dTDP-4-dehydrorhamnose 3,5-epimerase
type: ProteinReference
xref: Reference/UniProt K9ENR9

dTDP-glucose 4,6-dehydratase
type: ProteinReference
xref: Reference/UniProt K9E275

Reference/ChemSpider 17215925
type: UnificationXref
id: 17215925
db: ChemSpider

Reference/ChemSpider 937
type: UnificationXref
id: 937
db: ChemSpider

Reference/ChEBI CHEBI 35452
type: UnificationXref
id: CHEBI:35452
db: ChEBI

Protein/Generic518/Stoichiometry/2.0
type: Stoichiometry
physical entity: [Acyl-carrier protein]
stoichiometric coefficient: 2.0

dTDP-D-glucose
type: SmallMolecule
entity reference: dTDP-D-glucose

Protein/Generic203/Stoichiometry/2.0
type: Stoichiometry
physical entity: (3R)-3-Hydroxyacyl-[acyl-carrier protein]
stoichiometric coefficient: 2.0

ChemicalStructure/PW C108465
type: ChemicalStructure
structure format: SMILES
structure data: CCCCCC\C=C/CCCCC[C@@H](O)CC(=O)O[C@H](CCC\C=C/CCCCCC)CC(O)=O

ChemicalStructure/PW C001420
type: ChemicalStructure
structure format: SMILES
structure data: O

diRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
type: SmallMolecule
entity reference: diRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))

Pyrophosphate
type: SmallMolecule
entity reference: Pyrophosphate

Compound/PW C040034/Stoichiometry/1.0
type: Stoichiometry
physical entity: Hydrogen Ion
stoichiometric coefficient: 1.0

ChemicalStructure/PW C042658
type: ChemicalStructure
structure format: SMILES

Reference/KEGG Compound C00688
type: UnificationXref
id: C00688
db: KEGG Compound

Reference/BioCyc Mono-Rhamnolipids
type: UnificationXref
id: Mono-Rhamnolipids
db: BioCyc

(3R)-3-Hydroxyacyl-[acyl-carrier protein]
type: ProteinReference
xref: Reference/KEGG Compound C01271

Reference/ChemSpider 559142
type: UnificationXref
id: 559142
db: ChemSpider

Rhamnolipid Biosynthesis RL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
type: Pathway
pathway order: PathwayEnzymeReaction/7083870
pathway order: PathwayEnzymeReaction/7083881
pathway order: PathwaySubPathway/536354
pathway order: PathwayEnzymeReaction/7083878
pathway order: PathwayEnzymeReaction/7083866
pathway order: PathwaySubPathway/536355
pathway order: PathwayEnzymeReaction/7083875
pathway order: PathwayEnzymeReaction/7083873
pathway order: PathwayEnzymeReaction/7083883
pathway order: PathwayEnzymeReaction/7083882
pathway component: 5.1.3.13
pathway component: 2.7.7.24
pathway component: Reaction1326682
pathway component: ReactionCatalysis1359639
pathway component: 2.4.1.-
pathway component: 2.3.1.-
pathway component: 5.4.2.2
pathway component: ReactionCatalysis1359637
pathway component: Fatty Acid Biosynthesis
pathway component: ReactionCatalysis1359635
pathway component: ReactionCatalysis1359646
pathway component: ReactionCatalysis1359645
pathway component: ReactionCatalysis1098186
pathway component: ReactionCatalysis1359644
pathway component: Galactose Metabolism
pathway component: 1.1.1.133
pathway component: ReactionCatalysis1359642
xref: Reference/SMPDB SMP0486760
xref: Reference/PathWhiz PW510003
organism: Bacteroides oleiciplenus YIT 12058

Galactose Metabolism
type: Pathway
pathway order: SubPathwayInteractionSteps/SubPathway536355
pathway component: SubPathwayInteraction536355
xref: Reference/SMPDB SMP0000841
xref: Reference/PathWhiz PW000821
name: SubPathway

Compound/PW C044520/Stoichiometry/1.0
type: Stoichiometry
physical entity: dTDP-4-dehydro-β-L-rhamnose
stoichiometric coefficient: 1.0

Reference/KEGG Compound C00459
type: UnificationXref
id: C00459
db: KEGG Compound

