDP-4-dehydro-6-deoxy-D-glucose