Phosphomannomutase / Phosphoglucomutase / Phosphoglucosamine mutase
(3R)-3-Hydroxyacyl-[acyl-carrier protein]
UTP--glucose-1-phosphate uridylyltransferase
dTDP-β-L-rhamnose + monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z)) → Hydrogen Ion + dTDP + diRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z)) + dTDP-β-L-rhamnose → Hydrogen Ion + dTDP + monoRL(16:1(3-OH,9Z)/14:1(3-OH,7Z))
2 (3R)-3-Hydroxyacyl-[acyl-carrier protein] + Water → HAA(16:1(3-OH,9Z)/14:1(3-OH,7Z)) + Hydrogen Ion + 2 [Acyl-carrier protein]
Lead, cadmium, zinc and mercury transporting ATPase
Glucose 1-phosphate + Thymidine 5'-triphosphate → Pyrophosphate + dTDP-D-glucose
Glucose 6-phosphate ↔ Glucose 1-phosphate
dTDP-4-dehydro-6-deoxy-D-glucose ↔ dTDP-4-dehydro-β-L-rhamnose
dTDP-D-glucose → Water + dTDP-4-dehydro-6-deoxy-D-glucose
Hydrogen Ion + NADPH + dTDP-4-dehydro-β-L-rhamnose → NADP + dTDP-β-L-rhamnose
Rhamnolipid Biosynthesis RL(16:1(3-OH,9Z)/14:1(3-OH,7Z))