Reference/ChemSpider 388455
type: UnificationXref
id: 388455
db: ChemSpider

Reference/CAS 53-59-8
type: UnificationXref
id: 53-59-8
db: CAS

Reference/ChemSpider 5743
type: UnificationXref
id: 5743
db: ChemSpider

Reference/CAS 365-08-2
type: UnificationXref
id: 365-08-2
db: CAS

Reference/PubChem-compound 1038
type: UnificationXref
id: 1038
db: PubChem-compound

Compound/PW C002734/Stoichiometry/1.0
type: Stoichiometry
physical entity: dTDP-β-L-rhamnose
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 16474
type: UnificationXref
id: CHEBI:16474
db: ChEBI

Reference/HMDB HMDB0001401
type: UnificationXref
id: HMDB0001401
db: HMDB

Reference/PubChem-compound 64968
type: UnificationXref
id: 64968
db: PubChem-compound

Reference/PubChem-compound 439975
type: UnificationXref
id: 439975
db: PubChem-compound

ChemicalStructure/PW C001083
type: ChemicalStructure
structure format: SMILES

diRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
type: SmallMoleculeReference
xref: Reference/BioCyc Di-Rhamnolipids
chemical formula: C42H74O13
molecular weight: 786.51294
structure: ChemicalStructure/PW C108627

Unknown
type: Protein
entity reference: Unknown

Reference/KEGG Compound C00229
type: UnificationXref
id: C00229
db: KEGG Compound

Reference/PathWhiz PW002458
type: UnificationXref
id: PW002458
db: PathWhiz

Reference/PubChem-compound 164628
type: UnificationXref
id: 164628
db: PubChem-compound

Reference/UniProt K9EKV7
type: UnificationXref
id: K9EKV7
db: UniProt

Reference/ChemSpider 58493
type: UnificationXref
id: 58493
db: ChemSpider

NADPH
type: SmallMolecule
entity reference: NADPH

Reference/KEGG Compound C00103
type: UnificationXref
id: C00103
db: KEGG Compound

ChemicalStructure/PW C002734
type: ChemicalStructure
structure format: SMILES

Reference/ChemSpider 1010
type: UnificationXref
id: 1010
db: ChemSpider

Reference/PubChem-compound 439165
type: UnificationXref
id: 439165
db: PubChem-compound

NADP
type: SmallMolecule
entity reference: NADP

Reference/BioCyc PPI
type: UnificationXref
id: PPI
db: BioCyc

NADPH
type: SmallMoleculeReference
xref: Reference/CAS 53-57-6
xref: Reference/HMDB HMDB0000221
xref: Reference/PubChem-compound 22833512
xref: Reference/BioCyc NADPH
xref: Reference/ChemSpider 17215925
xref: Reference/KEGG Compound C00005
xref: Reference/ChEBI CHEBI 16474
chemical formula: C21H30N7O17P3
molecular weight: 745.0911
structure: ChemicalStructure/PW C000146

Fatty Acid Biosynthesis
type: Pathway
pathway order: SubPathwayInteractionSteps/SubPathway536354
pathway component: SubPathwayInteraction536354
xref: Reference/SMPDB SMP0002360
xref: Reference/PathWhiz PW002458
name: SubPathway

[Acyl-carrier protein]
type: Protein
entity reference: [Acyl-carrier protein]

Compound/PW C000987/Stoichiometry/1.0
type: Stoichiometry
physical entity: dTDP
stoichiometric coefficient: 1.0

NADP
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00006
xref: Reference/CAS 53-59-8
xref: Reference/BioCyc NAD(P)
xref: Reference/HMDB HMDB0000217
xref: Reference/ChEBI CHEBI 18009
xref: Reference/PubChem-compound 5886
xref: Reference/ChemSpider 5675
chemical formula: C21H28N7O17P3
molecular weight: 743.07544
structure: ChemicalStructure/PW C000143

Reference/PathWhiz PW000821
type: UnificationXref
id: PW000821
db: PathWhiz

SubPathwayInteraction536355
type: Interaction
name: SubPathwayReaction
name: SubPathway536355Reaction
participant: Glucose 6-phosphate

