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geranylgeranyl
dehydrogenase
geranylgeranyl
dehydrogenase
geranylgeranyl
dehydrogenase
2-carboxy- 1,4-
naphthoquinol
reductase
2-carboxy- 1,4-
naphthoquinone
phytyltransferase
demethylphylloquinone
dehydrogenase
demethylphylloquinol
methyltransferase
Geranylgeranyl-
PP
1,4-
dihydroxy-2-
naphthoate
NADPH
H
+
dihydrogeranylgeranyl
diphosphate
NADP
NADPH
H
+
tetrahydrogeranylgeranyl
diphosphate
NADP
NADPH
H
+
Phytyl
diphosphate
NADP
2-carboxy- 1,4-
naphthoquinone
H
+
Demethylphylloquinone
CO
2
PP
i
NADPH
H
+
demethylphylloquinol
NADP
S-
Adenosylmethionine
Phylloquinol
S-
Adenosylhomocysteine
H
+
FAD
oxidized
electron
acceptor
reduced
electron
acceptor
geranylgeranyl
diphosphate
biosynthesis
1,4-
dihydroxy-2-
naphthoate
biosynthesis
Inner Chloroplast Membrane
Stroma
Chloroplast
CHLP
CHLP
CHLP
?
ABC4
NDC1
MENG
Geranylgeranyl-
PP
1,4-
dihydroxy-2-
naphthoate
NADPH
Hydrogen Ion
dihydrogeranylgeranyl
diphosphate
NADP
NADPH
Hydrogen Ion
tetrahydrogeranylgeranyl
diphosphate
NADP
NADPH
Hydrogen Ion
Phytyl
diphosphate
NADP
2-carboxy- 1,4-
naphthoquinone
Hydrogen Ion
Demethylphylloquinone
Carbon dioxide
Pyrophosphate
NADPH
Hydrogen Ion
demethylphylloquinol
NADP
S-
Adenosylmethionine
Phylloquinol
S-
Adenosylhomocysteine
Hydrogen Ion
oxidized
electron
acceptor
reduced
electron
acceptor
geranylgeranyl
diphosphate
biosynthesis
1,4-
dihydroxy-2-
naphthoate
biosynthesis
CHLP
CHLP
CHLP
?
ABC4
NDC1
MENG
GGDP
14D2N
NADPH
H
+
DHGGDPP
NADP
NADPH
H
+
TetagDP
NADP
NADPH
H
+
Phytldp
NADP
2C14NQ
H
+
DMPQONE
CO
2
PP
i
NADPH
H
+
DMPQOL
NADP
SAMe
Phyl
SAH
H
+
FAD
ox-e
red-e
ge di b
1-d-2-n
Inner Chloroplast Membrane
Stroma