SubPathwayInteraction536354
type: Interaction
name: SubPathwayReaction
name: SubPathway536354Reaction
participant: (3R)-3-Hydroxyacyl-[acyl-carrier protein]

Compound/PW C000146/Stoichiometry/1.0
type: Stoichiometry
physical entity: NADPH
stoichiometric coefficient: 1.0

Reference/ChemSpider 144320
type: UnificationXref
id: 144320
db: ChemSpider

Reference/BioCyc NADPH
type: UnificationXref
id: NADPH
db: BioCyc

dTDP
type: SmallMoleculeReference
xref: Reference/CAS 491-97-4
xref: Reference/ChemSpider 144320
xref: Reference/PubChem-compound 164628
xref: Reference/KEGG Compound C00363
xref: Reference/ChEBI CHEBI 18075
xref: Reference/HMDB HMDB0001274
xref: Reference/BioCyc TDP
chemical formula: C10H16N2O11P2
molecular weight: 402.02292
structure: ChemicalStructure/PW C000987

(3R)-3-Hydroxyacyl-[acyl-carrier protein]
type: Protein
entity reference: (3R)-3-Hydroxyacyl-[acyl-carrier protein]

Hydrogen Ion
type: SmallMolecule
entity reference: Hydrogen Ion

Reference/SMPDB SMP0000841
type: UnificationXref
id: SMP0000841
db: SMPDB

Reference/CAS 59-56-3
type: UnificationXref
id: 59-56-3
db: CAS

Reference/ChemSpider 388311
type: UnificationXref
id: 388311
db: ChemSpider

Reference/HMDB HMDB0000217
type: UnificationXref
id: HMDB0000217
db: HMDB

Reference/SMPDB SMP0486760
type: UnificationXref
id: SMP0486760
db: SMPDB

Reference/GENE ONTOLOGY GO 0005886
type: UnificationXref
id: GO:0005886
db: GENE ONTOLOGY

monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
type: SmallMolecule
entity reference: monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))

Compound/PW C042658/Stoichiometry/1.0
type: Stoichiometry
physical entity: dTDP-4-dehydro-6-deoxy-D-glucose
stoichiometric coefficient: 1.0

Reference/KEGG Compound C00006
type: UnificationXref
id: C00006
db: KEGG Compound

Reference/ChEBI CHEBI 18009
type: UnificationXref
id: CHEBI:18009
db: ChEBI

Reference/KEGG Compound C00001
type: UnificationXref
id: C00001
db: KEGG Compound

Reference/KEGG Compound C00363
type: UnificationXref
id: C00363
db: KEGG Compound

Reference/ChEBI CHEBI 35248
type: UnificationXref
id: CHEBI:35248
db: ChEBI

Reference/ChEBI CHEBI 18361
type: UnificationXref
id: CHEBI:18361
db: ChEBI

Reference/HMDB HMDB0060081
type: UnificationXref
id: HMDB0060081
db: HMDB

Reference/KEGG Compound C00005
type: UnificationXref
id: C00005
db: KEGG Compound

ChemicalStructure/PW C000143
type: ChemicalStructure
structure format: SMILES

Reference/HMDB HMDB0000221
type: UnificationXref
id: HMDB0000221
db: HMDB

ChemicalStructure/PW C000146
type: ChemicalStructure
structure format: SMILES

Reference/BioCyc GLC-1-P
type: UnificationXref
id: GLC-1-P
db: BioCyc

Compound/PW C108627/Stoichiometry/1.0
type: Stoichiometry
physical entity: diRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
stoichiometric coefficient: 1.0

Reference/CAS 53-57-6
type: UnificationXref
id: 53-57-6
db: CAS

[Acyl-carrier protein]
type: ProteinReference
xref: Reference/KEGG Compound C00229

Reference/BioCyc TDP
type: UnificationXref
id: TDP
db: BioCyc

Reference/KEGG Compound C00013
type: UnificationXref
id: C00013
db: KEGG Compound

Pyrophosphate
type: SmallMoleculeReference
xref: Reference/PubChem-compound 644102
xref: Reference/BioCyc PPI
xref: Reference/ChemSpider 559142
xref: Reference/ChEBI CHEBI 18361
xref: Reference/HMDB HMDB0000250
xref: Reference/CAS 14000-31-8
xref: Reference/KEGG Compound C00013
chemical formula: H4O7P2
molecular weight: 177.94322
structure: ChemicalStructure/PW C000170

Reference/SMPDB SMP0002360
type: UnificationXref
id: SMP0002360
db: SMPDB

Reference/PubChem-compound 5958
type: UnificationXref
id: 5958
db: PubChem-compound

Reference/BioCyc NAD(P)
type: UnificationXref
id: NAD(P)
db: BioCyc

dTDP-D-glucose
type: SmallMoleculeReference
xref: Reference/ChemSpider 388455
xref: Reference/KEGG Compound C00842
xref: Reference/PubChem-compound 439324
xref: Reference/HMDB HMDB0001328
xref: Reference/CAS 2196-62-5
xref: Reference/ChEBI CHEBI 35248
xref: Reference/BioCyc DTDP-D-GLUCOSE
chemical formula: C16H26N2O16P2
molecular weight: 564.07574
structure: ChemicalStructure/PW C001024

Reference/HMDB HMDB0001328
type: UnificationXref
id: HMDB0001328
db: HMDB

Bacteroides oleiciplenus YIT 12058
type: BioSource
xref: Reference/TAXONOMY 742727

dTDP-glucose 4,6-dehydratase
type: Protein
entity reference: dTDP-glucose 4,6-dehydratase

dTDP-4-dehydrorhamnose 3,5-epimerase
type: Protein
entity reference: dTDP-4-dehydrorhamnose 3,5-epimerase

monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
type: SmallMoleculeReference
xref: Reference/BioCyc Mono-Rhamnolipids
chemical formula: C36H64O9
molecular weight: 640.455
structure: ChemicalStructure/PW C108546

Hydrogen Ion
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00080
xref: Reference/ChEBI CHEBI 15378
xref: Reference/HMDB HMDB0059597
xref: Reference/PubChem-compound 1038
xref: Reference/ChemSpider 1010
chemical formula: H
molecular weight: 1.007825
structure: ChemicalStructure/PW C040034

Compound/PW C001035/Stoichiometry/1.0
type: Stoichiometry
physical entity: Thymidine 5'-triphosphate
stoichiometric coefficient: 1.0

dTDP-4-dehydro-β-L-rhamnose
type: SmallMolecule
entity reference: dTDP-4-dehydro-β-L-rhamnose

ChemicalStructure/PW C001207
type: ChemicalStructure
structure format: SMILES

dTDP
type: SmallMolecule
entity reference: dTDP

5.4.2.2
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001083/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001207/Stoichiometry/1.0
right: Glucose 1-phosphate
spontaneous: false
EC number: 5.4.2.2
left: Glucose 6-phosphate
name: Glucose 6-phosphate ↔ Glucose 1-phosphate
conversion direction: REVERSIBLE

Thymidine 5'-triphosphate
type: SmallMolecule
entity reference: Thymidine 5'-triphosphate

Thymidine 5'-triphosphate
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00459
xref: Reference/CAS 365-08-2
xref: Reference/ChEBI CHEBI 18077
xref: Reference/ChemSpider 58493
xref: Reference/PubChem-compound 64968
xref: Reference/HMDB HMDB0001342
xref: Reference/BioCyc TTP
chemical formula: C10H17N2O14P3
molecular weight: 481.98926
structure: ChemicalStructure/PW C001035

Compound/PW C000143/Stoichiometry/1.0
type: Stoichiometry
physical entity: NADP
stoichiometric coefficient: 1.0

dTDP-4-dehydro-β-L-rhamnose
type: SmallMoleculeReference
xref: Reference/ChEBI CHEBI 45868
xref: Reference/KEGG Compound C00688
chemical formula: C16H24N2O15P2
molecular weight: 546.0652
structure: ChemicalStructure/PW C044520

Reference/BioCyc TTP
type: UnificationXref
id: TTP
db: BioCyc

5.1.3.13
type: BiochemicalReaction
participant stoichiometry: Compound/PW C044520/Stoichiometry/1.0
participant stoichiometry: Compound/PW C042658/Stoichiometry/1.0
right: dTDP-4-dehydro-β-L-rhamnose
spontaneous: false
EC number: 5.1.3.13
left: dTDP-4-dehydro-6-deoxy-D-glucose
name: dTDP-4-dehydro-6-deoxy-D-glucose ↔ dTDP-4-dehydro-β-L-rhamnose
conversion direction: REVERSIBLE

2.7.7.24
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001207/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000170/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001035/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001024/Stoichiometry/1.0
right: dTDP-D-glucose
right: Pyrophosphate
spontaneous: false
EC number: 2.7.7.24
left: Thymidine 5'-triphosphate
left: Glucose 1-phosphate
name: Glucose 1-phosphate + Thymidine 5'-triphosphate → Pyrophosphate + dTDP-D-glucose
conversion direction: LEFT_TO_RIGHT

Reaction1326682
type: BiochemicalReaction
participant stoichiometry: Compound/PW C042658/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001420/Stoichiometry/1.0
participant stoichiometry: Compound/PW C001024/Stoichiometry/1.0
right: Water
right: dTDP-4-dehydro-6-deoxy-D-glucose
spontaneous: false
left: dTDP-D-glucose
name: dTDP-D-glucose → Water + dTDP-4-dehydro-6-deoxy-D-glucose
conversion direction: LEFT_TO_RIGHT

Reference/ChemSpider 388998
type: UnificationXref
id: 388998
db: ChemSpider

Glycosyl transferase family 11
type: ProteinReference
xref: Reference/UniProt K9E9D7

Glycosyltransferase 2-like domain-containing protein
type: ProteinReference
xref: Reference/UniProt K9DYV3

F5/8 type C domain-containing protein
type: ProteinReference
xref: Reference/UniProt K9EMK2

Glucose-1-phosphate thymidylyltransferase
type: Protein
entity reference: Glucose-1-phosphate thymidylyltransferase

Phosphoglucosamine mutase
type: Protein
entity reference: Phosphoglucosamine mutase

dTDP-4-dehydro-6-deoxy-D-glucose
type: SmallMolecule
entity reference: dTDP-4-dehydro-6-deoxy-D-glucose

2.4.1.-
type: BiochemicalReaction
participant stoichiometry: Compound/PW C000987/Stoichiometry/1.0
participant stoichiometry: Compound/PW C002734/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108546/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108465/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034/Stoichiometry/1.0
right: Hydrogen Ion
right: dTDP
right: monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
spontaneous: false
EC number: 2.4.1.-
left: HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z))
left: dTDP-β-L-rhamnose
name: HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z)) + dTDP-β-L-rhamnose → Hydrogen Ion + dTDP + monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
conversion direction: LEFT_TO_RIGHT

2.3.1.-
type: BiochemicalReaction
participant stoichiometry: Compound/PW C001420/Stoichiometry/1.0
participant stoichiometry: Protein/Generic203/Stoichiometry/2.0
participant stoichiometry: Protein/Generic518/Stoichiometry/2.0
participant stoichiometry: Compound/PW C108465/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034/Stoichiometry/1.0
right: HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z))
right: Hydrogen Ion
right: [Acyl-carrier protein]
spontaneous: false
EC number: 2.3.1.-
left: Water
left: (3R)-3-Hydroxyacyl-[acyl-carrier protein]
name: 2 (3R)-3-Hydroxyacyl-[acyl-carrier protein] + Water → HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z)) + Hydrogen Ion + 2 [Acyl-carrier protein]
conversion direction: LEFT_TO_RIGHT

2.4.1.-
type: BiochemicalReaction
participant stoichiometry: Compound/PW C108627/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000987/Stoichiometry/1.0
participant stoichiometry: Compound/PW C002734/Stoichiometry/1.0
participant stoichiometry: Compound/PW C108546/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034/Stoichiometry/1.0
right: Hydrogen Ion
right: diRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
right: dTDP
spontaneous: false
EC number: 2.4.1.-
left: dTDP-β-L-rhamnose
left: monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
name: dTDP-β-L-rhamnose + monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z)) → Hydrogen Ion + dTDP + diRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
conversion direction: LEFT_TO_RIGHT

Reference/HMDB HMDB0001586
type: UnificationXref
id: HMDB0001586
db: HMDB

Water
type: SmallMolecule
entity reference: Water

HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z))
type: SmallMolecule
entity reference: HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z))

ChemicalStructure/PW C001024
type: ChemicalStructure
structure format: SMILES

ReactionCatalysis1098186
type: Catalysis
controller: Unknown
controlled: 1.1.1.133
control type: ACTIVATION

Reference/HMDB HMDB0000250
type: UnificationXref
id: HMDB0000250
db: HMDB

Glucose 6-phosphate
type: SmallMoleculeReference
xref: Reference/KEGG Compound C00092
xref: Reference/BioCyc GLC-6-P
xref: Reference/HMDB HMDB0001401
xref: Reference/PubChem-compound 5958
xref: Reference/ChemSpider 5743
xref: Reference/CAS 56-73-5
xref: Reference/ChEBI CHEBI 4170
chemical formula: C6H13O9P
molecular weight: 260.02972
structure: ChemicalStructure/PW C001083

Reference/HMDB HMDB0001342
type: UnificationXref
id: HMDB0001342
db: HMDB

ChemicalStructure/PW C000170
type: ChemicalStructure
structure format: SMILES
structure data: OP(O)(=O)OP(O)(O)=O

ChemicalStructure/PW C108627
type: ChemicalStructure
structure format: SMILES

Reference/CAS 14000-31-8
type: UnificationXref
id: 14000-31-8
db: CAS

Reference/HMDB HMDB0006354
type: UnificationXref
id: HMDB0006354
db: HMDB

Reference/KEGG Compound C00842
type: UnificationXref
id: C00842
db: KEGG Compound

Reference/UniProt K9ENR9
type: UnificationXref
id: K9ENR9
db: UniProt

Reference/KEGG Compound C03319
type: UnificationXref
id: C03319
db: KEGG Compound

dTDP-β-L-rhamnose
type: SmallMoleculeReference
xref: Reference/CAS 2147-59-3
xref: Reference/KEGG Compound C03319
xref: Reference/ChemSpider 388998
xref: Reference/ChEBI CHEBI 35452
xref: Reference/PubChem-compound 439975
xref: Reference/BioCyc DTDP-RHAMNOSE
xref: Reference/HMDB HMDB0006354
chemical formula: C16H26N2O15P2
molecular weight: 548.0809
structure: ChemicalStructure/PW C002734

Reference/ChemSpider 5675
type: UnificationXref
id: 5675
db: ChemSpider

Reference/BioCyc DTDP-RHAMNOSE
type: UnificationXref
id: DTDP-RHAMNOSE
db: BioCyc

Compound/PW C000170/Stoichiometry/1.0
type: Stoichiometry
physical entity: Pyrophosphate
stoichiometric coefficient: 1.0

ChemicalStructure/PW C001035
type: ChemicalStructure
structure format: SMILES

dTDP-glucose 4,6-dehydratase
type: Complex
component stoichiometry: Protein/77380/Stoichiometry/2.0
component: dTDP-glucose 4,6-dehydratase

Reference/PathWhiz PW510003
type: UnificationXref
id: PW510003
db: PathWhiz

Compound/PW C108546/Stoichiometry/1.0
type: Stoichiometry
physical entity: monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
stoichiometric coefficient: 1.0

Reference/ChEBI CHEBI 16077
type: UnificationXref
id: CHEBI:16077
db: ChEBI

Reference/CAS 7732-18-5
type: UnificationXref
id: 7732-18-5
db: CAS

Reference/ChEBI CHEBI 4170
type: UnificationXref
id: CHEBI:4170
db: ChEBI

dTDP-β-L-rhamnose
type: SmallMolecule
entity reference: dTDP-β-L-rhamnose

Reference/UniProt K9EF32
type: UnificationXref
id: K9EF32
db: UniProt

Reference/KEGG Compound C01271
type: UnificationXref
id: C01271
db: KEGG Compound

HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z))
type: SmallMoleculeReference
xref: Reference/BioCyc 3-3-HAAs
chemical formula: C30H54O5
molecular weight: 494.39713
structure: ChemicalStructure/PW C108465

Glucose 6-phosphate
type: SmallMolecule
entity reference: Glucose 6-phosphate
name: SubPathwayOutput

dTDP-4-dehydro-6-deoxy-D-glucose
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0060081
chemical formula: C16H24N2O15P2
molecular weight: 546.0652
structure: ChemicalStructure/PW C042658

Reference/BioCyc DTDP-D-GLUCOSE
type: UnificationXref
id: DTDP-D-GLUCOSE
db: BioCyc

Reference/BioCyc GLC-6-P
type: UnificationXref
id: GLC-6-P
db: BioCyc

Protein/77380/Stoichiometry/2.0
type: Stoichiometry
physical entity: dTDP-glucose 4,6-dehydratase
stoichiometric coefficient: 2.0

Reference/PubChem-compound 439324
type: UnificationXref
id: 439324
db: PubChem-compound

Unknown
type: ProteinReference

Reference/BioCyc 3-3-HAAs
type: UnificationXref
id: 3-3-HAAs
db: BioCyc

Compound/PW C001024/Stoichiometry/1.0
type: Stoichiometry
physical entity: dTDP-D-glucose
stoichiometric coefficient: 1.0

1.1.1.133
type: BiochemicalReaction
participant stoichiometry: Compound/PW C044520/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000146/Stoichiometry/1.0
participant stoichiometry: Compound/PW C000143/Stoichiometry/1.0
participant stoichiometry: Compound/PW C002734/Stoichiometry/1.0
participant stoichiometry: Compound/PW C040034/Stoichiometry/1.0
right: NADP
right: dTDP-β-L-rhamnose
spontaneous: false
EC number: 1.1.1.133
left: dTDP-4-dehydro-β-L-rhamnose
left: Hydrogen Ion
left: NADPH
name: Hydrogen Ion + NADPH + dTDP-4-dehydro-β-L-rhamnose → NADP + dTDP-β-L-rhamnose
conversion direction: LEFT_TO_RIGHT

Reference/PubChem-compound 962
type: UnificationXref
id: 962
db: PubChem-compound

Reference/UniProt K9EMK2
type: UnificationXref
id: K9EMK2
db: UniProt

Reference/UniProt K9DYV3
type: UnificationXref
id: K9DYV3
db: UniProt

Reference/ChEBI CHEBI 18077
type: UnificationXref
id: CHEBI:18077
db: ChEBI

Reference/ChEBI CHEBI 18075
type: UnificationXref
id: CHEBI:18075
db: ChEBI

Reference/KEGG Compound C00080
type: UnificationXref
id: C00080
db: KEGG Compound

ReactionCatalysis1359637
type: Catalysis
controller: Glucose-1-phosphate thymidylyltransferase
controlled: 2.7.7.24
control type: ACTIVATION

ReactionCatalysis1359635
type: Catalysis
controller: Phosphoglucosamine mutase
controlled: 5.4.2.2
control type: ACTIVATION

ChemicalStructure/PW C108546
type: ChemicalStructure
structure format: SMILES

Reference/HMDB HMDB0002111
type: UnificationXref
id: HMDB0002111
db: HMDB

Reference/ChEBI CHEBI 15377
type: UnificationXref
id: CHEBI:15377
db: ChEBI

Reference/ChEBI CHEBI 45868
type: UnificationXref
id: CHEBI:45868
db: ChEBI

Cell Membrane
type: CellularLocationVocabulary
xref: Reference/GENE ONTOLOGY GO 0005886

Reference/ChEBI CHEBI 15378
type: UnificationXref
id: CHEBI:15378
db: ChEBI

ChemicalStructure/PW C040034
type: ChemicalStructure
structure format: SMILES
structure data: [H+]

Reference/PubChem-compound 5886
type: UnificationXref
id: 5886
db: PubChem-compound

Reference/UniProt K9E9D7
type: UnificationXref
id: K9E9D7
db: UniProt

Glucose 1-phosphate
type: SmallMoleculeReference
xref: Reference/HMDB HMDB0001586
xref: Reference/PubChem-compound 439165
xref: Reference/CAS 59-56-3
xref: Reference/BioCyc GLC-1-P
xref: Reference/ChEBI CHEBI 16077
xref: Reference/KEGG Compound C00103
xref: Reference/ChemSpider 388311
chemical formula: C6H13O9P
molecular weight: 260.02972
structure: ChemicalStructure/PW C001207

Reference/KEGG Compound C00092
type: UnificationXref
id: C00092
db: KEGG Compound

Reference/CAS 2147-59-3
type: UnificationXref
id: 2147-59-3
db: CAS

Compound/PW C001420/Stoichiometry/1.0
type: Stoichiometry
physical entity: Water
stoichiometric coefficient: 1.0

Reference/CAS 2196-62-5
type: UnificationXref
id: 2196-62-5
db: CAS

ChemicalStructure/PW C044520
type: ChemicalStructure
structure format: SMILES

Phosphoglucosamine mutase
type: ProteinReference
xref: Reference/UniProt K9EF32

Reference/HMDB HMDB0001274
type: UnificationXref
id: HMDB0001274
db: HMDB

Glucose-1-phosphate thymidylyltransferase
type: ProteinReference
xref: Reference/UniProt K9EKV7

Reference/CAS 491-97-4
type: UnificationXref
id: 491-97-4
db: CAS

Reference/PubChem-compound 644102
type: UnificationXref
id: 644102
db: PubChem-compound

ChemicalStructure/PW C000987
type: ChemicalStructure
structure format: SMILES

Glucose 1-phosphate
type: SmallMolecule
entity reference: Glucose 1-phosphate

Reference/CAS 56-73-5
type: UnificationXref
id: 56-73-5
db: CAS

Reference/UniProt K9E275
type: UnificationXref
id: K9E275
db: UniProt

Compound/PW C108465/Stoichiometry/1.0
type: Stoichiometry
physical entity: HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z))
stoichiometric coefficient: 1.0

Reference/PubChem-compound 22833512
type: UnificationXref
id: 22833512
db: PubChem-compound

Water
type: SmallMoleculeReference
xref: Reference/PubChem-compound 962
xref: Reference/ChEBI CHEBI 15377
xref: Reference/KEGG Compound C00001
xref: Reference/ChemSpider 937
xref: Reference/HMDB HMDB0002111
xref: Reference/CAS 7732-18-5
chemical formula: H2O
molecular weight: 18.010565
structure: ChemicalStructure/PW C001420

Reference/TAXONOMY 742727
type: UnificationXref
id: 742727
db: TAXONOMY

Reference/BioCyc Di-Rhamnolipids
type: UnificationXref
id: Di-Rhamnolipids
db: BioCyc

Compound/PW C001083/Stoichiometry/1.0
type: Stoichiometry
physical entity: Glucose 6-phosphate
stoichiometric coefficient: 1.0

Compound/PW C001207/Stoichiometry/1.0
type: Stoichiometry
physical entity: Glucose 1-phosphate
stoichiometric coefficient: 1.0

Reference/HMDB HMDB0059597
type: UnificationXref
id: HMDB0059597
db: HMDB

ReactionCatalysis1359639
type: Catalysis
controller: dTDP-glucose 4,6-dehydratase
controlled: Reaction1326682
control type: ACTIVATION

Glycosyltransferase 2-like domain-containing protein
type: Protein
entity reference: Glycosyltransferase 2-like domain-containing protein

Glycosyl transferase family 11
type: Protein
entity reference: Glycosyl transferase family 11

F5/8 type C domain-containing protein
type: Protein
entity reference: F5/8 type C domain-containing protein

(3R)-3-Hydroxyacyl-[acyl-carrier protein]
type: Protein
cellular location: Cell Membrane
entity reference: (3R)-3-Hydroxyacyl-[acyl-carrier protein]
name: SubPathwayOutput

ReactionCatalysis1359646
type: Catalysis
controller: Glycosyltransferase 2-like domain-containing protein
controlled: 2.4.1.-
control type: ACTIVATION

ReactionCatalysis1359645
type: Catalysis
controller: Glycosyl transferase family 11
controlled: 2.4.1.-
control type: ACTIVATION

ReactionCatalysis1359644
type: Catalysis
controller: F5/8 type C domain-containing protein
controlled: 2.3.1.-
control type: ACTIVATION

ReactionCatalysis1359642
type: Catalysis
controller: dTDP-4-dehydrorhamnose 3,5-epimerase
controlled: 5.1.3.13
control type: ACTIVATION